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Title: Solvent Dependent Disorder in M2(BzOip)2(H2O)·Solvate (M = Co or Zn)

Abstract

Coordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip and M(OAc)2 (M = Co and Zn), from water to a water/alcohol mixture, coordination polymers of different topology could be formed. Instead, two polymorphs of the existing M2(BzOip)2(H2O) (M = Co and Zn) were isolated from aqueous methanol and aqueous ethanol, in which a small number of guest solvent molecules are present in the crystals. These guest water molecules disrupt the hexaphenyl embrace motif, leading to varying degrees of disorder of the benzyl groups.

Authors:
 [1];  [2];  [3];  [4];  [4]
+ Show Author Affiliations
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Univ. of St. Andrews, St. Andrews (United Kingdom). School of Chemistry
  2. Univ. of St. Andrews, St. Andrews (United Kingdom). School of Chemistry; Nanyang Technological Univ. (Singapore). Facility for Analysis, Characterisation, Testing and Simulation
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  4. Univ. of St. Andrews, St. Andrews (United Kingdom). School of Chemistry
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC); British Heart Foundation
OSTI Identifier:
1436166
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Crystals
Additional Journal Information:
Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2073-4352
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; X-ray crystallography; solvothermal; polymorph; disorder

Citation Formats

McCormick, Laura, Morris, Samuel A., Teat, Simon J., Slawin, Alexandra M. Z., and Morris, Russell E. Solvent Dependent Disorder in M2(BzOip)2(H2O)·Solvate (M = Co or Zn). United States: N. p., 2017. Web. doi:10.3390/cryst8010006.
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McCormick, Laura, Morris, Samuel A., Teat, Simon J., Slawin, Alexandra M. Z., & Morris, Russell E. Solvent Dependent Disorder in M2(BzOip)2(H2O)·Solvate (M = Co or Zn). United States. https://doi.org/10.3390/cryst8010006
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McCormick, Laura, Morris, Samuel A., Teat, Simon J., Slawin, Alexandra M. Z., and Morris, Russell E. Sun . "Solvent Dependent Disorder in M2(BzOip)2(H2O)·Solvate (M = Co or Zn)". United States. https://doi.org/10.3390/cryst8010006. https://www.osti.gov/servlets/purl/1436166.
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@article{osti_1436166,
title = {Solvent Dependent Disorder in M2(BzOip)2(H2O)·Solvate (M = Co or Zn)},
author = {McCormick, Laura and Morris, Samuel A. and Teat, Simon J. and Slawin, Alexandra M. Z. and Morris, Russell E.},
abstractNote = {Coordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip and M(OAc)2 (M = Co and Zn), from water to a water/alcohol mixture, coordination polymers of different topology could be formed. Instead, two polymorphs of the existing M2(BzOip)2(H2O) (M = Co and Zn) were isolated from aqueous methanol and aqueous ethanol, in which a small number of guest solvent molecules are present in the crystals. These guest water molecules disrupt the hexaphenyl embrace motif, leading to varying degrees of disorder of the benzyl groups.},
doi = {10.3390/cryst8010006},
journal = {Crystals},
number = 1,
volume = 8,
place = {United States},
year = {Sun Dec 24 00:00:00 EST 2017},
month = {Sun Dec 24 00:00:00 EST 2017}
}
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https://doi.org/10.3390/cryst8010006
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Works referenced in this record:

A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999

Multicomponent Assembly of Fluorescent-Tag Functionalized Ligands in Metal-Organic Frameworks for Sensing Explosives
journal, August 2014

  • Gole, Bappaditya; Bar, Arun Kumar; Mukherjee, Partha Sarathi
  • Chemistry - A European Journal, Vol. 20, Issue 41
  • DOI: 10.1002/chem.201402791

WinGX and ORTEP for Windows : an update
journal, July 2012

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

  • Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M.
  • Journal of Applied Crystallography, Vol. 48, Issue 1
  • DOI: 10.1107/S1600576714022985

Tail of the Organic Ligand Templated Metal-Organic Framework
journal, May 2012

  • Zhang, Xin; Yang, Jin-Xia; Yao, Yuan-Gen
  • Journal of Inorganic and Organometallic Polymers and Materials, Vol. 22, Issue 5
  • DOI: 10.1007/s10904-012-9690-z

Synthesis and catalytic properties of MIL-100(Fe), an iron( iii ) carboxylate with large pores
journal, January 2007

  • Horcajada, Patricia; Surblé, Suzy; Serre, Christian
  • Chem. Commun., Issue 27
  • DOI: 10.1039/B704325B

Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework
journal, January 2006

  • Dietzel, Pascal D. C.; Panella, Barbara; Hirscher, Michael
  • Chemical Communications, Issue 9
  • DOI: 10.1039/b515434k

An In Situ High-Temperature Single-Crystal Investigation of a Dehydrated Metal-Organic Framework Compound and Field-Induced Magnetization of One-Dimensional Metal-Oxygen Chains
journal, October 2005

  • Dietzel, Pascal D. C.; Morita, Yusuke; Blom, Richard
  • Angewandte Chemie International Edition, Vol. 44, Issue 39, p. 6354-6358
  • DOI: 10.1002/anie.200501508

Sextuplet phenyl embrace in a metal–organic Kagomé lattice
journal, January 2004

  • Perry, John J.; McManus, Gregory J.; Zaworotko, Michael J.
  • Chem. Commun., Issue 22
  • DOI: 10.1039/B408973A

Synthesis of a honeycomb-like Cu-based metal–organic framework and its carbon dioxide adsorption behaviour
journal, January 2013

  • Sanz, Raúl; Martínez, Fernando; Orcajo, Gisela
  • Dalton Trans., Vol. 42, Issue 7
  • DOI: 10.1039/C2DT32138F

Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites
journal, September 2011

  • Bloch, Eric D.; Murray, Leslie J.; Queen, Wendy L.
  • Journal of the American Chemical Society, Vol. 133, Issue 37
  • DOI: 10.1021/ja205976v

Modification of Extended Open Frameworks with Fluorescent Tags for Sensing Explosives: Competition between Size Selectivity and Electron Deficiency
journal, January 2014

  • Gole, Bappaditya; Bar, Arun Kumar; Mukherjee, Partha Sarathi
  • Chemistry - A European Journal, Vol. 20, Issue 8
  • DOI: 10.1002/chem.201302455

A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
journal, August 2004

  • Férey, Gérard; Serre, Christian; Mellot-Draznieks, Caroline
  • Angewandte Chemie International Edition, Vol. 43, Issue 46
  • DOI: 10.1002/anie.200460592

Crystal Structures, Topological Analyses, and Magnetic Properties of Manganese-Dihydroxyterephthalate Complexes
journal, January 2010

  • Gao, Qiang; Jiang, Fei-Long; Wu, Ming-Yan
  • Australian Journal of Chemistry, Vol. 63, Issue 2
  • DOI: 10.1071/CH09378

A novel 1D→2D interdigitated framework directed by hydrogen bonds
journal, April 2011

Synthesis, Crystal Structure, and Photoluminescent Property of a New 1D→2D Interdigitated Framework
journal, October 2014

  • Zhang, Da-Wei; Zhao, Guang-Yue
  • Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 45, Issue 4
  • DOI: 10.1080/15533174.2013.841212

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053273314026370

Rotaxanes from Tetralactams
journal, January 2012

  • Gibson, Harry W.; Wang, Hong; Niu, Zhenbin
  • Macromolecules, Vol. 45, Issue 3
  • DOI: 10.1021/ma202373x

Water Stable Zr-Benzenedicarboxylate Metal-Organic Frameworks as Photocatalysts for Hydrogen Generation
journal, August 2010

  • Gomes Silva, Cláudia; Luz, Ignacio; Llabrés i. Xamena, Francesc X.
  • Chemistry - A European Journal, Vol. 16, Issue 36
  • DOI: 10.1002/chem.200903526

Base-Induced Formation of Two Magnesium Metal-Organic Framework Compounds with a Bifunctional Tetratopic Ligand
journal, August 2008

  • Dietzel, Pascal D. C.; Blom, Richard; Fjellvåg, Helmer
  • European Journal of Inorganic Chemistry, Vol. 2008, Issue 23
  • DOI: 10.1002/ejic.200701284

Facile Self-Assembly of Neutral Dendritic Metallocycles via Oxygen-to-Platinum Coordination
journal, September 2009

  • Yang, Hai-Bo; Northrop, Brian H.; Zheng, Yao-Rong
  • The Journal of Organic Chemistry, Vol. 74, Issue 18
  • DOI: 10.1021/jo9013589

A short history of SHELX
journal, December 2007

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
  • DOI: 10.1107/S0108767307043930

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

  • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
  • Science, Vol. 295, Issue 5554, p. 469-472
  • DOI: 10.1126/science.1067208

Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005

  • Rosi, Nathaniel L.; Kim, Jaheon; Eddaoudi, Mohamed
  • Journal of the American Chemical Society, Vol. 127, Issue 5, p. 1504-1518
  • DOI: 10.1021/ja045123o

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005

  • Ferey, G.; Mellot-Draznieks, C.; Serre, C.
  • Science, Vol. 309, Issue 5743, p. 2040-2042
  • DOI: 10.1126/science.1116275

Crystal structure refinement with SHELXL
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053229614024218

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
  • DOI: 10.1021/ja8057953

Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy
journal, November 2002

  • Serre, Christian; Millange, Franck; Thouvenot, Christelle
  • Journal of the American Chemical Society, Vol. 124, Issue 45, p. 13519-13526
  • DOI: 10.1021/ja0276974

Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology
journal, April 2009

  • Ahnfeldt, Tim; Gunzelmann, Daniel; Loiseau, Thierry
  • Inorganic Chemistry, Vol. 48, Issue 7
  • DOI: 10.1021/ic8023265

Supramolecular Motifs: Concerted Multiple Phenyl Embraces between Ph 4 P + Cations Are Attractive and Ubiquitous
journal, May 1996

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

The sextuple phenyl embrace, a ubiquitous concerted supramolecular motif
journal, January 1995

  • Dance, Ian; Scudder, Marcia
  • Journal of the Chemical Society, Chemical Communications, Issue 10
  • DOI: 10.1039/c39950001039

Coordination Polymers of 5-Alkoxy Isophthalic Acids
journal, September 2016

  • McCormick, Laura J.; Morris, Samuel A.; Slawin, Alexandra M. Z.
  • Crystal Growth & Design, Vol. 16, Issue 10
  • DOI: 10.1021/acs.cgd.6b00853

Vanadium Analogues of Nonfunctionalized and Amino-Functionalized MOFs with MIL-101 Topology - Synthesis, Characterization, and Gas Sorption Properties
journal, April 2012

  • Biswas, Shyam; Couck, Sarah; Grzywa, Maciej
  • European Journal of Inorganic Chemistry, Vol. 2012, Issue 15
  • DOI: 10.1002/ejic.201200106

Corrections to tabulated anomalous-scattering factors
journal, March 1990

  • Kissel, L.; Pratt, R. H.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 46, Issue 3
  • DOI: 10.1107/S0108767389010718

A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
journal, August 2004

  • Férey, Gérard; Serre, Christian; Mellot-Draznieks, Caroline
  • Angewandte Chemie, Vol. 116, Issue 46, p. 6456-6461
  • DOI: 10.1002/ange.200460592
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