Elucidating the alkaline oxygen evolution reaction mechanism on platinum
Abstract
Understanding the interplay between surface chemistry, electronic structure, and reaction mechanism of the catalyst at the electrified solid/liquid interface will enable the design of more efficient materials systems for sustainable energy production. The substantial progress in operando characterization, particularly using synchrotron based X-ray spectroscopies, provides the unprecedented opportunity to uncover surface chemical and structural transformations under various (electro)chemical reaction environments. In this work, we study a polycrystalline platinum surface under oxygen evolution conditions in an alkaline electrolyte by means of ambient pressure X-ray photoelectron spectroscopy performed at the electrified solid/liquid interface. We elucidate previously inaccessible aspects of the surface chemistry and structure as a function of the applied potential, allowing us to propose a reaction mechanism for oxygen evolution on a platinum electrode in alkaline solutions.
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source. Joint Center for Artificial Photosynthesis. Chemical Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source. Joint Center for Energy Storage Research
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Joint Center for Artificial Photosynthesis. Molecular Biophysics and Integrated Bioimaging Division
- Chinese Academy of Sciences (CAS), Shanghai (China). State Key Lab. of Functional Materials for Informatics. Shanghai Inst. of Microsystem and Information Technology; ShanghaiTech Univ. (China). Division of Condensed Matter Physics and Photon Science. School of Physical Science and Technology
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); LBNL Laboratory Directed Research and Development (LDRD) Program; National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1436336
- Grant/Contract Number:
- AC02-05CH11231; SC0004993; 11227902
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 23; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Favaro, M., Valero-Vidal, C., Eichhorn, J., Toma, F. M., Ross, P. N., Yano, J., Liu, Z., and Crumlin, E. J. Elucidating the alkaline oxygen evolution reaction mechanism on platinum. United States: N. p., 2017.
Web. doi:10.1039/c7ta00409e.
Favaro, M., Valero-Vidal, C., Eichhorn, J., Toma, F. M., Ross, P. N., Yano, J., Liu, Z., & Crumlin, E. J. Elucidating the alkaline oxygen evolution reaction mechanism on platinum. United States. https://doi.org/10.1039/c7ta00409e
Favaro, M., Valero-Vidal, C., Eichhorn, J., Toma, F. M., Ross, P. N., Yano, J., Liu, Z., and Crumlin, E. J. Tue .
"Elucidating the alkaline oxygen evolution reaction mechanism on platinum". United States. https://doi.org/10.1039/c7ta00409e. https://www.osti.gov/servlets/purl/1436336.
@article{osti_1436336,
title = {Elucidating the alkaline oxygen evolution reaction mechanism on platinum},
author = {Favaro, M. and Valero-Vidal, C. and Eichhorn, J. and Toma, F. M. and Ross, P. N. and Yano, J. and Liu, Z. and Crumlin, E. J.},
abstractNote = {Understanding the interplay between surface chemistry, electronic structure, and reaction mechanism of the catalyst at the electrified solid/liquid interface will enable the design of more efficient materials systems for sustainable energy production. The substantial progress in operando characterization, particularly using synchrotron based X-ray spectroscopies, provides the unprecedented opportunity to uncover surface chemical and structural transformations under various (electro)chemical reaction environments. In this work, we study a polycrystalline platinum surface under oxygen evolution conditions in an alkaline electrolyte by means of ambient pressure X-ray photoelectron spectroscopy performed at the electrified solid/liquid interface. We elucidate previously inaccessible aspects of the surface chemistry and structure as a function of the applied potential, allowing us to propose a reaction mechanism for oxygen evolution on a platinum electrode in alkaline solutions.},
doi = {10.1039/c7ta00409e},
journal = {Journal of Materials Chemistry. A},
number = 23,
volume = 5,
place = {United States},
year = {Tue Mar 07 00:00:00 EST 2017},
month = {Tue Mar 07 00:00:00 EST 2017}
}
Web of Science
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