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Title: Elucidating Solvation Structures for Rational Design of Multivalent Electrolytes—A Review

Fundamental molecular-level understanding of functional properties of liquid solutions provides an important basis for designing optimized electrolytes for numerous applications. In particular, exhaustive knowledge of solvation structure, stability, and transport properties is critical for developing stable electrolytes for fast-charging and high-energy-density next-generation energy storage systems. Accordingly, there is growing interest in the rational design of electrolytes for beyond lithium-ion systems by tuning the molecular-level interactions of solvate species present in the electrolytes. Here in this paper, we present a review of the solvation structure of multivalent electrolytes and its impact on the electrochemical performance of these batteries. A direct correlation between solvate species present in the solution and macroscopic properties of electrolytes is sparse for multivalent electrolytes and contradictory results have been reported in the literature. This review aims to illustrate the current understanding, compare results, and highlight future needs and directions to enable the deep understanding needed for the rational design of improved multivalent electrolytes.
Authors:
 [1] ;  [1] ;  [2] ;  [3] ;  [4]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Joint Center for Energy Storage Research (JCESR), Chicago, IL (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States). Graduate Group in Applied Science and Technology; Joint Center for Energy Storage Research (JCESR), Chicago, IL (United States)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
  4. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering; Joint Center for Energy Storage Research (JCESR), Chicago, IL (United States)
Publication Date:
Grant/Contract Number:
AC02-05CH11231; AC02-06CH11357
Type:
Published Article
Journal Name:
Topics in Current Chemistry
Additional Journal Information:
Journal Volume: 376; Journal Issue: 3; Journal ID: ISSN 2365-0869
Publisher:
Springer
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Multivalent electrolytes; Solvation structure; Renewable energy
OSTI Identifier:
1434802
Alternate Identifier(s):
OSTI ID: 1460339

Rajput, Nav Nidhi, Seguin, Trevor J., Wood, Brandon M., Qu, Xiaohui, and Persson, Kristin A.. Elucidating Solvation Structures for Rational Design of Multivalent Electrolytes—A Review. United States: N. p., Web. doi:10.1007/s41061-018-0195-2.
Rajput, Nav Nidhi, Seguin, Trevor J., Wood, Brandon M., Qu, Xiaohui, & Persson, Kristin A.. Elucidating Solvation Structures for Rational Design of Multivalent Electrolytes—A Review. United States. doi:10.1007/s41061-018-0195-2.
Rajput, Nav Nidhi, Seguin, Trevor J., Wood, Brandon M., Qu, Xiaohui, and Persson, Kristin A.. 2018. "Elucidating Solvation Structures for Rational Design of Multivalent Electrolytes—A Review". United States. doi:10.1007/s41061-018-0195-2.
@article{osti_1434802,
title = {Elucidating Solvation Structures for Rational Design of Multivalent Electrolytes—A Review},
author = {Rajput, Nav Nidhi and Seguin, Trevor J. and Wood, Brandon M. and Qu, Xiaohui and Persson, Kristin A.},
abstractNote = {Fundamental molecular-level understanding of functional properties of liquid solutions provides an important basis for designing optimized electrolytes for numerous applications. In particular, exhaustive knowledge of solvation structure, stability, and transport properties is critical for developing stable electrolytes for fast-charging and high-energy-density next-generation energy storage systems. Accordingly, there is growing interest in the rational design of electrolytes for beyond lithium-ion systems by tuning the molecular-level interactions of solvate species present in the electrolytes. Here in this paper, we present a review of the solvation structure of multivalent electrolytes and its impact on the electrochemical performance of these batteries. A direct correlation between solvate species present in the solution and macroscopic properties of electrolytes is sparse for multivalent electrolytes and contradictory results have been reported in the literature. This review aims to illustrate the current understanding, compare results, and highlight future needs and directions to enable the deep understanding needed for the rational design of improved multivalent electrolytes.},
doi = {10.1007/s41061-018-0195-2},
journal = {Topics in Current Chemistry},
number = 3,
volume = 376,
place = {United States},
year = {2018},
month = {4}
}

Works referenced in this record:

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

Poly(methylmethacrylate)�magnesium triflate gel polymer electrolyte for solid state magnesium battery application
journal, January 2002

Magnesium Borohydride: From Hydrogen Storage to Magnesium Battery
journal, August 2012
  • Mohtadi, Rana; Matsui, Masaki; Arthur, Timothy S.
  • Angewandte Chemie International Edition, Vol. 51, Issue 39, p. 9780-9783
  • DOI: 10.1002/anie.201204913

Electrolyte Solutions for Rechargeable Magnesium Batteries Based on Organomagnesium Chloroaluminate Complexes
journal, January 2002
  • Aurbach, Doron; Gizbar, Haim; Schechter, Alex
  • Journal of The Electrochemical Society, Vol. 149, Issue 2, p. A115-A121
  • DOI: 10.1149/1.1429925

A novel electrolyte system without a Grignard reagent for rechargeable magnesium batteries
journal, January 2012
  • Wang, Fei-fei; Guo, Yong-sheng; Yang, Jun
  • Chemical Communications, Vol. 48, Issue 87, Article No. 10763
  • DOI: 10.1039/c2cc35857c

Nonaqueous magnesium electrochemistry and its application in secondary batteries
journal, January 2003
  • Aurbach, Doron; Weissman, Idit; Gofer, Yosef
  • The Chemical Record, Vol. 3, Issue 1, p. 61-73
  • DOI: 10.1002/tcr.10051

Magnesium insertion electrodes for rechargeable nonaqueous batteries � a competitive alternative to lithium?
journal, September 1999

Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries
journal, January 2008
  • Mizrahi, Oren; Amir, Nir; Pollak, Elad
  • Journal of The Electrochemical Society, Vol. 155, Issue 2, p. A103-A109
  • DOI: 10.1149/1.2806175

Prototype systems for rechargeable magnesium batteries
journal, October 2000
  • Aurbach, D.; Lu, Z.; Schechter, A.
  • Nature, Vol. 407, Issue 6805, p. 724-727
  • DOI: 10.1038/35037553

Magnesium(II) Bis(trifluoromethane sulfonyl) Imide-Based Electrolytes with Wide Electrochemical Windows for Rechargeable Magnesium Batteries
journal, March 2014
  • Ha, Se-Young; Lee, Yong-Won; Woo, Sang Won
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 6, p. 4063-4073
  • DOI: 10.1021/am405619v

Mg rechargeable batteries: an on-going challenge
journal, January 2013
  • Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef
  • Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279
  • DOI: 10.1039/c3ee40871j

Electrochemical Insertion of Magnesium into Hydrated Vanadium Bronzes
journal, January 1995
  • Nova?k, Petr; Scheifele, Werner; Joho, Felix
  • Journal of The Electrochemical Society, Vol. 142, Issue 8, p. 2544-2550
  • DOI: 10.1149/1.2050051

Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries
journal, January 2014
  • Doe, Robert E.; Han, Ruoban; Hwang, Jaehee
  • Chemical Communications, Vol. 50, Issue 2, p. 243-245
  • DOI: 10.1039/C3CC47896C

On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions
journal, May 1999

Structure and compatibility of a magnesium electrolyte with a sulphur cathode
journal, August 2011
  • Kim, Hee Soo; Arthur, Timothy S.; Allred, Gary D.
  • Nature Communications, Vol. 2, Article No. 427
  • DOI: 10.1038/ncomms1435

The Coupling between Stability and Ion Pair Formation in Magnesium Electrolytes from First-Principles Quantum Mechanics and Classical Molecular Dynamics
journal, February 2015
  • Rajput, Nav Nidhi; Qu, Xiaohui; Sa, Niya
  • Journal of the American Chemical Society, Vol. 137, Issue 9, p. 3411-3420
  • DOI: 10.1021/jacs.5b01004

Aluminum as anode for energy storage and conversion: a review
journal, July 2002

Corrosion of magnesium electrolytes: chlorides � the culprit
journal, December 2012
  • Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G.
  • Energy Environ. Sci., Vol. 6, Issue 2, p. 482-487
  • DOI: 10.1039/C2EE23686A

Nonaqueous Electrochemistry of Magnesium
journal, January 1990
  • Gregory, Thomas D.; Hoffman, Ronald J.; Winterton, Richard C.
  • Journal of The Electrochemical Society, Vol. 137, Issue 3, p. 775-780
  • DOI: 10.1149/1.2086553

Electrolyte roadblocks to a magnesium rechargeable battery
journal, January 2012
  • Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G.
  • Energy & Environmental Science, Vol. 5, Issue 3, p. 5941-5950
  • DOI: 10.1039/c2ee03029b