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Title: Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors

Here, energy-efficient solid-state-lighting (SSL) technologies are rapidly developing, but the lack of stable, high-performance rare-earth free phosphors may impede the growth of the SSL market. One possible alternative is organic phosphor materials, but these can suffer from lower quantum yields and thermal instability compared to rare-earth phosphors. However, if luminescent organic chromophores can be built into a rigid metal-organic framework, their quantum yields and thermal stability can be greatly improved. This Forum Article discusses the design of a group of such chromophore-based luminescent metal-organic frameworks with exceptionally high performance and rational control of the important parameters that influence their emission properties, including electronic structures of chromophore, coligands, metal ions, and guest molecule s.
Authors:
 [1] ;  [1] ;  [2] ;  [1] ;  [1] ;  [1]
  1. Rutgers Univ., Piscataway, NJ (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Accepted Manuscript
Journal Name:
Inorganic Chemistry
Additional Journal Information:
Journal Volume: 55; Journal Issue: 15; Journal ID: ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1436596

Lustig, William P., Wang, Fangming, Teat, Simon J., Hu, Zhichao, Gong, Qihan, and Li, Jing. Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors. United States: N. p., Web. doi:10.1021/acs.inorgchem.6b00897.
Lustig, William P., Wang, Fangming, Teat, Simon J., Hu, Zhichao, Gong, Qihan, & Li, Jing. Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors. United States. doi:10.1021/acs.inorgchem.6b00897.
Lustig, William P., Wang, Fangming, Teat, Simon J., Hu, Zhichao, Gong, Qihan, and Li, Jing. 2016. "Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors". United States. doi:10.1021/acs.inorgchem.6b00897. https://www.osti.gov/servlets/purl/1436596.
@article{osti_1436596,
title = {Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors},
author = {Lustig, William P. and Wang, Fangming and Teat, Simon J. and Hu, Zhichao and Gong, Qihan and Li, Jing},
abstractNote = {Here, energy-efficient solid-state-lighting (SSL) technologies are rapidly developing, but the lack of stable, high-performance rare-earth free phosphors may impede the growth of the SSL market. One possible alternative is organic phosphor materials, but these can suffer from lower quantum yields and thermal instability compared to rare-earth phosphors. However, if luminescent organic chromophores can be built into a rigid metal-organic framework, their quantum yields and thermal stability can be greatly improved. This Forum Article discusses the design of a group of such chromophore-based luminescent metal-organic frameworks with exceptionally high performance and rational control of the important parameters that influence their emission properties, including electronic structures of chromophore, coligands, metal ions, and guest molecule s.},
doi = {10.1021/acs.inorgchem.6b00897},
journal = {Inorganic Chemistry},
number = 15,
volume = 55,
place = {United States},
year = {2016},
month = {5}
}