Site-Directed Synthesis of Cobalt Oxide Clusters in a Metal–Organic Framework

Peters, Aaron W.; Otake, Kenichi; Platero-Prats, Ana E.; Li, Zhanyong; DeStefano, Matthew R.; Chapman, Karena W.; Farha, Omar K.; Hupp, Joseph T.

doi:10.1021/acsami.8b02825

Title: Site-Directed Synthesis of Cobalt Oxide Clusters in a Metal–Organic Framework

Journal Article · 19 April 2018 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.8b02825 · OSTI ID:1435951

^[1]; Otake, Kenichi ^[1];

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Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Univ. Autonoma de Madrid, Madrid (Spain)
Argonne National Lab. (ANL), Argonne, IL (United States)
Northwestern Univ., Evanston, IL (United States); King Abdulaziz, Univ., Jeddah (Saudi Arabia)

Here, direct control over structure and location of catalytic species deposited on amorphous supports represents a formidable challenge in heterogeneous catalysis. In contrast, a structurally well-defined, crystalline metal–organic framework (MOF) can be rationally designed using post-synthetic techniques to allow for desired structural or locational changes of deposited metal ions. Herein, naphthalene dicarboxylate linkers are incorporated in the MOF, NU-1000, to block the small cavities where few-atom clusters of cobalt oxide preferentially grow, inducing catalyst deposition towards hither-to ill-favored grafting sites orientated toward NU-1000’s mesoporous channels. Despite the different cobalt oxide location, the resulting material is still an active propane oxidative dehydrogenation catalyst at low temperature, reaching a turnover frequency of 0.68 ± 0.05 h^–1 at 230 °C and confirming the utility of MOFs as crystalline supports to guide rational design of catalysts.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1435951

Journal Information:: ACS Applied Materials and Interfaces, Vol. 10, Issue 17; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 42 works

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Catalyst Location
Cobalt Oxide
Metal–Organic Frameworks
Oxidative Dehydrogenation of Propane
Post-Synthetic Modification