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Title: In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation

Abstract

In operando XRD and TXM-XANES approaches demonstrate that structure evolution in NaNi1/3Fe1/3Mn1/3O2 during cycling follows a continuous change, and the formation of a nonequilibrium solid solution phase in the existence of two phases. Here, an O3' and P3' monoclinic phase occur, and redox couples of Ni3+/Ni4+ and Fe3+/Fe4+ are mainly responsible in the charge voltage range from 4.0 to 4.3 V.

Authors:
 [1];  [2];  [3];  [4];  [5];  [3];  [6];  [6];  [5];  [4];  [5];  [3];  [3];  [2]
  1. Shanghai Jiao Tong Univ. (China). Dept. of Chemical Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Shanghai Jiao Tong Univ. (China). Dept. of Chemical Engineering
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Photon Sciences Directorate
  5. Argonne National Lab. (ANL), Argonne, IL (United States). Electron Microscopy Center-Center for Nanoscale Materials
  6. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NNSFC)
OSTI Identifier:
1436248
Report Number(s):
BNL-203469-2018-JAAM
Journal ID: ISSN 1614-6832
Grant/Contract Number:  
SC0012704; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 6; Journal Issue: 24; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, and Ma, Zi-Feng. In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation. United States: N. p., 2016. Web. doi:10.1002/aenm.201601306.
Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, & Ma, Zi-Feng. In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation. United States. doi:10.1002/aenm.201601306.
Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, and Ma, Zi-Feng. Fri . "In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation". United States. doi:10.1002/aenm.201601306. https://www.osti.gov/servlets/purl/1436248.
@article{osti_1436248,
title = {In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation},
author = {Xie, Yingying and Wang, Hong and Xu, Guiliang and Wang, Jiajun and Sheng, Huaping and Chen, Zonghai and Ren, Yang and Sun, Cheng-Jun and Wen, Jianguo and Wang, Jun and Miller, Dean J. and Lu, Jun and Amine, Khalil and Ma, Zi-Feng},
abstractNote = {In operando XRD and TXM-XANES approaches demonstrate that structure evolution in NaNi1/3Fe1/3Mn1/3O2 during cycling follows a continuous change, and the formation of a nonequilibrium solid solution phase in the existence of two phases. Here, an O3' and P3' monoclinic phase occur, and redox couples of Ni3+/Ni4+ and Fe3+/Fe4+ are mainly responsible in the charge voltage range from 4.0 to 4.3 V.},
doi = {10.1002/aenm.201601306},
journal = {Advanced Energy Materials},
number = 24,
volume = 6,
place = {United States},
year = {2016},
month = {9}
}

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Works referenced in this record:

Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012

  • Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo
  • Nature Materials, Vol. 11, Issue 11
  • DOI: 10.1038/nmat3435

Probing three-dimensional sodiation–desodiation equilibrium in sodium-ion batteries by in situ hard X-ray nanotomography
journal, June 2015

  • Wang, Jiajun; Eng, Christopher; Chen-Wiegart, Yu-chen Karen
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8496

Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010

  • Berthelot, R.; Carlier, D.; Delmas, C.
  • Nature Materials, Vol. 10, Issue 1
  • DOI: 10.1038/nmat2920

Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011

  • Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
  • Advanced Functional Materials, Vol. 21, Issue 20
  • DOI: 10.1002/adfm.201100854

Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode
journal, October 2015


The P2-Na2/3Co2/3Mn1/3O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery
journal, January 2011

  • Carlier, D.; Cheng, J. H.; Berthelot, R.
  • Dalton Transactions, Vol. 40, Issue 36
  • DOI: 10.1039/c1dt10798d

Electrochemical intercalation of sodium in NaxCoO2 bronzes
journal, August 1981


Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life
journal, June 2011

  • Cao, Yuliang; Xiao, Lifen; Wang, Wei
  • Advanced Materials, Vol. 23, Issue 28, p. 3155-3160
  • DOI: 10.1002/adma.201100904

Prussian blue without coordinated water as a superior cathode for sodium-ion batteries
journal, January 2015

  • Yang, Dezhi; Xu, Jing; Liao, Xiao-Zhen
  • Chemical Communications, Vol. 51, Issue 38
  • DOI: 10.1039/C5CC01180A

Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes
journal, June 2014


Large-Scale Synthesis of NaNi 1/3 Fe 1/3 Mn 1/3 O 2 as High Performance Cathode Materials for Sodium Ion Batteries
journal, January 2016

  • Wang, Hong; Liao, Xiao-Zhen; Yang, Yang
  • Journal of The Electrochemical Society, Vol. 163, Issue 3
  • DOI: 10.1149/2.0011605jes

O3–Na x Mn 1/3 Fe 2/3 O 2 as a positive electrode material for Na-ion batteries: structural evolutions and redox mechanisms upon Na + (de)intercalation
journal, January 2015

  • Mortemard de Boisse, B.; Cheng, J. -H.; Carlier, D.
  • Journal of Materials Chemistry A, Vol. 3, Issue 20
  • DOI: 10.1039/C4TA06688J

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013

  • Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
  • Energy & Environmental Science, Vol. 6, Issue 8
  • DOI: 10.1039/c3ee40847g

Prussian blue: a new framework of electrode materials for sodium batteries
journal, January 2012

  • Lu, Yuhao; Wang, Long; Cheng, Jinguang
  • Chemical Communications, Vol. 48, Issue 52, p. 6544-6546
  • DOI: 10.1039/c2cc31777j

Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes
journal, February 2011

  • Kim, Donghan; Kang, Sun-Ho; Slater, Michael
  • Advanced Energy Materials, Vol. 1, Issue 3, p. 333-336
  • DOI: 10.1002/aenm.201000061

Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application
journal, January 2012


P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012

  • Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
  • Nature Materials, Vol. 11, Issue 6
  • DOI: 10.1038/nmat3309

Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi 1 / 3 Mn 1 / 3 Co 1 / 3 O 2
journal, April 2012

  • Sathiya, M.; Hemalatha, K.; Ramesha, K.
  • Chemistry of Materials, Vol. 24, Issue 10
  • DOI: 10.1021/cm300466b

A thermodynamic study of sodium-intercalated TaS2 and TiS2
journal, September 1979


O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries
journal, December 2014


New Insights into the Performance Degradation of Fe-Based Layered Oxides in Sodium-Ion Batteries: Instability of Fe 3+ /Fe 4+ Redox in α-NaFeO 2
journal, September 2015


Advanced Na[Ni 0.25 Fe 0.5 Mn 0.25 ]O 2 /C–Fe 3 O 4 Sodium-Ion Batteries Using EMS Electrolyte for Energy Storage
journal, February 2014

  • Oh, Seung-Min; Myung, Seung-Taek; Yoon, Chong Seung
  • Nano Letters, Vol. 14, Issue 3
  • DOI: 10.1021/nl500077v

Study of Thermal Decomposition of Li 1-x (Ni 1/3 Mn 1/3 Co 1/3 ) 0.9 O 2 Using In-Situ High-Energy X-Ray Diffraction
journal, March 2013

  • Chen, Zonghai; Ren, Yang; Lee, Eungje
  • Advanced Energy Materials, Vol. 3, Issue 6
  • DOI: 10.1002/aenm.201201059

In operando tracking phase transformation evolution of lithium iron phosphate with hard X-ray microscopy
journal, August 2014

  • Wang, Jiajun; Chen-Wiegart, Yu-chen Karen; Wang, Jun
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5570

    Works referencing / citing this record:

    Ni-based cathode materials for Na-ion batteries
    journal, June 2019


    Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy
    journal, July 2019

    • Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue
    • Batteries & Supercaps, Vol. 2, Issue 10
    • DOI: 10.1002/batt.201900054

    Ti-Substituted NaNi 0.5 Mn 0.5- x Ti x O 2 Cathodes with Reversible O3−P3 Phase Transition for High-Performance Sodium-Ion Batteries
    journal, March 2017


    A Stable Layered Oxide Cathode Material for High‐Performance Sodium‐Ion Battery
    journal, March 2019

    • Xiao, Yao; Zhu, Yan‐Fang; Yao, Hu‐Rong
    • Advanced Energy Materials, Vol. 9, Issue 19
    • DOI: 10.1002/aenm.201803978

    Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy
    journal, July 2019

    • Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue
    • Batteries & Supercaps, Vol. 2, Issue 10
    • DOI: 10.1002/batt.201900054

    Ni-based cathode materials for Na-ion batteries
    journal, June 2019