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Title: Boosting the thermoelectric performance of PbSe through dynamic doping and hierarchical phonon scattering

Abstract

Cu intercalation is demonstrated to enhance the thermoelectric performance of PbSe through the dynamic doping effect and hierarchical phonon scattering.

Authors:
 [1];  [1];  [2];  [3]; ORCiD logo [3];  [2];  [1];  [1]; ORCiD logo [4];  [5]; ORCiD logo [6]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [7]
  1. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
  2. Materials Genome Institute, Shanghai University, Shanghai 200444, China
  3. Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
  4. School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
  5. Shenzhen Key Laboratory of Thermoelectric Materials and Department of Physics, Southern University of Science and Technology, Shenzhen 518055, China
  6. Department of Materials Science and Engineering, Northwestern University, Evanston, USA
  7. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China, Materials Genome Institute
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1436811
Grant/Contract Number:  
SC0001299
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 11 Journal Issue: 7; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

You, Li, Liu, Yefeng, Li, Xin, Nan, Pengfei, Ge, Binghui, Jiang, Ying, Luo, Pengfei, Pan, Shanshan, Pei, Yanzhong, Zhang, Wenqing, Snyder, G. Jeffrey, Yang, Jiong, Zhang, Jiye, and Luo, Jun. Boosting the thermoelectric performance of PbSe through dynamic doping and hierarchical phonon scattering. United Kingdom: N. p., 2018. Web. doi:10.1039/C8EE00418H.
You, Li, Liu, Yefeng, Li, Xin, Nan, Pengfei, Ge, Binghui, Jiang, Ying, Luo, Pengfei, Pan, Shanshan, Pei, Yanzhong, Zhang, Wenqing, Snyder, G. Jeffrey, Yang, Jiong, Zhang, Jiye, & Luo, Jun. Boosting the thermoelectric performance of PbSe through dynamic doping and hierarchical phonon scattering. United Kingdom. doi:10.1039/C8EE00418H.
You, Li, Liu, Yefeng, Li, Xin, Nan, Pengfei, Ge, Binghui, Jiang, Ying, Luo, Pengfei, Pan, Shanshan, Pei, Yanzhong, Zhang, Wenqing, Snyder, G. Jeffrey, Yang, Jiong, Zhang, Jiye, and Luo, Jun. Mon . "Boosting the thermoelectric performance of PbSe through dynamic doping and hierarchical phonon scattering". United Kingdom. doi:10.1039/C8EE00418H.
@article{osti_1436811,
title = {Boosting the thermoelectric performance of PbSe through dynamic doping and hierarchical phonon scattering},
author = {You, Li and Liu, Yefeng and Li, Xin and Nan, Pengfei and Ge, Binghui and Jiang, Ying and Luo, Pengfei and Pan, Shanshan and Pei, Yanzhong and Zhang, Wenqing and Snyder, G. Jeffrey and Yang, Jiong and Zhang, Jiye and Luo, Jun},
abstractNote = {Cu intercalation is demonstrated to enhance the thermoelectric performance of PbSe through the dynamic doping effect and hierarchical phonon scattering.},
doi = {10.1039/C8EE00418H},
journal = {Energy & Environmental Science},
number = 7,
volume = 11,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8EE00418H

Citation Metrics:
Cited by: 18 works
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Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Temperature-dependent effective third-order interatomic force constants from first principles
journal, October 2013


High-performance n-type YbxCo4Sb12: from partially filled skutterudites towards composite thermoelectrics
journal, July 2016

  • Wang, Shanyu; Salvador, James R.; Yang, Jiong
  • NPG Asia Materials, Vol. 8, Issue 7
  • DOI: 10.1038/am.2016.77

Chemical diffusion of copper in lead telluride
journal, May 2017


Promoting SnTe as an Eco-Friendly Solution for p-PbTe Thermoelectric via Band Convergence and Interstitial Defects
journal, March 2017


Rationally Designing High-Performance Bulk Thermoelectric Materials
journal, August 2016


Dual-frequency resonant phonon scattering in BaxRyCo4Sb12 (R=La, Ce, and Sr)
journal, May 2007

  • Yang, J.; Zhang, W.; Bai, S. Q.
  • Applied Physics Letters, Vol. 90, Issue 19
  • DOI: 10.1063/1.2737422

Study of thermal stability of Cu2Se thermoelectric material
conference, January 2016

  • Bohra, Anil; Bhatt, Ranu; Bhattacharya, Shovit
  • DAE SOLID STATE PHYSICS SYMPOSIUM 2015, AIP Conference Proceedings
  • DOI: 10.1063/1.4948031

Compromise and Synergy in High-Efficiency Thermoelectric Materials
journal, March 2017


Optimum Carrier Concentration in n-Type PbTe Thermoelectrics
journal, May 2014

  • Pei, Yanzhong; Gibbs, Zachary M.; Gloskovskii, Andrei
  • Advanced Energy Materials, Vol. 4, Issue 13
  • DOI: 10.1002/aenm.201400486

Self-Tuning the Carrier Concentration of PbTe/Ag2Te Composites with Excess Ag for High Thermoelectric Performance
journal, February 2011

  • Pei, Yanzhong; May, Andrew F.; Snyder, G. Jeffrey
  • Advanced Energy Materials, Vol. 1, Issue 2
  • DOI: 10.1002/aenm.201000072

Low effective mass leading to high thermoelectric performance
journal, January 2012

  • Pei, Yanzhong; LaLonde, Aaron D.; Wang, Heng
  • Energy & Environmental Science, Vol. 5, Issue 7
  • DOI: 10.1039/c2ee21536e

Projector augmented-wave method
journal, December 1994


Resonant level-induced high thermoelectric response in indium-doped GeTe
journal, January 2017

  • Wu, Lihua; Li, Xin; Wang, Shanyu
  • NPG Asia Materials, Vol. 9, Issue 1
  • DOI: 10.1038/am.2016.203

Weak electron-phonon coupling contributing to high thermoelectric performance in n-type PbSe
journal, May 2012

  • Wang, H.; Pei, Y.; LaLonde, A. D.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 25
  • DOI: 10.1073/pnas.1111419109

Thermoelectric properties of Ag-doped Cu2Se and Cu2Te
journal, January 2013

  • Ballikaya, Sedat; Chi, Hang; Salvador, James R.
  • Journal of Materials Chemistry A, Vol. 1, Issue 40
  • DOI: 10.1039/c3ta12508d

Stabilizing the Optimal Carrier Concentration for High Thermoelectric Efficiency
journal, November 2011

  • Pei, Yanzhong; LaLonde, Aaron D.; Heinz, Nicholas A.
  • Advanced Materials, Vol. 23, Issue 47
  • DOI: 10.1002/adma.201103153

Figure of merit ZT of a thermoelectric device defined from materials properties
journal, January 2017

  • Snyder, G. Jeffrey; Snyder, Alemayouh H.
  • Energy & Environmental Science, Vol. 10, Issue 11
  • DOI: 10.1039/C7EE02007D

Partial indium solubility induces chemical stability and colossal thermoelectric figure of merit in Cu 2 Se
journal, January 2017

  • Olvera, A. A.; Moroz, N. A.; Sahoo, P.
  • Energy & Environmental Science, Vol. 10, Issue 7
  • DOI: 10.1039/C7EE01193H

Temperature dependent effective potential method for accurate free energy calculations of solids
journal, March 2013


Enhancement of thermoelectric figure-of-merit by resonant states of aluminium doping in lead selenide
journal, January 2012

  • Zhang, Qinyong; Wang, Hui; Liu, Weishu
  • Energy Environ. Sci., Vol. 5, Issue 1, p. 5246-5251
  • DOI: 10.1039/C1EE02465E

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Interrelation of Electronic Properties and Defect Equilibria in PbTe
journal, November 1961

  • Miller, E.; Komarek, K.; Cadoff, I.
  • Journal of Applied Physics, Vol. 32, Issue 11
  • DOI: 10.1063/1.1777091

Contrasting role of antimony and bismuth dopants on the thermoelectric performance of lead selenide
journal, May 2014

  • Lee, Yeseul; Lo, Shih-Han; Chen, Changqiang
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4640

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Cooling, Heating, Generating Power, and Recovering Waste Heat with Thermoelectric Systems
journal, September 2008


Anomalously low electronic thermal conductivity in metallic vanadium dioxide
journal, January 2017


Study of the Thermoelectric Properties of Lead Selenide Doped with Boron, Gallium, Indium, or Thallium
journal, October 2012

  • Zhang, Qian; Cao, Feng; Lukas, Kevin
  • Journal of the American Chemical Society, Vol. 134, Issue 42
  • DOI: 10.1021/ja307910u

Thermoelectric efficiency in graded indium-doped PbTe crystals
journal, August 2002

  • Dashevsky, Z.; Shusterman, S.; Dariel, M. P.
  • Journal of Applied Physics, Vol. 92, Issue 3
  • DOI: 10.1063/1.1490152

Lattice Dislocations Enhancing Thermoelectric PbTe in Addition to Band Convergence
journal, April 2017


Enhanced thermoelectric properties of p-type Ag 2 Te by Cu substitution
journal, January 2015

  • Zhu, Hangtian; Luo, Jun; Zhao, Huaizhou
  • Journal of Materials Chemistry A, Vol. 3, Issue 19
  • DOI: 10.1039/C5TA01266J

High-performance bulk thermoelectrics with all-scale hierarchical architectures
journal, September 2012

  • Biswas, Kanishka; He, Jiaqing; Blum, Ivan D.
  • Nature, Vol. 489, Issue 7416, p. 414-418
  • DOI: 10.1038/nature11439

Interstitial Point Defect Scattering Contributing to High Thermoelectric Performance in SnTe
journal, May 2016

  • Pei, Yanzhong; Zheng, Linglang; Li, Wen
  • Advanced Electronic Materials, Vol. 2, Issue 6
  • DOI: 10.1002/aelm.201600019

High Thermoelectric Performance in Non-Toxic Earth-Abundant Copper Sulfide
journal, March 2014


Exploring the doping effects of copper on thermoelectric properties of lead selenide
journal, June 2016


Hierarchical Chemical Bonds Contributing to the Intrinsically Low Thermal Conductivity in α-MgAgSb Thermoelectric Materials
journal, October 2016

  • Ying, Pingjun; Li, Xin; Wang, Yancheng
  • Advanced Functional Materials, Vol. 27, Issue 1
  • DOI: 10.1002/adfm.201604145

Enhanced Average Thermoelectric Figure of Merit of the PbTe–SrTe–MnTe Alloy
journal, March 2017

  • Luo, Jun; You, Li; Zhang, Jiye
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 10
  • DOI: 10.1021/acsami.6b16060

High Performance Na-doped PbTe–PbS Thermoelectric Materials: Electronic Density of States Modification and Shape-Controlled Nanostructures
journal, October 2011

  • Girard, Steven N.; He, Jiaqing; Zhou, Xiaoyuan
  • Journal of the American Chemical Society, Vol. 133, Issue 41
  • DOI: 10.1021/ja206380h

Quantitative measurement of displacement and strain fields from HREM micrographs
journal, August 1998


On the tuning of electrical and thermal transport in thermoelectrics: an integrated theory–experiment perspective
journal, February 2016


Copper ion liquid-like thermoelectrics
journal, March 2012

  • Liu, Huili; Shi, Xun; Xu, Fangfang
  • Nature Materials, Vol. 11, Issue 5, p. 422-425
  • DOI: 10.1038/nmat3273

Ultrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe
journal, November 2015


Ultrahigh thermoelectric performance in Cu 2 Se-based hybrid materials with highly dispersed molecular CNTs
journal, January 2017

  • Nunna, Raghavendra; Qiu, Pengfei; Yin, Meijie
  • Energy & Environmental Science, Vol. 10, Issue 9
  • DOI: 10.1039/C7EE01737E