skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Importance of Electronic Correlations and Unusual Excitonic Effects in Formamidinium Lead Halide Perovskites

Authors:
; ; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1436391
Grant/Contract Number:  
R-144-000-379-114; R-144-000-368-112
Resource Type:
Published Article
Journal Name:
Physical Review X
Additional Journal Information:
Journal Name: Physical Review X Journal Volume: 8 Journal Issue: 2; Journal ID: ISSN 2160-3308
Publisher:
American Physical Society
Country of Publication:
United States
Language:
English

Citation Formats

Whitcher, T. J., Zhu, J. -X., Chi, X., Hu, H., Zhao, Daming, Asmara, T. C., Yu, X., Breese, M. B. H., Castro Neto, A. H., Lam, Y. M., Wee, A. T. S., Chia, Elbert E. M., and Rusydi, A. Importance of Electronic Correlations and Unusual Excitonic Effects in Formamidinium Lead Halide Perovskites. United States: N. p., 2018. Web. https://doi.org/10.1103/PhysRevX.8.021034.
Whitcher, T. J., Zhu, J. -X., Chi, X., Hu, H., Zhao, Daming, Asmara, T. C., Yu, X., Breese, M. B. H., Castro Neto, A. H., Lam, Y. M., Wee, A. T. S., Chia, Elbert E. M., & Rusydi, A. Importance of Electronic Correlations and Unusual Excitonic Effects in Formamidinium Lead Halide Perovskites. United States. https://doi.org/10.1103/PhysRevX.8.021034
Whitcher, T. J., Zhu, J. -X., Chi, X., Hu, H., Zhao, Daming, Asmara, T. C., Yu, X., Breese, M. B. H., Castro Neto, A. H., Lam, Y. M., Wee, A. T. S., Chia, Elbert E. M., and Rusydi, A. Tue . "Importance of Electronic Correlations and Unusual Excitonic Effects in Formamidinium Lead Halide Perovskites". United States. https://doi.org/10.1103/PhysRevX.8.021034.
@article{osti_1436391,
title = {Importance of Electronic Correlations and Unusual Excitonic Effects in Formamidinium Lead Halide Perovskites},
author = {Whitcher, T. J. and Zhu, J. -X. and Chi, X. and Hu, H. and Zhao, Daming and Asmara, T. C. and Yu, X. and Breese, M. B. H. and Castro Neto, A. H. and Lam, Y. M. and Wee, A. T. S. and Chia, Elbert E. M. and Rusydi, A.},
abstractNote = {},
doi = {10.1103/PhysRevX.8.021034},
journal = {Physical Review X},
number = 2,
volume = 8,
place = {United States},
year = {2018},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1103/PhysRevX.8.021034

Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Electronic band structure trends of perovskite halides: Beyond Pb and Sn to Ge and Si
journal, May 2016


Modeling of Lead Halide Perovskites for Photovoltaic Applications
journal, November 2014

  • Jishi, Radi A.; Ta, Oliver B.; Sharif, Adel A.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 49
  • DOI: 10.1021/jp5050145

NH 2 CH═NH 2 PbI 3 : An Alternative Organolead Iodide Perovskite Sensitizer for Mesoscopic Solar Cells
journal, January 2014

  • Pang, Shuping; Hu, Hao; Zhang, Jiliang
  • Chemistry of Materials, Vol. 26, Issue 3
  • DOI: 10.1021/cm404006p

Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013

  • Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
  • Nature, Vol. 499, Issue 7458, p. 316-319
  • DOI: 10.1038/nature12340

Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance
journal, March 2014

  • De Wolf, Stefaan; Holovsky, Jakub; Moon, Soo-Jin
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 6
  • DOI: 10.1021/jz500279b

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors
journal, May 2013

  • Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong
  • Nature Photonics, Vol. 7, Issue 6, p. 486-491
  • DOI: 10.1038/nphoton.2013.80

Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites
journal, June 2015

  • Miyata, Atsuhiko; Mitioglu, Anatolie; Plochocka, Paulina
  • Nature Physics, Vol. 11, Issue 7
  • DOI: 10.1038/nphys3357

Metal-insulator transition in manganites: Changes in optical conductivity up to 22 eV
journal, September 2008


Excitons versus free charges in organo-lead tri-halide perovskites
journal, April 2014

  • D’Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4586

Formamidinium-Containing Metal-Halide: An Alternative Material for Near-IR Absorption Perovskite Solar Cells
journal, December 2013

  • Koh, Teck Ming; Fu, Kunwu; Fang, Yanan
  • The Journal of Physical Chemistry C, Vol. 118, Issue 30
  • DOI: 10.1021/jp411112k

Cesium Enhances Long-Term Stability of Lead Bromide Perovskite-Based Solar Cells
journal, December 2015

  • Kulbak, Michael; Gupta, Satyajit; Kedem, Nir
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 1
  • DOI: 10.1021/acs.jpclett.5b02597

Cesium Lead Halide Perovskites with Improved Stability for Tandem Solar Cells
journal, February 2016

  • Beal, Rachel E.; Slotcavage, Daniel J.; Leijtens, Tomas
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 5
  • DOI: 10.1021/acs.jpclett.6b00002

Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells
journal, January 2014

  • Eperon, Giles E.; Stranks, Samuel D.; Menelaou, Christopher
  • Energy & Environmental Science, Vol. 7, Issue 3
  • DOI: 10.1039/c3ee43822h

Complex Refractive Index Spectra of CH 3 NH 3 PbI 3 Perovskite Thin Films Determined by Spectroscopic Ellipsometry and Spectrophotometry
journal, December 2014

  • Löper, Philipp; Stuckelberger, Michael; Niesen, Bjoern
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 1
  • DOI: 10.1021/jz502471h

Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

  • Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
  • Nature, Vol. 501, Issue 7467, p. 395-398
  • DOI: 10.1038/nature12509

Dielectric study of CH3NH3PbX3 (X = Cl, Br, I)
journal, July 1992

  • Onoda-Yamamuro, Noriko; Matsuo, Takasuke; Suga, Hiroshi
  • Journal of Physics and Chemistry of Solids, Vol. 53, Issue 7
  • DOI: 10.1016/0022-3697(92)90121-S

Facet-dependent photovoltaic efficiency variations in single grains of hybrid halide perovskite
journal, July 2016


Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012


Emerging giant resonant exciton induced by Ta substitution in anatase TiO 2 : A tunable correlation effect
journal, May 2016


Evolution of the in-gap state in high- T c cuprates
journal, December 1992


Temperature dependence of hole conductor free formamidinium lead iodide perovskite based solar cells
journal, January 2015

  • Aharon, Sigalit; Dymshits, Alexander; Rotem, Amit
  • Journal of Materials Chemistry A, Vol. 3, Issue 17
  • DOI: 10.1039/C4TA05149A

Electrodynamics of correlated electron materials
journal, June 2011

  • Basov, D. N.; Averitt, Richard D.; van der Marel, Dirk
  • Reviews of Modern Physics, Vol. 83, Issue 2
  • DOI: 10.1103/RevModPhys.83.471

Elucidating the role of disorder and free-carrier recombination kinetics in CH3NH3PbI3 perovskite films
journal, July 2015

  • La-o-vorakiat, Chan; Salim, Teddy; Kadro, Jeannette
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8903

Spectral-weight transfer: Breakdown of low-energy-scale sum rules in correlated systems
journal, August 1993


Ab initiomolecular dynamics for liquid metals
journal, January 1993


A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells
journal, January 2016


Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance
journal, May 2014


Mott Transition in VO2 Revealed by Infrared Spectroscopy and Nano-Imaging
journal, December 2007


Formamidinium and Cesium Hybridization for Photo- and Moisture-Stable Perovskite Solar Cell
journal, September 2015

  • Lee, Jin-Wook; Kim, Deok-Hwan; Kim, Hui-Seon
  • Advanced Energy Materials, Vol. 5, Issue 20
  • DOI: 10.1002/aenm.201501310

Entropic stabilization of mixed A-cation ABX 3 metal halide perovskites for high performance perovskite solar cells
journal, January 2016

  • Yi, Chenyi; Luo, Jingshan; Meloni, Simone
  • Energy & Environmental Science, Vol. 9, Issue 2
  • DOI: 10.1039/C5EE03255E

Polaronic exciton binding energy in iodide and bromide organic-inorganic lead halide perovskites
journal, December 2015

  • Soufiani, Arman Mahboubi; Huang, Fuzhi; Reece, Peter
  • Applied Physics Letters, Vol. 107, Issue 23
  • DOI: 10.1063/1.4936418

Determination of the exciton binding energy and effective masses for methylammonium and formamidinium lead tri-halide perovskite semiconductors
journal, January 2016

  • Galkowski, Krzysztof; Mitioglu, Anatolie; Miyata, Atsuhiko
  • Energy & Environmental Science, Vol. 9, Issue 3
  • DOI: 10.1039/C5EE03435C

How Important Is the Organic Part of Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr 3 Cells
journal, June 2015

  • Kulbak, Michael; Cahen, David; Hodes, Gary
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 13
  • DOI: 10.1021/acs.jpclett.5b00968

First-Principles Study on Electronic Structures of FAPbX3 (X = Cl, Br, I) Hybrid Perovskites
journal, September 2016

  • Pan, Y. Y.; Su, Y. H.; Hsu, C. H.
  • Journal of Advances in Nanomaterials, Vol. 1, Issue 1
  • DOI: 10.22606/jan.2016.11004

Colloquium : Identifying the propagating charge modes in doped Mott insulators
journal, May 2010


Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%
journal, August 2012

  • Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok
  • Scientific Reports, Vol. 2, Issue 1
  • DOI: 10.1038/srep00591

Signatures of Electronic Correlations in Optical Properties of LaFeAsO 1 x F x
journal, January 2009


Cubic Perovskite Structure of Black Formamidinium Lead Iodide, α-[HC(NH 2 ) 2 ]PbI 3 , at 298 K
journal, July 2015

  • Weller, Mark T.; Weber, Oliver J.; Frost, Jarvist M.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 16
  • DOI: 10.1021/acs.jpclett.5b01432

Anomalous transfer of spectral weight in doped strongly correlated systems
journal, August 1991