Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity

Parker, B. F.; Hohloch, S.; Pankhurst, J. R.; Zhang, Z.; Love, J. B.; Arnold, J.; Rao, L.

doi:10.1039/C7DT04069E

Title: Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity

Journal Article · 01 January 2018 · Dalton Transactions

DOI: https://doi.org/10.1039/C7DT04069E · OSTI ID:1434189

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Department of Chemistry, University of California – Berkeley, Berkeley, USA, Chemical Sciences Division
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
EaStCHEM School of Chemistry, University of Edinburgh, Edinburgh, UK

Vanadium is the main competitor for uranium extraction from seawater, and V( iv ) comprises a minor but important portion of this. V( iv ) undergoes redox reactions with oximes and amidoxime ligands under seawater-relevant conditions, leading to V( v ) complexes and loss of oxime functional groups.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1434189

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 16 Vol. 47; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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