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Title: Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction

Authors:
 [1];  [2];  [2];  [3];  [3];  [3];  [4];  [1];  [1];  [1];  [4];  [3];  [2];  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Pennsylvania State Univ., University Park, PA (United States). Dept of Mechanical and Nuclear Engineering
  3. Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Chemical Engineering and Materials Science
  4. Univ. of Delaware, Newark, DE (United States). Dept. of Chemistry and Biochemistry
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1434934
Alternate Identifier(s):
OSTI ID: 1435201
Grant/Contract Number:  
AC02-06CH11357; AC02-05CH11231; AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 30; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Bismuth electrodes; cathodic corrosion; CO2 reduction; imidazolium ionic liquids

Citation Formats

Medina Ramos, Jonnathan, Zhang, Weiwei, Yoon, Kichul, Bai, Peng, Chemburkar, Ashwin, Tang, Wenjie, Atifi, Abderrahman, Lee, Sang Soo, Fister, Timothy T., Ingram, Brian J., Rosenthal, Joel, Neurock, Matthew, van Duin, Adri C. T., and Fenter, Paul. Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction. United States: N. p., 2018. Web. doi:10.1021/acs.chemmater.8b00050.
Medina Ramos, Jonnathan, Zhang, Weiwei, Yoon, Kichul, Bai, Peng, Chemburkar, Ashwin, Tang, Wenjie, Atifi, Abderrahman, Lee, Sang Soo, Fister, Timothy T., Ingram, Brian J., Rosenthal, Joel, Neurock, Matthew, van Duin, Adri C. T., & Fenter, Paul. Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction. United States. doi:10.1021/acs.chemmater.8b00050.
Medina Ramos, Jonnathan, Zhang, Weiwei, Yoon, Kichul, Bai, Peng, Chemburkar, Ashwin, Tang, Wenjie, Atifi, Abderrahman, Lee, Sang Soo, Fister, Timothy T., Ingram, Brian J., Rosenthal, Joel, Neurock, Matthew, van Duin, Adri C. T., and Fenter, Paul. Thu . "Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction". United States. doi:10.1021/acs.chemmater.8b00050. https://www.osti.gov/servlets/purl/1434934.
@article{osti_1434934,
title = {Cathodic Corrosion at the Bismuth-Ionic Liquid Electrolyte Interface under Conditions for CO2 Reduction},
author = {Medina Ramos, Jonnathan and Zhang, Weiwei and Yoon, Kichul and Bai, Peng and Chemburkar, Ashwin and Tang, Wenjie and Atifi, Abderrahman and Lee, Sang Soo and Fister, Timothy T. and Ingram, Brian J. and Rosenthal, Joel and Neurock, Matthew and van Duin, Adri C. T. and Fenter, Paul},
abstractNote = {},
doi = {10.1021/acs.chemmater.8b00050},
journal = {Chemistry of Materials},
number = ,
volume = 30,
place = {United States},
year = {2018},
month = {3}
}

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Cited by: 2 works
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Figures / Tables:

Figure 1 Figure 1: X-ray reflectivity in the (a) low-angle and (b) crystal truncation rod (CTR) regimes of a Bi thin film immersed in a CO2-saturated acetonitrile solution containing 100 mM [BMIM]OTf, before (yellow circles) and after running one cyclic voltammogram (blue squares) between −0.32 V and −1.90 V vs. Ag/ AgCl,more » at 10 mV/s (the data after one CV scan has been scaled by a factor of 102 in order to improve data visualization). (c) CTR of the Bi (001) Bragg peak region recorded with the Bi thin film in solution at open circuit potential and polarized at −1.9 V. In all three figures, the solid black lines represent the best fit model of the respective reflectivity data, and the dotted line in (b) corresponds to the fitting result of the CTR signal prior to the CV scan.« less

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Works referencing / citing this record:

Few‐Layer Bismuthene with Anisotropic Expansion for High‐Areal‐Capacity Sodium‐Ion Batteries
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  • Zhou, Jing; Chen, Jiangchun; Chen, Mengxue
  • Advanced Materials, Vol. 31, Issue 12
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Reaction mechanisms at the homogeneous–heterogeneous frontier: insights from first-principles studies on ligand-decorated metal nanoparticles
journal, January 2019

  • Ortuño, Manuel A.; López, Núria
  • Catalysis Science & Technology, Vol. 9, Issue 19
  • DOI: 10.1039/c9cy01351b

Conversion of CO 2 to value-added products mediated by ionic liquids
journal, January 2019


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