Selective Glucose‐to‐Fructose Isomerization over Modified Zirconium UiO‐66 in Alcohol Media
Abstract
Abstract Modulated zirconium metal–organic framework UiO‐66 is shown to catalyze the isomerization of d ‐glucose to d ‐fructose in alcohol media. Fructose selectivity can change depending on solvent choice. We hypothesize that the difference in selectivity is related to a combined effect of adsorption and solvation effects, which may lead to the high formation of alkylglucosides in depletion of fructose if methanol or ethanol are used. A fructose selectivity of 72 % at 82 % glucose conversion in 1‐PrOH was achieved. The reaction mechanism was investigated using nuclear magnetic resonance spectroscopy. We demonstrate that UiO‐66 isomerizes glucose to fructose through an intramolecular C2–C1 hydride transfer. In addition, we show that modulated UiO‐66 is a highly active and stable catalyst at the reaction conditions, showing great potential for other sugar reactions.
- Authors:
-
[1]
- Department of Chemical Engineering and Materials Science University of Minnesota 421 Washington Avenue SE Minneapolis MN 55455 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1434389
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemCatChem
- Additional Journal Information:
- Journal Name: ChemCatChem Journal Volume: 10 Journal Issue: 11; Journal ID: ISSN 1867-3880
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
de Mello, Matheus Dorneles, and Tsapatsis, Michael. Selective Glucose‐to‐Fructose Isomerization over Modified Zirconium UiO‐66 in Alcohol Media. Germany: N. p., 2018.
Web. doi:10.1002/cctc.201800371.
de Mello, Matheus Dorneles, & Tsapatsis, Michael. Selective Glucose‐to‐Fructose Isomerization over Modified Zirconium UiO‐66 in Alcohol Media. Germany. https://doi.org/10.1002/cctc.201800371
de Mello, Matheus Dorneles, and Tsapatsis, Michael. Tue .
"Selective Glucose‐to‐Fructose Isomerization over Modified Zirconium UiO‐66 in Alcohol Media". Germany. https://doi.org/10.1002/cctc.201800371.
@article{osti_1434389,
title = {Selective Glucose‐to‐Fructose Isomerization over Modified Zirconium UiO‐66 in Alcohol Media},
author = {de Mello, Matheus Dorneles and Tsapatsis, Michael},
abstractNote = {Abstract Modulated zirconium metal–organic framework UiO‐66 is shown to catalyze the isomerization of d ‐glucose to d ‐fructose in alcohol media. Fructose selectivity can change depending on solvent choice. We hypothesize that the difference in selectivity is related to a combined effect of adsorption and solvation effects, which may lead to the high formation of alkylglucosides in depletion of fructose if methanol or ethanol are used. A fructose selectivity of 72 % at 82 % glucose conversion in 1‐PrOH was achieved. The reaction mechanism was investigated using nuclear magnetic resonance spectroscopy. We demonstrate that UiO‐66 isomerizes glucose to fructose through an intramolecular C2–C1 hydride transfer. In addition, we show that modulated UiO‐66 is a highly active and stable catalyst at the reaction conditions, showing great potential for other sugar reactions.},
doi = {10.1002/cctc.201800371},
journal = {ChemCatChem},
number = 11,
volume = 10,
place = {Germany},
year = {Tue Apr 24 00:00:00 EDT 2018},
month = {Tue Apr 24 00:00:00 EDT 2018}
}
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