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Title: In Operando XRD and TXM Study on the Metastable Structure Change of NaNi 1/3Fe 1/3Mn 1/3O 2 under Electrochemical Sodium-Ion Intercalation

Abstract

In operando XRD and TXM-XANES approaches demonstrate that structure evolution in NaNi 1/3Fe 1/3Mn 1/3O 2 during cycling follows a continuous change, and the formation of a nonequilibrium solid solution phase in the existence of two phases. Here, an O3' and P3' monoclinic phase occur, and redox couples of Ni 3+/Ni 4+ and Fe 3+/Fe 4+ are mainly responsible in the charge voltage range from 4.0 to 4.3 V.

Authors:
 [1];  [2];  [3];  [4];  [5];  [3];  [6];  [6];  [5];  [4];  [5];  [3];  [3];  [2]
  1. Shanghai Jiao Tong Univ. (China). Dept. of Chemical Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Shanghai Jiao Tong Univ. (China). Dept. of Chemical Engineering
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Photon Sciences Directorate
  5. Argonne National Lab. (ANL), Argonne, IL (United States). Electron Microscopy Center-Center for Nanoscale Materials
  6. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NNSFC)
OSTI Identifier:
1436248
Report Number(s):
BNL-203469-2018-JAAM
Journal ID: ISSN 1614-6832
Grant/Contract Number:  
SC0012704; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 6; Journal Issue: 24; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, and Ma, Zi-Feng. In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation. United States: N. p., 2016. Web. doi:10.1002/aenm.201601306.
Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, & Ma, Zi-Feng. In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation. United States. doi:10.1002/aenm.201601306.
Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, and Ma, Zi-Feng. Fri . "In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation". United States. doi:10.1002/aenm.201601306. https://www.osti.gov/servlets/purl/1436248.
@article{osti_1436248,
title = {In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation},
author = {Xie, Yingying and Wang, Hong and Xu, Guiliang and Wang, Jiajun and Sheng, Huaping and Chen, Zonghai and Ren, Yang and Sun, Cheng-Jun and Wen, Jianguo and Wang, Jun and Miller, Dean J. and Lu, Jun and Amine, Khalil and Ma, Zi-Feng},
abstractNote = {In operando XRD and TXM-XANES approaches demonstrate that structure evolution in NaNi1/3Fe1/3Mn1/3O2 during cycling follows a continuous change, and the formation of a nonequilibrium solid solution phase in the existence of two phases. Here, an O3' and P3' monoclinic phase occur, and redox couples of Ni3+/Ni4+ and Fe3+/Fe4+ are mainly responsible in the charge voltage range from 4.0 to 4.3 V.},
doi = {10.1002/aenm.201601306},
journal = {Advanced Energy Materials},
number = 24,
volume = 6,
place = {United States},
year = {2016},
month = {9}
}

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Works referenced in this record:

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