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Title: A Systematic Approach to Achieving High Performance Hybrid Lighting Phosphors with Excellent Thermal- and Photostability

We have designed and synthesized a family of high-performance inorganic-organic hybrid phosphor materials composed of extended and robust networks of one-, two- and three-dimensions. Following a bottom-up solution-based synthetic approach, these structures are constructed by connecting highly emissive Cu 4I 4 cubic clusters via carefully selected ligands that form strong Cu-N bonds. They emit intensive yellow-orange light with high luminescence quantum efficiency, coupled with large Stokes shift which greatly reduces self-absorption. They also demonstrate exceptionally high framework- and photo-stability, comparable to those of commercial phosphors. The high stabilities are the result of significantly enhanced Cu-N bonds, as confirmed by the DFT binding energy and electron density calculations. Possible emission mechanisms are analyzed based on the results of theoretical calculations and optical experiments. Two-component white phosphors obtained by blending blue and yellow emitters reach an internal quantum yield (IQY) as high as 82% and correlated color temperature (CCT) as low as 2534 K. The performance level of this sub-family exceeds all other types of Cu-I based hybrid systems. The combined advantages make them excellent candidates as alternative rare-earth element (REE) free phosphors for possible use in energy-efficient lighting devices.
Authors:
 [1] ;  [1] ;  [2] ;  [3] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1]
  1. Rutgers Univ., Piscataway, NJ (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  3. George Washington Univ., Washington, DC (United States). IMPACT
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Volume: 27; Journal Issue: 3; Journal ID: ISSN 1616-301X
Publisher:
Wiley
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE
OSTI Identifier:
1436618

Fang, Yang, Liu, Wei, Teat, Simon J., Dey, Gangotri, Shen, Zeqing, An, Litao, Yu, Dechao, Wang, Lu, O'Carroll, Deirdre M., and Li, Jing. A Systematic Approach to Achieving High Performance Hybrid Lighting Phosphors with Excellent Thermal- and Photostability. United States: N. p., Web. doi:10.1002/adfm.201603444.
Fang, Yang, Liu, Wei, Teat, Simon J., Dey, Gangotri, Shen, Zeqing, An, Litao, Yu, Dechao, Wang, Lu, O'Carroll, Deirdre M., & Li, Jing. A Systematic Approach to Achieving High Performance Hybrid Lighting Phosphors with Excellent Thermal- and Photostability. United States. doi:10.1002/adfm.201603444.
Fang, Yang, Liu, Wei, Teat, Simon J., Dey, Gangotri, Shen, Zeqing, An, Litao, Yu, Dechao, Wang, Lu, O'Carroll, Deirdre M., and Li, Jing. 2016. "A Systematic Approach to Achieving High Performance Hybrid Lighting Phosphors with Excellent Thermal- and Photostability". United States. doi:10.1002/adfm.201603444. https://www.osti.gov/servlets/purl/1436618.
@article{osti_1436618,
title = {A Systematic Approach to Achieving High Performance Hybrid Lighting Phosphors with Excellent Thermal- and Photostability},
author = {Fang, Yang and Liu, Wei and Teat, Simon J. and Dey, Gangotri and Shen, Zeqing and An, Litao and Yu, Dechao and Wang, Lu and O'Carroll, Deirdre M. and Li, Jing},
abstractNote = {We have designed and synthesized a family of high-performance inorganic-organic hybrid phosphor materials composed of extended and robust networks of one-, two- and three-dimensions. Following a bottom-up solution-based synthetic approach, these structures are constructed by connecting highly emissive Cu4I4 cubic clusters via carefully selected ligands that form strong Cu-N bonds. They emit intensive yellow-orange light with high luminescence quantum efficiency, coupled with large Stokes shift which greatly reduces self-absorption. They also demonstrate exceptionally high framework- and photo-stability, comparable to those of commercial phosphors. The high stabilities are the result of significantly enhanced Cu-N bonds, as confirmed by the DFT binding energy and electron density calculations. Possible emission mechanisms are analyzed based on the results of theoretical calculations and optical experiments. Two-component white phosphors obtained by blending blue and yellow emitters reach an internal quantum yield (IQY) as high as 82% and correlated color temperature (CCT) as low as 2534 K. The performance level of this sub-family exceeds all other types of Cu-I based hybrid systems. The combined advantages make them excellent candidates as alternative rare-earth element (REE) free phosphors for possible use in energy-efficient lighting devices.},
doi = {10.1002/adfm.201603444},
journal = {Advanced Functional Materials},
number = 3,
volume = 27,
place = {United States},
year = {2016},
month = {12}
}

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