Anisotropic magnetocaloric response in AlFe2B2

Barua, R.; Lejeune, B. T.; Ke, L.; Hadjipanayis, G.; Levin, E. M.; McCallum, R. W.; Kramer, M. J.; Lewis, L. H.

doi:10.1016/j.jallcom.2018.02.205

Title: Anisotropic magnetocaloric response in AlFe₂B₂

Journal Article · 18 February 2018 · Journal of Alloys and Compounds

DOI: https://doi.org/10.1016/j.jallcom.2018.02.205 · OSTI ID:1436423

^[1]; Lejeune, B. T. ^[1]; Ke, L. ^[2]; Hadjipanayis, G. ^[3]; Levin, E. M. ^[4];

^[5]; Kramer, M. J. ^[2]; Lewis, L. H. ^[6]

Northeastern Univ., Boston, MA (United States). College of Engineering
Ames Lab., Ames, IA (United States). Division of Materials Science & Engineering
Univ. of Delaware, Newark, DE (United States). Dept. of Physics and Astronomy
Ames Lab., Ames, IA (United States). Division of Materials Science & Engineering; Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy
McCallum Consulting LLC, Santa Fe, NM (United States)
Northeastern Univ., Boston, MA (United States). College of Engineering; Northeastern Univ., Boston, MA (United States). Mechanical Engineering

Experimental investigations of the magnetocaloric response of the intermetallic layered AlFe₂B₂ compound along the principle axes of the orthorhombic cell were carried out using aligned plate-like crystallites with an anisotropic [101] growth habit. Results were confirmed to be consistent with density functional theory calculations. Field-dependent magnetization data confirm that the a-axis is the easy direction of magnetization within the (ac) plane. The magnetocrystalline anisotropy energy required to rotate the spin quantization vector from the c-to the a-axis direction is determined as K~0.9 MJ/m³ at 50 K. Magnetic entropy change curves measured near the Curie transition temperature of 285 K reveal a large rotating magnetic entropy change of 1.3 J kg^-1K^-1 at μ₀H_app = 2 T, consistent with large differences in magnetic entropy change ΔS_mag measured along the a- and c-axes. Overall, this study provides insight of both fundamental and applied relevance concerning pathways for maximizing the magnetocaloric potential of AlFe₂B₂ for thermal management applications.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1436423

Report Number(s):: IS-J--9650; PII: S0925838818306923

Journal Information:: Journal of Alloys and Compounds, Journal Name: Journal of Alloys and Compounds Journal Issue: C Vol. 745; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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