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Title: Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film

In this paper, we demonstrate a new strategy for cooperative catalysis and proton abstraction via the incorporation of independent species competent in the desired reactivity into a metal–organic framework (MOF) thin film.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1]
  1. Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Publication Date:
Grant/Contract Number:
SC0012446
Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 4; Journal Issue: 43; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Research Org:
Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1436127

Usov, P. M., Ahrenholtz, S. R., Maza, W. A., Stratakes, B., Epley, C. C., Kessinger, M. C., Zhu, J., and Morris, A. J.. Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film. United States: N. p., Web. doi:10.1039/c6ta05877a.
Usov, P. M., Ahrenholtz, S. R., Maza, W. A., Stratakes, B., Epley, C. C., Kessinger, M. C., Zhu, J., & Morris, A. J.. Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film. United States. doi:10.1039/c6ta05877a.
Usov, P. M., Ahrenholtz, S. R., Maza, W. A., Stratakes, B., Epley, C. C., Kessinger, M. C., Zhu, J., and Morris, A. J.. 2016. "Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film". United States. doi:10.1039/c6ta05877a. https://www.osti.gov/servlets/purl/1436127.
@article{osti_1436127,
title = {Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film},
author = {Usov, P. M. and Ahrenholtz, S. R. and Maza, W. A. and Stratakes, B. and Epley, C. C. and Kessinger, M. C. and Zhu, J. and Morris, A. J.},
abstractNote = {In this paper, we demonstrate a new strategy for cooperative catalysis and proton abstraction via the incorporation of independent species competent in the desired reactivity into a metal–organic framework (MOF) thin film.},
doi = {10.1039/c6ta05877a},
journal = {Journal of Materials Chemistry. A},
number = 43,
volume = 4,
place = {United States},
year = {2016},
month = {10}
}

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