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This content will become publicly available on April 10, 2019

Title: Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity

Vanadium is the main competitor for uranium extraction from seawater, and V( iv ) comprises a minor but important portion of this. V( iv ) undergoes redox reactions with oximes and amidoxime ligands under seawater-relevant conditions, leading to V( v ) complexes and loss of oxime functional groups.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [1] ;  [2] ; ORCiD logo [3] ; ORCiD logo [1] ; ORCiD logo [2]
  1. Department of Chemistry, University of California – Berkeley, Berkeley, USA, Chemical Sciences Division
  2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
  3. EaStCHEM School of Chemistry, University of Edinburgh, Edinburgh, UK
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 16; Related Information: CHORUS Timestamp: 2018-04-24 05:16:38; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1434189