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Title: Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity

Vanadium is the main competitor for uranium extraction from seawater, and V( iv ) comprises a minor but important portion of this. V( iv ) undergoes redox reactions with oximes and amidoxime ligands under seawater-relevant conditions, leading to V( v ) complexes and loss of oxime functional groups.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [1] ;  [2] ; ORCiD logo [3] ; ORCiD logo [1] ; ORCiD logo [2]
  1. Department of Chemistry, University of California – Berkeley, Berkeley, USA, Chemical Sciences Division
  2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
  3. EaStCHEM School of Chemistry, University of Edinburgh, Edinburgh, UK
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 16; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1434189

Parker, B. F., Hohloch, S., Pankhurst, J. R., Zhang, Z., Love, J. B., Arnold, J., and Rao, L.. Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity. United Kingdom: N. p., Web. doi:10.1039/C7DT04069E.
Parker, B. F., Hohloch, S., Pankhurst, J. R., Zhang, Z., Love, J. B., Arnold, J., & Rao, L.. Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity. United Kingdom. doi:10.1039/C7DT04069E.
Parker, B. F., Hohloch, S., Pankhurst, J. R., Zhang, Z., Love, J. B., Arnold, J., and Rao, L.. 2018. "Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity". United Kingdom. doi:10.1039/C7DT04069E.
@article{osti_1434189,
title = {Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity},
author = {Parker, B. F. and Hohloch, S. and Pankhurst, J. R. and Zhang, Z. and Love, J. B. and Arnold, J. and Rao, L.},
abstractNote = {Vanadium is the main competitor for uranium extraction from seawater, and V( iv ) comprises a minor but important portion of this. V( iv ) undergoes redox reactions with oximes and amidoxime ligands under seawater-relevant conditions, leading to V( v ) complexes and loss of oxime functional groups.},
doi = {10.1039/C7DT04069E},
journal = {Dalton Transactions},
number = 16,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}