A metal–organic framework immobilised iridium pincer complex
Abstract
An iridium pincer complex has been immobilised in the metal–organic framework NU-1000. The stable Ir-pincer modified NU-1000 is catalytically active in the hydrogenation of alkenes in condensed phase and under flow conditions.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States)
- Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)
- Publication Date:
- Research Org.:
- Northwestern Univ., Evanston, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1436686
- Grant/Contract Number:
- SC0012702
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 8; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Rimoldi, Martino, Nakamura, Akitake, Vermeulen, Nicolaas A., Henkelis, James J., Blackburn, Anthea K., Hupp, Joseph T., Stoddart, J. Fraser, and Farha, Omar K. A metal–organic framework immobilised iridium pincer complex. United States: N. p., 2016.
Web. doi:10.1039/c6sc01376g.
Rimoldi, Martino, Nakamura, Akitake, Vermeulen, Nicolaas A., Henkelis, James J., Blackburn, Anthea K., Hupp, Joseph T., Stoddart, J. Fraser, & Farha, Omar K. A metal–organic framework immobilised iridium pincer complex. United States. https://doi.org/10.1039/c6sc01376g
Rimoldi, Martino, Nakamura, Akitake, Vermeulen, Nicolaas A., Henkelis, James J., Blackburn, Anthea K., Hupp, Joseph T., Stoddart, J. Fraser, and Farha, Omar K. Tue .
"A metal–organic framework immobilised iridium pincer complex". United States. https://doi.org/10.1039/c6sc01376g. https://www.osti.gov/servlets/purl/1436686.
@article{osti_1436686,
title = {A metal–organic framework immobilised iridium pincer complex},
author = {Rimoldi, Martino and Nakamura, Akitake and Vermeulen, Nicolaas A. and Henkelis, James J. and Blackburn, Anthea K. and Hupp, Joseph T. and Stoddart, J. Fraser and Farha, Omar K.},
abstractNote = {An iridium pincer complex has been immobilised in the metal–organic framework NU-1000. The stable Ir-pincer modified NU-1000 is catalytically active in the hydrogenation of alkenes in condensed phase and under flow conditions.},
doi = {10.1039/c6sc01376g},
journal = {Chemical Science},
number = 8,
volume = 7,
place = {United States},
year = {Tue May 10 00:00:00 EDT 2016},
month = {Tue May 10 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 62 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Catalysis by Palladium Pincer Complexes
journal, November 2010
- Selander, Nicklas; Szabó, Kálmán J.
- Chemical Reviews, Vol. 111, Issue 3
A stable 16-electron iridium(iii) hydride complex grafted on SBA-15: a single-site catalyst for alkene hydrogenation
journal, January 2013
- Rimoldi, Martino; Fodor, Daniel; van Bokhoven, Jeroen A.
- Chemical Communications, Vol. 49, Issue 96
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013
- Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
- Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)Ni II Complexes
journal, October 2015
- Madrahimov, Sherzod T.; Gallagher, James R.; Zhang, Guanghui
- ACS Catalysis, Vol. 5, Issue 11
Water stabilization of Zr 6 -based metal–organic frameworks via solvent-assisted ligand incorporation
journal, January 2015
- Deria, Pravas; Chung, Yongchul G.; Snurr, Randall Q.
- Chemical Science, Vol. 6, Issue 9
Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t-butylphosphino)methyl]phenyl
journal, January 1976
- Moulton, Christopher J.; Shaw, Bernard L.
- J. Chem. Soc., Dalton Trans., Issue 11
Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes
journal, January 2009
- Huang, Zheng; Brookhart, Maurice; Goldman, Alan S.
- Advanced Synthesis & Catalysis, Vol. 351, Issue 1-2
Alkane Metathesis by Tandem Alkane-Dehydrogenation–Olefin-Metathesis Catalysis and Related Chemistry
journal, January 2012
- Haibach, Michael C.; Kundu, Sabuj; Brookhart, Maurice
- Accounts of Chemical Research, Vol. 45, Issue 6
Silica-Grafted 16-Electron Hydride Pincer Complexes of Iridium(III) and Their Soluble Analogues: Synthesis and Reactivity with CO
journal, October 2014
- Rimoldi, Martino; Mezzetti, Antonio
- Inorganic Chemistry, Vol. 53, Issue 22
Metal–Organic Frameworks Stabilize Solution-Inaccessible Cobalt Catalysts for Highly Efficient Broad-Scope Organic Transformations
journal, February 2016
- Zhang, Teng; Manna, Kuntal; Lin, Wenbin
- Journal of the American Chemical Society, Vol. 138, Issue 9
Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium
journal, February 2013
- Lee, Chun-I; Zhou, Jia; Ozerov, Oleg V.
- Journal of the American Chemical Society, Vol. 135, Issue 9
Catalytic Dehydrogenation of Cycloalkanes to Arenes by a Dihydrido Iridium P−C−P Pincer Complex
journal, January 1997
- Gupta, Mukta; Hagen, Chrystel; Kaska, William C.
- Journal of the American Chemical Society, Vol. 119, Issue 4
Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes
journal, October 2009
- Tanaka, Ryo; Yamashita, Makoto; Nozaki, Kyoko
- Journal of the American Chemical Society, Vol. 131, Issue 40
Reactions of Anilines and Benzamides with a 14-Electron Iridium(I) Bis(phosphinite) Complex: N−H Oxidative Addition versus Lewis Base Coordination
journal, March 2006
- Sykes, Alison Cartwright; White, Peter; Brookhart, Maurice
- Organometallics, Vol. 25, Issue 7
Reactions of iridium bis(phosphinite) pincer complexes with protic acids
journal, April 2010
- Polukeev, A. V.; Kuklin, S. A.; Petrovskii, P. V.
- Russian Chemical Bulletin, Vol. 59, Issue 4
Synthesis and Properties of Iridium Bis(phosphinite) Pincer Complexes ( p -XPCP)IrH 2 , ( p -XPCP)Ir(CO), ( p -XPCP)Ir(H)(aryl), and {( p -XPCP)Ir} 2 {μ-N 2 } and Their Relevance in Alkane Transfer Dehydrogenation
journal, April 2004
- Göttker-Schnetmann, Inigo; White, Peter S.; Brookhart, Maurice
- Organometallics, Vol. 23, Issue 8
Selective Electrocatalytic Reduction of CO 2 to Formate by Water-Stable Iridium Dihydride Pincer Complexes
journal, March 2012
- Kang, Peng; Cheng, Chen; Chen, Zuofeng
- Journal of the American Chemical Society, Vol. 134, Issue 12
Salicylaldimine-Based Metal–Organic Framework Enabling Highly Active Olefin Hydrogenation with Iron and Cobalt Catalysts
journal, September 2014
- Manna, Kuntal; Zhang, Teng; Carboni, Michaël
- Journal of the American Chemical Society, Vol. 136, Issue 38
Iridium Bis(phosphinite) p -XPCP Pincer Complexes: Highly Active Catalysts for the Transfer Dehydrogenation of Alkanes
journal, February 2004
- Göttker-Schnetmann, Inigo; White, Peter; Brookhart, Maurice
- Journal of the American Chemical Society, Vol. 126, Issue 6
Alkylruthenium Complexes Containing Polypyridyl Ligands: Synthesis, Characterization, and Immobilization on Silica
journal, April 2013
- Huang, Enrique Kwan; Cheung, Wai-Man; Chan, Ka-Wang
- European Journal of Inorganic Chemistry, Vol. 2013, Issue 16
Improved Catalytic Activity and Stability of a Palladium Pincer Complex by Incorporation into a Metal–Organic Framework
journal, February 2016
- Burgess, Samantha A.; Kassie, Abebu; Baranowski, Sarah A.
- Journal of the American Chemical Society, Vol. 138, Issue 6
C−H Oxidative Addition with a (PCP)Ir(III)-Pincer Complex
journal, December 2002
- Mohammad, Hani A. Y.; Grimm, Jost C.; Eichele, Klaus
- Organometallics, Vol. 21, Issue 26
Catalytic hydrogenation of liquid alkenes with a silica-grafted hydride pincer iridium( iii ) complex: support for a heterogeneous mechanism
journal, January 2015
- Rimoldi, M.; Fodor, D.; van Bokhoven, J. A.
- Catalysis Science & Technology, Vol. 5, Issue 9
Catalytic Alkane Metathesis by Tandem Alkane Dehydrogenation-Olefin Metathesis
journal, April 2006
- Goldman, Alan S.; Roy, Amy H.; Huang, Zheng
- Science, Vol. 312, Issue 5771, p. 257-261
Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity
journal, September 2011
- Langer, Robert; Diskin-Posner, Yael; Leitus, Gregory
- Angewandte Chemie International Edition, Vol. 50, Issue 42
Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
journal, October 2014
- Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
- Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
- Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation
journal, March 2016
- Thacker, Nathan C.; Lin, Zekai; Zhang, Teng
- Journal of the American Chemical Society, Vol. 138, Issue 10
Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes
journal, December 2010
- Ahuja, Ritu; Punji, Benudhar; Findlater, Michael
- Nature Chemistry, Vol. 3, Issue 2
Mechanistic Studies of the Transfer Dehydrogenation of Cyclooctane Catalyzed by Iridium Bis(phosphinite) p -XPCP Pincer Complexes
journal, August 2004
- Göttker-Schnetmann, Inigo; Brookhart, Maurice
- Journal of the American Chemical Society, Vol. 126, Issue 30
Design of a well-defined, silica-supported chiral Zn scaffold for enantioselective catalysis
journal, January 2010
- Ternel, Jérémy; Delevoye, Laurent; Agbossou-Niedercorn, Francine
- Dalton Transactions, Vol. 39, Issue 16
Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity
journal, September 2011
- Langer, Robert; Diskin-Posner, Yael; Leitus, Gregory
- Angewandte Chemie, Vol. 123, Issue 42
Handbook of Heterogeneous Catalysis
journal, January 1999
- Öhlmann, G.
- Zeitschrift für Physikalische Chemie, Vol. 208, Issue 1-2
Reactions of Anilines and Benzamides with a 14-Electron Iridium(I) Bis(phosphinite) Complex: N−H Oxidative Addition versus Lewis Base Coordination
text, January 2006
- Cartwright, Sykes, Alison; Peter, White,; Maurice, Brookhart,
- The University of North Carolina at Chapel Hill University Libraries
Alkane Metathesis by Tandem Alkane-Dehydrogenation–Olefin-Metathesis Catalysis and Related Chemistry
journal, January 2012
- Haibach, Michael C.; Kundu, Sabuj; Brookhart, Maurice
- Accounts of Chemical Research, Vol. 45, Issue 6
Silica-Grafted 16-Electron Hydride Pincer Complexes of Iridium(III) and Their Soluble Analogues: Synthesis and Reactivity with CO
journal, October 2014
- Rimoldi, Martino; Mezzetti, Antonio
- Inorganic Chemistry, Vol. 53, Issue 22
Iridium Bis(phosphinite) p -XPCP Pincer Complexes: Highly Active Catalysts for the Transfer Dehydrogenation of Alkanes
journal, February 2004
- Göttker-Schnetmann, Inigo; White, Peter; Brookhart, Maurice
- Journal of the American Chemical Society, Vol. 126, Issue 6
Mechanistic Studies of the Transfer Dehydrogenation of Cyclooctane Catalyzed by Iridium Bis(phosphinite) p -XPCP Pincer Complexes
journal, August 2004
- Göttker-Schnetmann, Inigo; Brookhart, Maurice
- Journal of the American Chemical Society, Vol. 126, Issue 30
Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium
journal, February 2013
- Lee, Chun-I; Zhou, Jia; Ozerov, Oleg V.
- Journal of the American Chemical Society, Vol. 135, Issue 9
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013
- Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
- Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013
- Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
- Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation
journal, March 2016
- Thacker, Nathan C.; Lin, Zekai; Zhang, Teng
- Journal of the American Chemical Society, Vol. 138, Issue 10
Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
journal, October 2014
- Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
Works referencing / citing this record:
Encapsulation of Crabtree's Catalyst in Sulfonated MIL-101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment
journal, March 2018
- Grigoropoulos, Alexios; McKay, Alasdair I.; Katsoulidis, Alexandros P.
- Angewandte Chemie International Edition, Vol. 57, Issue 17
X‐ray structure of host‐guest nanosized organotin supramolecular coordination polymer based on cobalt cyanide and quinoxaline as an efficient catalyst for treatment of waste water
journal, January 2020
- Etaiw, Safaa Eldin H.; Abd El‐Aziz, Dina M.; Shalaby, Elsayed M.
- Applied Organometallic Chemistry, Vol. 34, Issue 4
Fighting Deactivation: Classical and Emerging Strategies for Efficient Stabilization of Molecular Electrocatalysts
journal, January 2020
- Bairagya, Monojit Das; Bujol, Ryan J.; Elgrishi, Noémie
- Chemistry – A European Journal
Single‐Site Ruthenium Pincer Complex Knitted into Porous Organic Polymers for Dehydrogenation of Formic Acid
journal, September 2018
- Wang, Xinbo; Ling, Eleanor Ang Pei; Guan, Chao
- ChemSusChem, Vol. 11, Issue 20
Rational design of a flu -type heterometallic cluster-based Zr-MOF
journal, January 2016
- Tan, Yan-Xi; Yang, Xue; Li, Bei-Bei
- Chemical Communications, Vol. 52, Issue 94
Stable metal–organic frameworks as a host platform for catalysis and biomimetics
journal, January 2018
- Qin, Jun-Sheng; Yuan, Shuai; Lollar, Christina
- Chemical Communications, Vol. 54, Issue 34
A mesoporous NNN-pincer-based metal–organic framework scaffold for the preparation of noble-metal-free catalysts
journal, January 2019
- Zhang, Yingmu; Li, Jialuo; Yang, Xinyu
- Chemical Communications, Vol. 55, Issue 14
A polystyrene supported [PdCl–(SeCSe)] complex: a novel, reusable and robust heterogeneous catalyst for the Sonogashira synthesis of 1,2-disubstituted alkynes and 1,3-enynes
journal, January 2018
- Mohammadi, Elmira; Movassagh, Barahman
- New Journal of Chemistry, Vol. 42, Issue 14
NanoMOFs: little crystallites for substantial applications
journal, January 2018
- Majewski, M. B.; Noh, H.; Islamoglu, T.
- Journal of Materials Chemistry A, Vol. 6, Issue 17
Alterations to secondary building units of metal–organic frameworks for the development of new functions
journal, January 2020
- Ha, Junsu; Lee, Jae Hwa; Moon, Hoi Ri
- Inorganic Chemistry Frontiers, Vol. 7, Issue 1
Encapsulation of Crabtree's Catalyst in Sulfonated MIL-101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment
journal, March 2018
- Grigoropoulos, Alexios; McKay, Alasdair I.; Katsoulidis, Alexandros P.
- Angewandte Chemie, Vol. 130, Issue 17