skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid

Authors:
; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1434352
Grant/Contract Number:  
AC0206CH11357
Resource Type:
Published Article
Journal Name:
Science
Additional Journal Information:
Journal Name: Science Journal Volume: 353 Journal Issue: 6298; Journal ID: ISSN 0036-8075
Publisher:
American Association for the Advancement of Science (AAAS)
Country of Publication:
United States
Language:
English

Citation Formats

Asadi, Mohammad, Kim, Kibum, Liu, Cong, Addepalli, Aditya Venkata, Abbasi, Pedram, Yasaei, Poya, Phillips, Patrick, Behranginia, Amirhossein, Cerrato, José M., Haasch, Richard, Zapol, Peter, Kumar, Bijandra, Klie, Robert F., Abiade, Jeremiah, Curtiss, Larry A., and Salehi-Khojin, Amin. Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid. United States: N. p., 2016. Web. doi:10.1126/science.aaf4767.
Asadi, Mohammad, Kim, Kibum, Liu, Cong, Addepalli, Aditya Venkata, Abbasi, Pedram, Yasaei, Poya, Phillips, Patrick, Behranginia, Amirhossein, Cerrato, José M., Haasch, Richard, Zapol, Peter, Kumar, Bijandra, Klie, Robert F., Abiade, Jeremiah, Curtiss, Larry A., & Salehi-Khojin, Amin. Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid. United States. doi:10.1126/science.aaf4767.
Asadi, Mohammad, Kim, Kibum, Liu, Cong, Addepalli, Aditya Venkata, Abbasi, Pedram, Yasaei, Poya, Phillips, Patrick, Behranginia, Amirhossein, Cerrato, José M., Haasch, Richard, Zapol, Peter, Kumar, Bijandra, Klie, Robert F., Abiade, Jeremiah, Curtiss, Larry A., and Salehi-Khojin, Amin. Thu . "Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid". United States. doi:10.1126/science.aaf4767.
@article{osti_1434352,
title = {Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid},
author = {Asadi, Mohammad and Kim, Kibum and Liu, Cong and Addepalli, Aditya Venkata and Abbasi, Pedram and Yasaei, Poya and Phillips, Patrick and Behranginia, Amirhossein and Cerrato, José M. and Haasch, Richard and Zapol, Peter and Kumar, Bijandra and Klie, Robert F. and Abiade, Jeremiah and Curtiss, Larry A. and Salehi-Khojin, Amin},
abstractNote = {},
doi = {10.1126/science.aaf4767},
journal = {Science},
number = 6298,
volume = 353,
place = {United States},
year = {2016},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1126/science.aaf4767

Citation Metrics:
Cited by: 298 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012

  • Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
  • DOI: 10.1021/ja3010978

Selective Conversion of CO 2 to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst
journal, June 2013

  • DiMeglio, John L.; Rosenthal, Joel
  • Journal of the American Chemical Society, Vol. 135, Issue 24
  • DOI: 10.1021/ja4033549

A lithium–oxygen battery based on lithium superoxide
journal, January 2016

  • Lu, Jun; Jung Lee, Yun; Luo, Xiangyi
  • Nature, Vol. 529, Issue 7586, p. 377-382
  • DOI: 10.1038/nature16484

Particle Size Effects in the Catalytic Electroreduction of CO 2 on Cu Nanoparticles
journal, May 2014

  • Reske, Rulle; Mistry, Hemma; Behafarid, Farzad
  • Journal of the American Chemical Society, Vol. 136, Issue 19
  • DOI: 10.1021/ja500328k

Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
journal, February 2011


Few-Layer MoSe2 Possessing High Catalytic Activity towards Iodide/Tri-iodide Redox Shuttles
journal, February 2014

  • Lee, Lawrence Tien Lin; He, Jian; Wang, Baohua
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep04063

Capacitance of the gold electrode in 0.5 M H2SO4 solution: a.c. impedance studies
journal, May 1995


Nanoparticle Silver Catalysts That Show Enhanced Activity for Carbon Dioxide Electrolysis
journal, January 2013

  • Salehi-Khojin, Amin; Jhong, Huei-Ru Molly; Rosen, Brian A.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 4
  • DOI: 10.1021/jp310509z

In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
journal, August 2008


Efficient Reduction of CO 2 to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials
journal, May 2014

  • Medina-Ramos, Jonnathan; DiMeglio, John L.; Rosenthal, Joel
  • Journal of the American Chemical Society, Vol. 136, Issue 23
  • DOI: 10.1021/ja501923g

A renewable amine for photochemical reduction of CO2
journal, February 2011

  • Richardson, Robert D.; Holland, Edward J.; Carpenter, Barry K.
  • Nature Chemistry, Vol. 3, Issue 4
  • DOI: 10.1038/nchem.1000

Amorphous Molybdenum Sulfide Catalysts for Electrochemical Hydrogen Production: Insights into the Origin of their Catalytic Activity
journal, August 2012

  • Benck, Jesse D.; Chen, Zhebo; Kuritzky, Leah Y.
  • ACS Catalysis, Vol. 2, Issue 9, p. 1916-1923
  • DOI: 10.1021/cs300451q

Size-Dependent Electrocatalytic Reduction of CO 2 over Pd Nanoparticles
journal, March 2015

  • Gao, Dunfeng; Zhou, Hu; Wang, Jing
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/jacs.5b00046

Molybdenum Sulfide/N-Doped CNT Forest Hybrid Catalysts for High-Performance Hydrogen Evolution Reaction
journal, February 2014

  • Li, Dong Jun; Maiti, Uday Narayan; Lim, Joonwon
  • Nano Letters, Vol. 14, Issue 3
  • DOI: 10.1021/nl404108a

Water Enhancement of CO2 Conversion on Silver in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate
journal, November 2012

  • Rosen, B. A.; Zhu, W.; Kaul, G.
  • Journal of the Electrochemical Society, Vol. 160, Issue 2, p. H138-H141
  • DOI: 10.1149/2.004303jes

High-Quality Black Phosphorus Atomic Layers by Liquid-Phase Exfoliation
journal, February 2015

  • Yasaei, Poya; Kumar, Bijandra; Foroozan, Tara
  • Advanced Materials, Vol. 27, Issue 11
  • DOI: 10.1002/adma.201405150

Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex
journal, January 2010


Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction
journal, December 2013

  • Kumar, Bijandra; Asadi, Mohammad; Pisasale, Davide
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3819

Wireless Solar Water Splitting Using Silicon-Based Semiconductors and Earth-Abundant Catalysts
journal, September 2011


Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Exceptional Size-Dependent Activity Enhancement in the Electroreduction of CO 2 over Au Nanoparticles
journal, November 2014

  • Mistry, Hemma; Reske, Rulle; Zeng, Zhenhua
  • Journal of the American Chemical Society, Vol. 136, Issue 47
  • DOI: 10.1021/ja508879j

Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
journal, October 2012

  • Kibsgaard, Jakob; Chen, Zhebo; Reinecke, Benjamin N.
  • Nature Materials, Vol. 11, Issue 11, p. 963-969
  • DOI: 10.1038/nmat3439

Designing Electrical Contacts to MoS 2 Monolayers: A Computational Study
journal, April 2012


Optical signature of symmetry variations and spin-valley coupling in atomically thin tungsten dichalcogenides
journal, April 2013

  • Zeng, Hualing; Liu, Gui-Bin; Dai, Junfeng
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep01608

Selective Photoelectrochemical Reduction of Aqueous CO 2 to CO by Solvated Electrons
journal, July 2014

  • Zhang, Linghong; Zhu, Di; Nathanson, Gilbert M.
  • Angewandte Chemie International Edition, Vol. 53, Issue 37
  • DOI: 10.1002/anie.201404328

Why gold is the noblest of all the metals
journal, July 1995


Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo3S13]2− clusters
journal, January 2014

  • Kibsgaard, Jakob; Jaramillo, Thomas F.; Besenbacher, Flemming
  • Nature Chemistry, Vol. 6, Issue 3
  • DOI: 10.1038/nchem.1853

Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials
journal, September 2011

  • Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.
  • Science, Vol. 334, Issue 6056, p. 643-644
  • DOI: 10.1126/science.1209786

Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO 2 Reduction to CO
journal, January 2013

  • Hansen, Heine A.; Varley, Joel B.; Peterson, Andrew A.
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 3
  • DOI: 10.1021/jz3021155

Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH
journal, November 2010

  • Surendranath, Yogesh; Kanan, Matthew W.; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 132, Issue 46
  • DOI: 10.1021/ja106102b

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
journal, November 2012

  • Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras
  • Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712
  • DOI: 10.1038/nnano.2012.193

Metal Contacts on Physical Vapor Deposited Monolayer MoS 2
journal, November 2013

  • Gong, Cheng; Huang, Chunming; Miller, Justin
  • ACS Nano, Vol. 7, Issue 12
  • DOI: 10.1021/nn4052138

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Robust carbon dioxide reduction on molybdenum disulphide edges
journal, July 2014

  • Asadi, Mohammad; Kumar, Bijandra; Behranginia, Amirhossein
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5470

A Self-Healing Oxygen-Evolving Catalyst
journal, March 2009

  • Lutterman, Daniel A.; Surendranath, Yogesh; Nocera, Daniel G.
  • Journal of the American Chemical Society, Vol. 131, Issue 11
  • DOI: 10.1021/ja900023k

Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO
journal, October 2013

  • Zhu, Wenlei; Michalsky, Ronald; Metin, Önder
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja409445p

How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
journal, January 2010

  • Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix
  • Energy & Environmental Science, Vol. 3, Issue 9
  • DOI: 10.1039/c0ee00071j

Tuning the MoS 2 Edge-Site Activity for Hydrogen Evolution via Support Interactions
journal, February 2014

  • Tsai, Charlie; Abild-Pedersen, Frank; Nørskov, Jens K.
  • Nano Letters, Vol. 14, Issue 3
  • DOI: 10.1021/nl404444k

Strong light–matter coupling in two-dimensional atomic crystals
journal, December 2014


Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
journal, November 2004

  • Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 46
  • DOI: 10.1021/jp047349j

Monolayer MoS 2 Films Supported by 3D Nanoporous Metals for High-Efficiency Electrocatalytic Hydrogen Production
journal, October 2014


Cathode Based on Molybdenum Disulfide Nanoflakes for Lithium–Oxygen Batteries
journal, January 2016


Unusually Small Electrical Resistance of Three-Dimensional Nanoporous Gold in External Magnetic Fields
journal, October 2008


Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts
journal, July 2007

  • Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J.
  • Science, Vol. 317, Issue 5834, p. 100-102
  • DOI: 10.1126/science.1141483

Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
journal, November 2012

  • Chen, Yihong; Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 49
  • DOI: 10.1021/ja309317u

Theoretical surface science and catalysis—calculations and concepts
book, January 2000


Surface-induced resistivity of ultrathin metallic films: A limit law
journal, March 1989