skip to main content

DOE PAGESDOE PAGES

Title: Efficient hydrogen evolution by ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam

With the massive consumption of fossil fuels and its detrimental impact on the environment, methods of generating clean power are urgent. Hydrogen is an ideal carrier for renewable energy; however, hydrogen generation is inefficient because of the lack of robust catalysts that are substantially cheaper than platinum. Therefore, robust and durable earth-abundant and cost-effective catalysts are desirable for hydrogen generation from water splitting via hydrogen evolution reaction. In this paper, we report an active and durable earth-abundant transition metal dichalcogenide-based hybrid catalyst that exhibits high hydrogen evolution activity approaching the state-of-the-art platinum catalysts, and superior to those of most transition metal dichalcogenides (molybdenum sulfide, cobalt diselenide and so on). Our material is fabricated by growing ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam. This advance provides a different pathway to design cheap, efficient and sizable hydrogen-evolving electrode by simultaneously tuning the number of catalytic edge sites, porosity, heteroatom doping and electrical conductivity.
Authors:
 [1] ;  [1] ;  [2] ;  [1] ;  [3] ;  [2] ;  [1] ; ORCiD logo [3] ;  [2] ;  [1] ;  [1]
  1. Univ. of Houston, Houston, TX (United States). Dept. of Physics and Texas Center for Superconductivity (TcSUH)
  2. California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center
  3. Univ. of Houston, Houston, TX (United States). Dept. of Electrical and Computer Engineering
Publication Date:
Grant/Contract Number:
SC0004993; FA 7000-13-1-0001; ECCS-1240510; E-1728
Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Research Org:
California Inst. of Technology (CalTech), Pasadena, CA (United States); Univ. of Houston, Houston, TX (United States)
Sponsoring Org:
USDOE Office of Science (SC); Defense Threat Reduction Agency (DTRA); National Science Foundation (NSF); Welch Foundation, Houston, TX (United States)
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN; 36 MATERIALS SCIENCE; electrocatalysis; porous materials
OSTI Identifier:
1435783

Zhou, Haiqing, Yu, Fang, Huang, Yufeng, Sun, Jingying, Zhu, Zhuan, Nielsen, Robert J., He, Ran, Bao, Jiming, Goddard III, William A., Chen, Shuo, and Ren, Zhifeng. Efficient hydrogen evolution by ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam. United States: N. p., Web. doi:10.1038/ncomms12765.
Zhou, Haiqing, Yu, Fang, Huang, Yufeng, Sun, Jingying, Zhu, Zhuan, Nielsen, Robert J., He, Ran, Bao, Jiming, Goddard III, William A., Chen, Shuo, & Ren, Zhifeng. Efficient hydrogen evolution by ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam. United States. doi:10.1038/ncomms12765.
Zhou, Haiqing, Yu, Fang, Huang, Yufeng, Sun, Jingying, Zhu, Zhuan, Nielsen, Robert J., He, Ran, Bao, Jiming, Goddard III, William A., Chen, Shuo, and Ren, Zhifeng. 2016. "Efficient hydrogen evolution by ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam". United States. doi:10.1038/ncomms12765. https://www.osti.gov/servlets/purl/1435783.
@article{osti_1435783,
title = {Efficient hydrogen evolution by ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam},
author = {Zhou, Haiqing and Yu, Fang and Huang, Yufeng and Sun, Jingying and Zhu, Zhuan and Nielsen, Robert J. and He, Ran and Bao, Jiming and Goddard III, William A. and Chen, Shuo and Ren, Zhifeng},
abstractNote = {With the massive consumption of fossil fuels and its detrimental impact on the environment, methods of generating clean power are urgent. Hydrogen is an ideal carrier for renewable energy; however, hydrogen generation is inefficient because of the lack of robust catalysts that are substantially cheaper than platinum. Therefore, robust and durable earth-abundant and cost-effective catalysts are desirable for hydrogen generation from water splitting via hydrogen evolution reaction. In this paper, we report an active and durable earth-abundant transition metal dichalcogenide-based hybrid catalyst that exhibits high hydrogen evolution activity approaching the state-of-the-art platinum catalysts, and superior to those of most transition metal dichalcogenides (molybdenum sulfide, cobalt diselenide and so on). Our material is fabricated by growing ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam. This advance provides a different pathway to design cheap, efficient and sizable hydrogen-evolving electrode by simultaneously tuning the number of catalytic edge sites, porosity, heteroatom doping and electrical conductivity.},
doi = {10.1038/ncomms12765},
journal = {Nature Communications},
number = ,
volume = 7,
place = {United States},
year = {2016},
month = {9}
}

Works referenced in this record:

MoS2 Nanoparticles Grown on Graphene An Advanced Catalyst for the Hydrogen Evolution Reaction
journal, May 2011
  • Li, Yanguang; Wang, Hailiang; Xie, Liming
  • Journal of the American Chemical Society, Vol. 133, Issue 19, p. 7296-7299
  • DOI: 10.1021/ja201269b

Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
journal, October 2012
  • Kibsgaard, Jakob; Chen, Zhebo; Reinecke, Benjamin N.
  • Nature Materials, Vol. 11, Issue 11, p. 963-969
  • DOI: 10.1038/nmat3439

Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition
journal, April 2011
  • Chen, Zongping; Ren, Wencai; Gao, Libo
  • Nature Materials, Vol. 10, Issue 6, p. 424-428
  • DOI: 10.1038/nmat3001

Growth of Alloy MoS2xSe2(1–x) Nanosheets with Fully Tunable Chemical Compositions and Optical Properties
journal, February 2014
  • Li, Honglai; Duan, Xidong; Wu, Xueping
  • Journal of the American Chemical Society, Vol. 136, Issue 10, p. 3756-3759
  • DOI: 10.1021/ja500069b

Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts
journal, July 2007
  • Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J.
  • Science, Vol. 317, Issue 5834, p. 100-102
  • DOI: 10.1126/science.1141483

Amorphous Molybdenum Sulfide Catalysts for Electrochemical Hydrogen Production: Insights into the Origin of their Catalytic Activity
journal, August 2012
  • Benck, Jesse D.; Chen, Zhebo; Kuritzky, Leah Y.
  • ACS Catalysis, Vol. 2, Issue 9, p. 1916-1923
  • DOI: 10.1021/cs300451q