Self-Formed Hybrid Interphase Layer on Lithium Metal for High-Performance Lithium–Sulfur Batteries

Li, Guoxing; Huang, Qingquan; He, Xin; Gao, Yue; Wang, Daiwei; Kim, Seong H.; Wang, Donghai

doi:10.1021/acsnano.7b08035

Title: Self-Formed Hybrid Interphase Layer on Lithium Metal for High-Performance Lithium–Sulfur Batteries

Journal Article · 29 January 2018 · ACS Nano

DOI: https://doi.org/10.1021/acsnano.7b08035 · OSTI ID:1435963

^[1]; Huang, Qingquan ^[1]; He, Xin ^[2];

^[1]; Wang, Daiwei ^[1];

^[2];

^[1]

Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering
Pennsylvania State Univ., University Park, PA (United States). Dept. of Chemical Engineering

Lithium–sulfur (Li–S) batteries are promising candidates for high-energy storage devices due to high theoretical capacities of both the sulfur cathode and lithium (Li) metal anode. Considerable efforts have been devoted to improving sulfur cathodes. However, issues associated with Li anodes, such as low Coulombic efficiency (CE) and growth of Li dendrites, remain unsolved due to unstable solid-electrolyte interphase (SEI) and lead to poor capacity retention and a short cycling life of Li–S batteries. In this paper, we demonstrate a facile and effective approach to fabricate a flexible and robust hybrid SEI layer through co-deposition of aromatic-based organosulfides and inorganic Li salts using poly(sulfur-random-1,3-diisopropenylbenzene) as an additive in an electrolyte. The aromatic-based organic components with planar backbone conformation and π–π interaction in the SEI layers can improve the toughness and flexibility to promote stable and high efficient Li deposition/dissolution. The as-formed durable SEI layer can inhibit dendritic Li growth, enhance Li deposition/dissolution CE (99.1% over 420 cycles), and in turn enable Li–S batteries with good cycling stability (1000 cycles) and slow capacity decay. Finally, this work demonstrates a route to address the issues associated with Li metal anodes and promote the development of high-energy rechargeable Li metal batteries.

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Research Organization:: Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Science Foundation (NSF)

Grant/Contract Number:: EE0007795; CMMI-1435766

OSTI ID:: 1435963

Alternate ID(s):: OSTI ID: 1430273

Report Number(s):: DOE-PENNSTATE-0007795; PII:974

Journal Information:: ACS Nano, Vol. 12, Issue 2; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 131 works

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25 ENERGY STORAGE
36 MATERIALS SCIENCE
77 NANOSCIENCE AND NANOTECHNOLOGY
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lithium metal anodes
lithium organopolysulfides
lithium organosulfides
lithium-sulfur battery
solid-electrolyte interphase