DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction

Authors:
 [1];  [2];  [2];  [3];  [3];  [3];  [4];  [1];  [1];  [1];  [4];  [3];  [2];  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Pennsylvania State Univ., University Park, PA (United States). Dept of Mechanical and Nuclear Engineering
  3. Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Chemical Engineering and Materials Science
  4. Univ. of Delaware, Newark, DE (United States). Dept. of Chemistry and Biochemistry
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1434934
Alternate Identifier(s):
OSTI ID: 1435201
Grant/Contract Number:  
AC02-06CH11357; AC02-05CH11231; AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 30; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Bismuth electrodes; cathodic corrosion; CO2 reduction; imidazolium ionic liquids

Citation Formats

Medina Ramos, Jonnathan, Zhang, Weiwei, Yoon, Kichul, Bai, Peng, Chemburkar, Ashwin, Tang, Wenjie, Atifi, Abderrahman, Lee, Sang Soo, Fister, Timothy T., Ingram, Brian J., Rosenthal, Joel, Neurock, Matthew, van Duin, Adri C. T., and Fenter, Paul. Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction. United States: N. p., 2018. Web. doi:10.1021/acs.chemmater.8b00050.
Medina Ramos, Jonnathan, Zhang, Weiwei, Yoon, Kichul, Bai, Peng, Chemburkar, Ashwin, Tang, Wenjie, Atifi, Abderrahman, Lee, Sang Soo, Fister, Timothy T., Ingram, Brian J., Rosenthal, Joel, Neurock, Matthew, van Duin, Adri C. T., & Fenter, Paul. Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction. United States. https://doi.org/10.1021/acs.chemmater.8b00050
Medina Ramos, Jonnathan, Zhang, Weiwei, Yoon, Kichul, Bai, Peng, Chemburkar, Ashwin, Tang, Wenjie, Atifi, Abderrahman, Lee, Sang Soo, Fister, Timothy T., Ingram, Brian J., Rosenthal, Joel, Neurock, Matthew, van Duin, Adri C. T., and Fenter, Paul. Thu . "Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction". United States. https://doi.org/10.1021/acs.chemmater.8b00050. https://www.osti.gov/servlets/purl/1434934.
@article{osti_1434934,
title = {Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction},
author = {Medina Ramos, Jonnathan and Zhang, Weiwei and Yoon, Kichul and Bai, Peng and Chemburkar, Ashwin and Tang, Wenjie and Atifi, Abderrahman and Lee, Sang Soo and Fister, Timothy T. and Ingram, Brian J. and Rosenthal, Joel and Neurock, Matthew and van Duin, Adri C. T. and Fenter, Paul},
abstractNote = {},
doi = {10.1021/acs.chemmater.8b00050},
journal = {Chemistry of Materials},
number = ,
volume = 30,
place = {United States},
year = {2018},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 25 works
Citation information provided by
Web of Science

Figures / Tables:

Figure 1 Figure 1: X-ray reflectivity in the (a) low-angle and (b) crystal truncation rod (CTR) regimes of a Bi thin film immersed in a CO2-saturated acetonitrile solution containing 100 mM [BMIM]OTf, before (yellow circles) and after running one cyclic voltammogram (blue squares) between −0.32 V and −1.90 V vs. Ag/ AgCl,more » at 10 mV/s (the data after one CV scan has been scaled by a factor of 102 in order to improve data visualization). (c) CTR of the Bi (001) Bragg peak region recorded with the Bi thin film in solution at open circuit potential and polarized at −1.9 V. In all three figures, the solid black lines represent the best fit model of the respective reflectivity data, and the dotted line in (b) corresponds to the fitting result of the CTR signal prior to the CV scan.« less

Save / Share:

Works referenced in this record:

Efficient Conversion of CO 2 to CO Using Tin and Other Inexpensive and Easily Prepared Post-Transition Metal Catalysts
journal, April 2015

  • Medina-Ramos, Jonnathan; Pupillo, Rachel C.; Keane, Thomas P.
  • Journal of the American Chemical Society, Vol. 137, Issue 15
  • DOI: 10.1021/ja5121088

Efficient Reduction of CO 2 to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials
journal, May 2014

  • Medina-Ramos, Jonnathan; DiMeglio, John L.; Rosenthal, Joel
  • Journal of the American Chemical Society, Vol. 136, Issue 23
  • DOI: 10.1021/ja501923g

Rational Design of Bi Nanoparticles for Efficient Electrochemical CO 2 Reduction: The Elucidation of Size and Surface Condition Effects
journal, August 2016


Selective Conversion of CO 2 to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst
journal, June 2013

  • DiMeglio, John L.; Rosenthal, Joel
  • Journal of the American Chemical Society, Vol. 135, Issue 24
  • DOI: 10.1021/ja4033549

Structural Dynamics and Evolution of Bismuth Electrodes during Electrochemical Reduction of CO 2 in Imidazolium-Based Ionic Liquid Solutions
journal, September 2017

  • Medina-Ramos, Jonnathan; Lee, Sang Soo; Fister, Timothy T.
  • ACS Catalysis, Vol. 7, Issue 10
  • DOI: 10.1021/acscatal.7b01370

Dimensionally Controlled Lithiation of Chromium Oxide
journal, December 2015


Co-refinement of multiple-contrast neutron/X-ray reflectivity data using MOTOFIT
journal, March 2006


Interfacial ionic ‘liquids’: connecting static and dynamic structures
journal, December 2014


Structural Origins of Potential Dependent Hysteresis at the Electrified Graphene/Ionic Liquid Interface
journal, December 2013

  • Uysal, Ahmet; Zhou, Hua; Feng, Guang
  • The Journal of Physical Chemistry C, Vol. 118, Issue 1
  • DOI: 10.1021/jp4111025

Heteroepitaxial growth of cadmium carbonate at dolomite and calcite surfaces: Mechanisms and rates
journal, May 2017

  • Callagon, Erika Blanca R.; Lee, Sang Soo; Eng, Peter J.
  • Geochimica et Cosmochimica Acta, Vol. 205
  • DOI: 10.1016/j.gca.2016.12.007

Electronegativity-equalization method for the calculation of atomic charges in molecules
journal, July 1986

  • Mortier, Wilfried J.; Ghosh, Swapan K.; Shankar, S.
  • Journal of the American Chemical Society, Vol. 108, Issue 15
  • DOI: 10.1021/ja00275a013

Chemistry with ADF
journal, January 2001

  • te Velde, G.; Bickelhaupt, F. M.; Baerends, E. J.
  • Journal of Computational Chemistry, Vol. 22, Issue 9, p. 931-967
  • DOI: 10.1002/jcc.1056

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Projector augmented-wave method
journal, December 1994


Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006

  • Grimme, Stefan
  • Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799
  • DOI: 10.1002/jcc.20495

Low-Temperature Growth of Bismuth Thin Films with (111) Facet on Highly Oriented Pyrolytic Graphite
journal, April 2015

  • Song, Fei; Wells, Justin W.; Jiang, Zheng
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 16
  • DOI: 10.1021/acsami.5b00264

Special points for Brillouin-zone integrations
journal, June 1976

  • Monkhorst, Hendrik J.; Pack, James D.
  • Physical Review B, Vol. 13, Issue 12, p. 5188-5192
  • DOI: 10.1103/PhysRevB.13.5188

Elucidation of the Electrochemical Activation of Water over Pd by First Principles
journal, January 2006

  • Filhol, Jean-Sébastien; Neurock, Matthew
  • Angewandte Chemie International Edition, Vol. 45, Issue 3
  • DOI: 10.1002/anie.200502540

Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi
journal, January 1985

  • Wadt, Willard R.; Hay, P. Jeffrey
  • The Journal of Chemical Physics, Vol. 82, Issue 1
  • DOI: 10.1063/1.448800

Quaternary ammonium amalgams
journal, January 1968

  • Littlehailes, J. D.; Woodhall, B. J.
  • Discussions of the Faraday Society, Vol. 45
  • DOI: 10.1039/df9684500187

On the cathodic behaviour of tetraalkylammonium cations at a platinum electrode
journal, July 1998


Reactivity of Platinum Metal with Organic Radical Anions from Metal to Negative Oxidation States
journal, April 2007

  • Ghilane, Jalal; Guilloux-Viry, Maryline; Lagrost, Corinne
  • Journal of the American Chemical Society, Vol. 129, Issue 20
  • DOI: 10.1021/ja071483a

Spectroscopic Evidence of Platinum Negative Oxidation States at Electrochemically Reduced Surfaces
journal, April 2007

  • Ghilane, J.; Lagrost, C.; Guilloux-Viry, M.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 15
  • DOI: 10.1021/jp068879d

Cathodic Corrosion as a Facile and Effective Method To Prepare Clean Metal Alloy Nanoparticles
journal, November 2011

  • Rodriguez, Paramaconi; Tichelaar, Frans D.; Koper, Marc T. M.
  • Journal of the American Chemical Society, Vol. 133, Issue 44
  • DOI: 10.1021/ja208264e

Cathodic Corrosion: A Quick, Clean, and Versatile Method for the Synthesis of Metallic Nanoparticles
journal, May 2011

  • Yanson, Alexei I.; Rodriguez, Paramaconi; Garcia-Araez, Nuria
  • Angewandte Chemie International Edition, Vol. 50, Issue 28, p. 6346-6350
  • DOI: 10.1002/anie.201100471

Reaction of solid cathodes with tetraalkylammonium electrolytes
journal, May 1990

  • Svetličič, Vesna; Lawin, Phillip B.; Kariv-Miller, Essie
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 284, Issue 1
  • DOI: 10.1016/0022-0728(90)87071-Q

Dimethylpyrrolidinium amalgam formation and catalysis of organic electroreductions
journal, June 1984

  • Kariv-Miller, Essie; Nanjundiah, Chenniah; Eaton, Jon
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 167, Issue 1-2
  • DOI: 10.1016/0368-1874(84)87063-X

Dimethylpyrrolidinium, a catalyst for organic electroreductions
journal, May 1985

  • Kariv-Miller, Essie; Andruzzi, Romano
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 187, Issue 1
  • DOI: 10.1016/0368-1874(85)85584-2

Hydrated Cation Speciation at the Muscovite (001)−Water Interface
journal, November 2010

  • Lee, Sang Soo; Fenter, Paul; Park, Changyong
  • Langmuir, Vol. 26, Issue 22
  • DOI: 10.1021/la1032866

Tuning Selectivity of CO 2 Hydrogenation Reactions at the Metal/Oxide Interface
journal, July 2017

  • Kattel, Shyam; Liu, Ping; Chen, Jingguang G.
  • Journal of the American Chemical Society, Vol. 139, Issue 29
  • DOI: 10.1021/jacs.7b05362

Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution
journal, October 2015

  • Bergmann, Arno; Martinez-Moreno, Elias; Teschner, Detre
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9625

Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
journal, January 2016


Directing the Outcome of CO 2 Reduction at Bismuth Cathodes Using Varied Ionic Liquid Promoters
journal, March 2018


Works referencing / citing this record:

Few‐Layer Bismuthene with Anisotropic Expansion for High‐Areal‐Capacity Sodium‐Ion Batteries
journal, January 2019

  • Zhou, Jing; Chen, Jiangchun; Chen, Mengxue
  • Advanced Materials, Vol. 31, Issue 12
  • DOI: 10.1002/adma.201807874

Reaction mechanisms at the homogeneous–heterogeneous frontier: insights from first-principles studies on ligand-decorated metal nanoparticles
journal, January 2019

  • Ortuño, Manuel A.; López, Núria
  • Catalysis Science & Technology, Vol. 9, Issue 19
  • DOI: 10.1039/c9cy01351b

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.