Disentangling Strong-Field Multielectron Dynamics with Angular Streaking
Abstract
The study into the interaction between a strong laser field and atoms/molecules has led to significant advances in developing spectroscopic tools in the attosecond time-domain and methods for controlling chemical reactions. There has been great interest in understanding the complex electronic and nuclear dynamics of molecules in strong laser fields. However, it is still a formidable challenge to fully model such dynamics. Conventional experimental tools such as photoelectron spectroscopy encounter difficulties in revealing the involved states because the electron spectra are largely dictated by the property of the laser field. Here, with strong field angular streaking technique, we measure the angle-dependent ionization yields that directly reflect the symmetry of the ionizing orbitals of methyl iodide and thus reveal the ionization/dissociation dynamics. Moreover, kinematically complete measurements of momentum vectors of all fragments in dissociative double ionization processes allow access to electron-momentum correlations that reveal correlated multielectron dynamics.
- Authors:
-
[1];
[1];
[1];
[1]
- Department of Chemistry, Wayne State University, Detroit, Michigan 48202, United States
- Publication Date:
- Research Org.:
- Wayne State Univ., Detroit, MI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), U.S. Army Research Office
- OSTI Identifier:
- 1436188
- Alternate Identifier(s):
- OSTI ID: 1508823
- Grant/Contract Number:
- SC0012628; W911NF-12-1-0598
- Resource Type:
- Published Article
- Journal Name:
- Journal of Physical Chemistry Letters
- Additional Journal Information:
- Journal Name: Journal of Physical Chemistry Letters Journal Volume: 9 Journal Issue: 10; Journal ID: ISSN 1948-7185
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Winney, Alexander H., Basnayake, Gihan, Debrah, Duke A., Lin, Yun Fei, Lee, Suk Kyoung, Hoerner, Paul, Liao, Qing, Schlegel, H. Bernhard, and Li, Wen. Disentangling Strong-Field Multielectron Dynamics with Angular Streaking. United States: N. p., 2018.
Web. doi:10.1021/acs.jpclett.8b00028.
Winney, Alexander H., Basnayake, Gihan, Debrah, Duke A., Lin, Yun Fei, Lee, Suk Kyoung, Hoerner, Paul, Liao, Qing, Schlegel, H. Bernhard, & Li, Wen. Disentangling Strong-Field Multielectron Dynamics with Angular Streaking. United States. https://doi.org/10.1021/acs.jpclett.8b00028
Winney, Alexander H., Basnayake, Gihan, Debrah, Duke A., Lin, Yun Fei, Lee, Suk Kyoung, Hoerner, Paul, Liao, Qing, Schlegel, H. Bernhard, and Li, Wen. Fri .
"Disentangling Strong-Field Multielectron Dynamics with Angular Streaking". United States. https://doi.org/10.1021/acs.jpclett.8b00028.
@article{osti_1436188,
title = {Disentangling Strong-Field Multielectron Dynamics with Angular Streaking},
author = {Winney, Alexander H. and Basnayake, Gihan and Debrah, Duke A. and Lin, Yun Fei and Lee, Suk Kyoung and Hoerner, Paul and Liao, Qing and Schlegel, H. Bernhard and Li, Wen},
abstractNote = {The study into the interaction between a strong laser field and atoms/molecules has led to significant advances in developing spectroscopic tools in the attosecond time-domain and methods for controlling chemical reactions. There has been great interest in understanding the complex electronic and nuclear dynamics of molecules in strong laser fields. However, it is still a formidable challenge to fully model such dynamics. Conventional experimental tools such as photoelectron spectroscopy encounter difficulties in revealing the involved states because the electron spectra are largely dictated by the property of the laser field. Here, with strong field angular streaking technique, we measure the angle-dependent ionization yields that directly reflect the symmetry of the ionizing orbitals of methyl iodide and thus reveal the ionization/dissociation dynamics. Moreover, kinematically complete measurements of momentum vectors of all fragments in dissociative double ionization processes allow access to electron-momentum correlations that reveal correlated multielectron dynamics.},
doi = {10.1021/acs.jpclett.8b00028},
journal = {Journal of Physical Chemistry Letters},
number = 10,
volume = 9,
place = {United States},
year = {Fri Apr 27 00:00:00 EDT 2018},
month = {Fri Apr 27 00:00:00 EDT 2018}
}
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https://doi.org/10.1021/acs.jpclett.8b00028
https://doi.org/10.1021/acs.jpclett.8b00028
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Cited by: 25 works
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Figures / Tables:
Figure 1: (a) Recoil-frame electron momentum distribution obtained by coincidence measurements of electrons and I+ for the dissociative single ionization of CH3I. The I+ recoil momentum is pointed up, indicated by the white arrow and the yellow curved arrow shows the helicity of the circularly polarized light. (b) RFPADs formore »
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