Mid-infrared dual-gas sensor for simultaneous detection of methane and ethane using a single continuous-wave interband cascade laser
Abstract
A continuous-wave (CW) interband cascade laser (ICL) based mid-infrared sensor system was demonstrated for simultaneous detection of atmospheric methane (CH4) and ethane (C2H6). A 3.337 µm CW ICL with an emitting wavenumber range of 2996.0–3001.5 cm–1 was used to simultaneously target two absorption lines, C2H6 at 2996.88 cm–1 and CH4 at 2999.06 cm–1, respectively. The sensor performance was first evaluated for single-gas detection by only targeting the absorption line of one gas species. Allan deviations of 11.2 parts per billion in volume (ppbv) for CH4 and 1.86 ppbv for C2H6 with an averaging time of 3.4 s were achieved for the detection of these two gases. Dual-gas detection was realized by using a long-term scan signal to target both CH4 and C2H6 lines. The Allan deviations increased slightly to 17.4 ppbv for CH4 and 2.4 ppbv for C2H6 with an averaging time of 4.6 s due to laser temperature and power drift caused by long-term wavelength scanning. Measurements for both indoor and outdoor concentration changes of CH4 and C2H6 were conducted. As a result, the reported single ICL based dual-gas sensor system has the advantages of reduced size and cost compared to two separate sensor systems.
- Authors:
-
- Rice Univ., Houston, TX (United States); Shantou Univ., Shantou (China)
- Rice Univ., Houston, TX (United States); Jilin Univ., Changchun (China)
- Rice Univ., Houston, TX (United States)
- Rice Univ., Houston, TX (United States); Shanxi Univ., Taiyuan (China)
- Publication Date:
- Research Org.:
- Rice Univ., Houston, TX (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1435135
- Alternate Identifier(s):
- OSTI ID: 1435134
- Report Number(s):
- DOE-MAXION-00538-11
Journal ID: ISSN 1094-4087; OPEXFF
- Grant/Contract Number:
- AR0000538
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Optics Express
- Additional Journal Information:
- Journal Volume: 24; Journal Issue: 15; Journal ID: ISSN 1094-4087
- Publisher:
- Optical Society of America (OSA)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; Laser sensors; Spectroscopy, infrared; Semiconductor lasers, quantum cascade
Citation Formats
Ye, Weilin, Li, Chunguang, Zheng, Chuantao, Sanchez, Nancy P., Gluszek, Aleksander K., Hudzikowski, Arkadiusz J., Dong, Lei, Griffin, Robert J., and Tittel, Frank K. Mid-infrared dual-gas sensor for simultaneous detection of methane and ethane using a single continuous-wave interband cascade laser. United States: N. p., 2016.
Web. doi:10.1364/OE.24.016973.
Ye, Weilin, Li, Chunguang, Zheng, Chuantao, Sanchez, Nancy P., Gluszek, Aleksander K., Hudzikowski, Arkadiusz J., Dong, Lei, Griffin, Robert J., & Tittel, Frank K. Mid-infrared dual-gas sensor for simultaneous detection of methane and ethane using a single continuous-wave interband cascade laser. United States. https://doi.org/10.1364/OE.24.016973
Ye, Weilin, Li, Chunguang, Zheng, Chuantao, Sanchez, Nancy P., Gluszek, Aleksander K., Hudzikowski, Arkadiusz J., Dong, Lei, Griffin, Robert J., and Tittel, Frank K. Mon .
"Mid-infrared dual-gas sensor for simultaneous detection of methane and ethane using a single continuous-wave interband cascade laser". United States. https://doi.org/10.1364/OE.24.016973. https://www.osti.gov/servlets/purl/1435135.
@article{osti_1435135,
title = {Mid-infrared dual-gas sensor for simultaneous detection of methane and ethane using a single continuous-wave interband cascade laser},
author = {Ye, Weilin and Li, Chunguang and Zheng, Chuantao and Sanchez, Nancy P. and Gluszek, Aleksander K. and Hudzikowski, Arkadiusz J. and Dong, Lei and Griffin, Robert J. and Tittel, Frank K.},
abstractNote = {A continuous-wave (CW) interband cascade laser (ICL) based mid-infrared sensor system was demonstrated for simultaneous detection of atmospheric methane (CH4) and ethane (C2H6). A 3.337 µm CW ICL with an emitting wavenumber range of 2996.0–3001.5 cm–1 was used to simultaneously target two absorption lines, C2H6 at 2996.88 cm–1 and CH4 at 2999.06 cm–1, respectively. The sensor performance was first evaluated for single-gas detection by only targeting the absorption line of one gas species. Allan deviations of 11.2 parts per billion in volume (ppbv) for CH4 and 1.86 ppbv for C2H6 with an averaging time of 3.4 s were achieved for the detection of these two gases. Dual-gas detection was realized by using a long-term scan signal to target both CH4 and C2H6 lines. The Allan deviations increased slightly to 17.4 ppbv for CH4 and 2.4 ppbv for C2H6 with an averaging time of 4.6 s due to laser temperature and power drift caused by long-term wavelength scanning. Measurements for both indoor and outdoor concentration changes of CH4 and C2H6 were conducted. As a result, the reported single ICL based dual-gas sensor system has the advantages of reduced size and cost compared to two separate sensor systems.},
doi = {10.1364/OE.24.016973},
journal = {Optics Express},
number = 15,
volume = 24,
place = {United States},
year = {2016},
month = {7}
}
Web of Science
Works referenced in this record:
Spatial variability of methane: Attributing atmospheric concentrations to emissions
journal, July 2014
- Bamberger, I.; Stieger, J.; Buchmann, N.
- Environmental Pollution, Vol. 190
Spatiotemporal variation of methane and other trace hydrocarbon concentrations in the Valley of Mexico
journal, December 2002
- Smith, Felisa A.; Elliott, Scott; Blake, Donald R.
- Environmental Science & Policy, Vol. 5, Issue 6
Influence of biomass burning during recent fluctuations in the slow growth of global tropospheric methane
journal, January 2006
- Simpson, Isobel J.; Rowland, F. Sherwood; Meinardi, Simone
- Geophysical Research Letters, Vol. 33, Issue 22
Global budget of ethane and regional constraints on U.S. sources
journal, January 2008
- Xiao, Yaping; Logan, Jennifer A.; Jacob, Daniel J.
- Journal of Geophysical Research, Vol. 113, Issue D21
Earth's Degassing: A Missing Ethane and Propane Source
journal, January 2009
- Etiope, G.; Ciccioli, P.
- Science, Vol. 323, Issue 5913
Elevation of Exhaled Ethane Concentration in Asthma
journal, October 2000
- Paredi, Paolo; Kharitonov, Sergei A.; Barnes, Peter J.
- American Journal of Respiratory and Critical Care Medicine, Vol. 162, Issue 4
Increased levels of ethane, a non-invasive, quantitative, direct marker of n-3 lipid peroxidation, in the breath of patients with schizophrenia
journal, April 2008
- Puri, Basant K.; Ross, Brian M.; Treasaden, Ian H.
- Progress in Neuro-Psychopharmacology and Biological Psychiatry, Vol. 32, Issue 3
Application of laser spectroscopy for measurement of exhaled ethane in patients with lung cancer
journal, February 2006
- Skeldon, K. D.; McMillan, L. C.; Wyse, C. A.
- Respiratory Medicine, Vol. 100, Issue 2
Compact CH4 sensor based on difference frequency mixing of diode lasers in quasi-phasematched LiNbO3
journal, March 2000
- Lancaster, D. G.; Weidner, R.; Richter, D.
- Optics Communications, Vol. 175, Issue 4-6
Methane detection with a narrow-band source at 34 μm based on a Nd:YAG pump laser and a combination of stimulated Raman scattering and difference frequency mixing
journal, January 1996
- Lancaster, D. G.; Dawes, J. M.
- Applied Optics, Vol. 35, Issue 21
Trace-gas sensing in the 3.3-μm region using a diode-based difference-frequency laser photoacoustic system
journal, September 2002
- Fischer, C.; Sigrist, M. W.
- Applied Physics B: Lasers and Optics, Vol. 75, Issue 2-3
Compact mid-infrared trace gas sensor based on difference-frequency generation of two diode lasers in periodically poled LiNbO 3
journal, September 1998
- Richter, D.; Lancaster, D. G.; Curl, R. F.
- Applied Physics B: Lasers and Optics, Vol. 67, Issue 3
Precise measurement of methane in air using diode-pumped 3.4-μm difference-frequency generation in PPLN
journal, May 1997
- Petrov, K. P.; Waltman, S.; Dlugokencky, E. J.
- Applied Physics B: Lasers and Optics, Vol. 64, Issue 5
Frequency-modulation spectroscopy for trace species detection: theory and comparison among experimental methods
journal, January 1992
- Silver, Joel A.
- Applied Optics, Vol. 31, Issue 6, p. 707-717
A review of recent advances in semiconductor laser based gas monitors
journal, February 1998
- Werle, Peter
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 54, Issue 2
Wavelength Modulation Spectroscopy: Combined Frequency and Intensity Laser Modulation
journal, January 2003
- Schilt, Stéphane; Thévenaz, Luc; Robert, Philippe
- Applied Optics, Vol. 42, Issue 33
A formaldehyde trace gas sensor based on a thermoelectrically cooled CW-DFB quantum cascade laser
journal, January 2014
- Li, Jingsong; Parchatka, Uwe; Fischer, Horst
- Anal. Methods, Vol. 6, Issue 15
Detection of formaldehyde using off-axis integrated cavity output spectroscopy with an interband cascade laser
journal, June 2006
- Miller, J. H.; Bakhirkin, Y. A.; Ajtai, T.
- Applied Physics B, Vol. 85, Issue 2-3
Demonstration of an Ethane Spectrometer for Methane Source Identification
journal, June 2014
- Yacovitch, Tara I.; Herndon, Scott C.; Roscioli, Joseph R.
- Environmental Science & Technology, Vol. 48, Issue 14
Compact TDLAS based optical sensor for ppb-level ethane detection by use of a 3.34 μm room-temperature CW interband cascade laser
journal, September 2016
- Li, Chunguang; Dong, Lei; Zheng, Chuantao
- Sensors and Actuators B: Chemical, Vol. 232
Compact CH 4 sensor system based on a continuous-wave, low power consumption, room temperature interband cascade laser
journal, January 2016
- Dong, Lei; Li, Chunguang; Sanchez, Nancy P.
- Applied Physics Letters, Vol. 108, Issue 1
Investigation of Wavelength Modulation and Wavelength Sweep Techniques in Intracavity Fiber Laser for Gas Detection
journal, January 2011
- Kun Liu,
- Journal of Lightwave Technology, Vol. 29, Issue 1
Analytical Line Shapes for Lorentzian Signals Broadened by Modulation
journal, August 1965
- Arndt, Rolf
- Journal of Applied Physics, Vol. 36, Issue 8
Second-harmonic detection with tunable diode lasers ? Comparison of experiment and theory
journal, November 1981
- Reid, J.; Labrie, D.
- Applied Physics B Photophysics and Laser Chemistry, Vol. 26, Issue 3
Works referencing / citing this record:
A Lagrangian interpolation-assisted direct laser absorption spectrum analyzer based on digital signal processor for methane detection
journal, April 2019
- Yu, Di; Zhou, Yanwen; Song, Fang
- Applied Physics B, Vol. 125, Issue 5
A near-infrared C 2 H 2 /CH 4 dual-gas sensor system combining off-axis integrated-cavity output spectroscopy and frequency-division-multiplexing-based wavelength modulation spectroscopy
journal, January 2019
- Zheng, Kaiyuan; Zheng, Chuantao; Yao, Dan
- The Analyst, Vol. 144, Issue 6
A near-infrared carbon dioxide sensor system using a compact folded optical structure for deep-sea natural gas hydrate exploration
journal, January 2018
- Liu, Zhiwei; Zheng, Chuantao; Chen, Chen
- Analytical Methods, Vol. 10, Issue 39
An auto-correction laser photoacoustic spectrometer based on 2 f /1 f wavelength modulation spectroscopy
journal, January 2020
- Chen, Ke; Liu, Shuai; Mei, Liang
- The Analyst, Vol. 145, Issue 4
Cavity enhanced absorption spectroscopy in the mid-infrared using a supercontinuum source
journal, August 2017
- Amiot, Caroline; Aalto, Antti; Ryczkowski, Piotr
- Applied Physics Letters, Vol. 111, Issue 6
Photoacoustic Measurement of Ethane with Near-Infrared DFB Diode Laser
journal, January 2018
- Cheng, Gang; Cao, Yuan; Liu, Kun
- Journal of Spectroscopy, Vol. 2018
Pressure-dependent sensitivity of a single-pass methane detection system using a continuous-wave distributed feedback laser at 3270 nm
journal, January 2019
- Razavipour, Seyed Ghasem; Gupta, James A.; Sabiston, Graeme
- Applied Optics, Vol. 58, Issue 25
Compact photoacoustic module for methane detection incorporating interband cascade light emitting device
journal, January 2017
- Zheng, Huadan; Lou, Minhan; Dong, Lei
- Optics Express, Vol. 25, Issue 14
Highly sensitive and selective CO sensor using a 233 μm diode laser and wavelength modulation spectroscopy
journal, January 2018
- Cui, Ruyue; Dong, Lei; Wu, Hongpeng
- Optics Express, Vol. 26, Issue 19
Near-infrared acetylene sensor system using off-axis integrated-cavity output spectroscopy and two measurement schemes
journal, January 2018
- Zheng, Kaiyuan; Zheng, Chuantao; He, Qixin
- Optics Express, Vol. 26, Issue 20
ICL-based mid-infrared carbon dioxide sensor system for deep-sea natural gas hydrate exploration
journal, January 2019
- Liu, Zhiwei; Zheng, Chuantao; Chen, Chen
- Optics Express, Vol. 27, Issue 4
Single-chip, mid-infrared array for room temperature video rate imaging
journal, January 2017
- Xie, Chengzhi; Aziz, Mohsin; Pusino, Vincenzo
- Optica, Vol. 4, Issue 12
Mid-Infrared Tunable Laser-Based Broadband Fingerprint Absorption Spectroscopy for Trace Gas Sensing: A Review
journal, January 2019
- Du, Zhenhui; Zhang, Shuai; Li, Jinyi
- Applied Sciences, Vol. 9, Issue 2
Recent Developments in Modulation Spectroscopy for Methane Detection Based on Tunable Diode Laser
journal, July 2019
- Wang, Fei; Jia, Shuhai; Wang, Yonglin
- Applied Sciences, Vol. 9, Issue 14