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Title: Imaging the halogen bond in self-assembled halogenbenzenes on silver

Authors:
ORCiD logo; ORCiD logo; ORCiD logo; ORCiD logo; ORCiD logo; ORCiD logo; ORCiD logo; ORCiD logo; ORCiD logo
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1434376
Grant/Contract Number:  
award220225; FG02-04ER15595,DE-FG02-06ER15826, DE-FG02-05ER46237
Resource Type:
Published Article
Journal Name:
Science
Additional Journal Information:
Journal Name: Science Journal Volume: 358 Journal Issue: 6360; Journal ID: ISSN 0036-8075
Publisher:
American Association for the Advancement of Science (AAAS)
Country of Publication:
United States
Language:
English

Citation Formats

Han, Zhumin, Czap, Gregory, Chiang, Chi-lun, Xu, Chen, Wagner, Peter J., Wei, Xinyuan, Zhang, Yanxing, Wu, Ruqian, and Ho, W. Imaging the halogen bond in self-assembled halogenbenzenes on silver. United States: N. p., 2017. Web. doi:10.1126/science.aai8625.
Han, Zhumin, Czap, Gregory, Chiang, Chi-lun, Xu, Chen, Wagner, Peter J., Wei, Xinyuan, Zhang, Yanxing, Wu, Ruqian, & Ho, W. Imaging the halogen bond in self-assembled halogenbenzenes on silver. United States. doi:10.1126/science.aai8625.
Han, Zhumin, Czap, Gregory, Chiang, Chi-lun, Xu, Chen, Wagner, Peter J., Wei, Xinyuan, Zhang, Yanxing, Wu, Ruqian, and Ho, W. Thu . "Imaging the halogen bond in self-assembled halogenbenzenes on silver". United States. doi:10.1126/science.aai8625.
@article{osti_1434376,
title = {Imaging the halogen bond in self-assembled halogenbenzenes on silver},
author = {Han, Zhumin and Czap, Gregory and Chiang, Chi-lun and Xu, Chen and Wagner, Peter J. and Wei, Xinyuan and Zhang, Yanxing and Wu, Ruqian and Ho, W.},
abstractNote = {},
doi = {10.1126/science.aai8625},
journal = {Science},
number = 6360,
volume = 358,
place = {United States},
year = {2017},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1126/science.aai8625

Citation Metrics:
Cited by: 36 works
Citation information provided by
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Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

The Halogen Bond
journal, January 2016


The Nature of Halogen⋅⋅⋅Halogen Interactions: A Model Derived from Experimental Charge-Density Analysis
journal, May 2009

  • Bui, Thai Thanh Thu; Dahaoui, Slimane; Lecomte, Claude
  • Angewandte Chemie International Edition, Vol. 48, Issue 21
  • DOI: 10.1002/anie.200805739

Direct Imaging of Covalent Bond Structure in Single-Molecule Chemical Reactions
journal, May 2013


Halogen Bonding in Supramolecular Chemistry
journal, August 2008

  • Metrangolo, Pierangelo; Meyer, Franck; Pilati, Tullio
  • Angewandte Chemie International Edition, Vol. 47, Issue 33
  • DOI: 10.1002/anie.200800128

A variable-temperature scanning tunneling microscope capable of single-molecule vibrational spectroscopy
journal, January 1999

  • Stipe, B. C.; Rezaei, M. A.; Ho, W.
  • Review of Scientific Instruments, Vol. 70, Issue 1
  • DOI: 10.1063/1.1149555

Differences in the Sublimation Energy of Benzene and Hexahalogenbenzenes Are Caused by Dispersion Energy
journal, May 2013

  • Trnka, Jakub; Sedlak, Robert; Kolář, Michal
  • The Journal of Physical Chemistry A, Vol. 117, Issue 20
  • DOI: 10.1021/jp401961g

Origin of the Contrast Interpreted as Intermolecular and Intramolecular Bonds in Atomic Force Microscopy Images
journal, June 2015

  • Guo, Chun-Sheng; Xin, Xiaojun; Van Hove, Michel A.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 25
  • DOI: 10.1021/acs.jpcc.5b02649

Halogen Bonding in Supramolecular Chemistry
journal, July 2015

  • Gilday, Lydia C.; Robinson, Sean W.; Barendt, Timothy A.
  • Chemical Reviews, Vol. 115, Issue 15
  • DOI: 10.1021/cr500674c

The Chemical Structure of a Molecule Resolved by Atomic Force Microscopy
journal, August 2009


Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Single-Molecule Vibrational Spectroscopy and Microscopy
journal, June 1998


A cartography of the van der Waals territories
journal, January 2013


Origin of High-Resolution IETS-STM Images of Organic Molecules with Functionalized Tips
journal, November 2014


Band Formation in a Molecular Quantum Well via 2D Superatom Orbital Interactions
journal, December 2012


Mechanism of high-resolution STM/AFM imaging with functionalized tips
journal, August 2014


Single-Molecule Resolution of an Organometallic Intermediate in a Surface-Supported Ullmann Coupling Reaction
journal, August 2011

  • Wang, Weihua; Shi, Xingqiang; Wang, Shiyong
  • Journal of the American Chemical Society, Vol. 133, Issue 34
  • DOI: 10.1021/ja204956b

An overview of halogen bonding
journal, September 2006

  • Politzer, Peter; Lane, Pat; Concha, Monica C.
  • Journal of Molecular Modeling, Vol. 13, Issue 2
  • DOI: 10.1007/s00894-006-0154-7

Halogen Bonds in Crystal Engineering: Like Hydrogen Bonds yet Different
journal, May 2014

  • Mukherjee, Arijit; Tothadi, Srinu; Desiraju, Gautam R.
  • Accounts of Chemical Research, Vol. 47, Issue 8
  • DOI: 10.1021/ar5001555

Material- and Orientation-Dependent Reactivity for Heterogeneously Catalyzed Carbon−Bromine Bond Homolysis
journal, June 2010

  • Walch, Hermann; Gutzler, Rico; Sirtl, Thomas
  • The Journal of Physical Chemistry C, Vol. 114, Issue 29
  • DOI: 10.1021/jp102704q

Chemical accuracy for the van der Waals density functional
journal, December 2009

  • Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
  • Journal of Physics: Condensed Matter, Vol. 22, Issue 2
  • DOI: 10.1088/0953-8984/22/2/022201

Halogen bonding: the σ-hole: Proceedings of “Modeling interactions in biomolecules II”, Prague, September 5th–9th, 2005
journal, August 2006

  • Clark, Timothy; Hennemann, Matthias; Murray, Jane S.
  • Journal of Molecular Modeling, Vol. 13, Issue 2
  • DOI: 10.1007/s00894-006-0130-2

The nature of halogen.cntdot..cntdot..cntdot.halogen interactions: are short halogen contacts due to specific attractive forces or due to close packing of nonspherical atoms?
journal, November 1989

  • Desiraju, Gautam R.; Parthasarathy, R.
  • Journal of the American Chemical Society, Vol. 111, Issue 23
  • DOI: 10.1021/ja00205a027

How Far Can We Push Chemical Self-Assembly?
journal, July 2005


Extended Halogen Bonding between Fully Fluorinated Aromatic Molecules
journal, February 2015

  • Kawai, Shigeki; Sadeghi, Ali; Xu, Feng
  • ACS Nano, Vol. 9, Issue 3
  • DOI: 10.1021/nn505876n

Image Distortions of a Partially Fluorinated Hydrocarbon Molecule in Atomic Force Microscopy with Carbon Monoxide Terminated Tips
journal, September 2014

  • Moll, Nikolaj; Schuler, Bruno; Kawai, Shigeki
  • Nano Letters, Vol. 14, Issue 11
  • DOI: 10.1021/nl502113z

C−H···F Interactions in the Crystal Structures of Some Fluorobenzenes
journal, September 1998

  • Thalladi, Venkat R.; Weiss, Hans-Christoph; Bläser, Dieter
  • Journal of the American Chemical Society, Vol. 120, Issue 34
  • DOI: 10.1021/ja981198e

Real-space imaging of molecular structure and chemical bonding by single-molecule inelastic tunneling probe
journal, May 2014


Visualizing Halogen Bonds in Planar Supramolecular Systems
journal, December 2010

  • Yoon, Jong Keon; Son, Won-joon; Chung, Kyung-Hoon
  • The Journal of Physical Chemistry C, Vol. 115, Issue 5
  • DOI: 10.1021/jp110891y

Halogen bonds in biological molecules
journal, November 2004

  • Auffinger, P.; Hays, F. A.; Westhof, E.
  • Proceedings of the National Academy of Sciences, Vol. 101, Issue 48
  • DOI: 10.1073/pnas.0407607101

STM investigations of C6Br6 on HOPG and MoS2
journal, October 1994


Assembling molecular Sierpiński triangle fractals
journal, March 2015

  • Shang, Jian; Wang, Yongfeng; Chen, Min
  • Nature Chemistry, Vol. 7, Issue 5
  • DOI: 10.1038/nchem.2211

Halogen BondingA Novel Interaction for Rational Drug Design?
journal, May 2009

  • Lu, Yunxiang; Shi, Ting; Wang, Yong
  • Journal of Medicinal Chemistry, Vol. 52, Issue 9
  • DOI: 10.1021/jm9000133

Halogen bonding: an electrostatically-driven highly directional noncovalent interaction
journal, January 2010

  • Politzer, Peter; Murray, Jane S.; Clark, Timothy
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 28
  • DOI: 10.1039/c004189k

Real-Space Identification of Intermolecular Bonding with Atomic Force Microscopy
journal, September 2013


Molecular Electronic Level Alignment at Weakly Coupled Organic Film/Metal Interfaces
journal, October 2014

  • Zhao, Jin; Feng, Min; Dougherty, Daniel Barker
  • ACS Nano, Vol. 8, Issue 10
  • DOI: 10.1021/nn5049969

Tribromobenzene on Cu(111): Temperature-dependent formation of halogen-bonded, organometallic, and covalent nanostructures
journal, March 2015

  • Fan, Qitang; Wang, Tao; Liu, Liming
  • The Journal of Chemical Physics, Vol. 142, Issue 10
  • DOI: 10.1063/1.4906214

Competition between Hexagonal and Tetragonal Hexabromobenzene Packing on Au(111)
journal, February 2016