Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction
Abstract
FePt bimetallic catalysts with intimate contact between the two metals were synthesized by controlled surface reactions (CSR) of (cyclohexadiene)iron tricarbonyl with hydrogen-treated supported Pt nanoparticles. Adsorption of the iron precursor on a Pt/SiO2 catalyst was studied, showing that the Fe loading could be increased by performing multiple CSR cycles, and the efficiency of this process was linked to the renewal of adsorption sites by a reducing pretreatment. Here, the catalytic activity of these bimetallic catalysts for the water gas shift reaction was improved due to promotion by iron, likely linked to H2O activation on FeOx species at or near the Pt surface, mostly in the (II) oxidation state.
- Authors:
-
- Univ. of Campinas (UNICAMP), Sao Paulo (Brazil); Univ. of Wisconsin-Madison, Madison, WI (United States)
- Univ. of Wisconsin-Madison, Madison, WI (United States)
- Univ. of Campinas (UNICAMP), Sao Paulo (Brazil)
- Publication Date:
- Research Org.:
- Univ. of Wisconsin, Madison, WI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Org.:
- Brazilian Synchrotron Light Laboratory (LNLS) and Advanced Photon Source at Argonne National Laboratory.
- OSTI Identifier:
- 1434303
- Alternate Identifier(s):
- OSTI ID: 1549371
- Grant/Contract Number:
- SC0014058; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Catalysis B: Environmental
- Additional Journal Information:
- Journal Volume: 222; Journal Issue: C; Journal ID: ISSN 0926-3373
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Bimetallic catalyst; FePt; Controlled surface reactions (CSR); Water-gas shift reaction (WGSR)
Citation Formats
Aragao, Isaias Barbosa, Ro, Insoo, Liu, Yifei, Ball, Madelyn, Huber, George W., Zanchet, Daniela, and Dumesic, James A. Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction. United States: N. p., 2017.
Web. doi:10.1016/j.apcatb.2017.10.004.
Aragao, Isaias Barbosa, Ro, Insoo, Liu, Yifei, Ball, Madelyn, Huber, George W., Zanchet, Daniela, & Dumesic, James A. Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction. United States. https://doi.org/10.1016/j.apcatb.2017.10.004
Aragao, Isaias Barbosa, Ro, Insoo, Liu, Yifei, Ball, Madelyn, Huber, George W., Zanchet, Daniela, and Dumesic, James A. Wed .
"Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction". United States. https://doi.org/10.1016/j.apcatb.2017.10.004. https://www.osti.gov/servlets/purl/1434303.
@article{osti_1434303,
title = {Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction},
author = {Aragao, Isaias Barbosa and Ro, Insoo and Liu, Yifei and Ball, Madelyn and Huber, George W. and Zanchet, Daniela and Dumesic, James A.},
abstractNote = {FePt bimetallic catalysts with intimate contact between the two metals were synthesized by controlled surface reactions (CSR) of (cyclohexadiene)iron tricarbonyl with hydrogen-treated supported Pt nanoparticles. Adsorption of the iron precursor on a Pt/SiO2 catalyst was studied, showing that the Fe loading could be increased by performing multiple CSR cycles, and the efficiency of this process was linked to the renewal of adsorption sites by a reducing pretreatment. Here, the catalytic activity of these bimetallic catalysts for the water gas shift reaction was improved due to promotion by iron, likely linked to H2O activation on FeOx species at or near the Pt surface, mostly in the (II) oxidation state.},
doi = {10.1016/j.apcatb.2017.10.004},
journal = {Applied Catalysis B: Environmental},
number = C,
volume = 222,
place = {United States},
year = {Wed Oct 04 00:00:00 EDT 2017},
month = {Wed Oct 04 00:00:00 EDT 2017}
}
Web of Science
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