Reconfigurable Printed Liquids

Journal Article · 24 March 2018 · Advanced Materials

DOI: https://doi.org/10.1002/adma.201707603 · OSTI ID:1434175

Forth, Joe ^[1]; Liu, Xubo ^[2]; Hasnain, Jaffar ^[3]; Toor, Anju ^[4]; Miszta, Karol ^[5]; Shi, Shaowei ^[2]; Geissler, Phillip L. ^[6]; Emrick, Todd ^[7]; Helms, Brett A. ^[8]; Russell, Thomas P.  ^[9]

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1. Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA
2. Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing Beijing University of Chemical Technology Beijing 100029 China
3. Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA, Department of Chemistry University of California Berkeley CA 94720 USA
4. Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA, Department of Mechanical Engineering University of California Berkeley CA 94720 USA
5. The Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
6. Department of Chemistry University of California Berkeley CA 94720 USA, Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
7. Polymer Science and Engineering Department Conte Center for Polymer Research University of Massachusetts 120 Governors Drive Amherst MA 01003 USA
8. Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA, The Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
9. Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA; Beijing Advanced Innovation Center for Soft Matter Science and Engineering; Beijing Beijing University of Chemical Technology Beijing 100029 China; Polymer Science and Engineering Department Conte Center for Polymer Research University of Massachusetts 120 Governors Drive Amherst MA 01003 USA; WPI – Advanced Institute for Materials Research (WPI‐AIMR) Tohoku University 2‐1‐1 Katahira Aoba Sendai 980‐8577 Japan

Abstract Liquids lack the spatial order required for advanced functionality. Interfacial assemblies of colloids, however, can be used to shape liquids into complex, 3D objects, simultaneously forming 2D layers with novel magnetic, plasmonic, or structural properties. Fully exploiting all‐liquid systems that are structured by their interfaces would create a new class of biomimetic, reconfigurable, and responsive materials. Here, printed constructs of water in oil are presented. Both form and function are given to the system by the assembly and jamming of nanoparticle surfactants, formed from the interfacial interaction of nanoparticles and amphiphilic polymers that bear complementary functional groups. These yield dissipative constructs that exhibit a compartmentalized response to chemical cues. Potential applications include biphasic reaction vessels, liquid electronics, novel media for the encapsulation of cells and active matter, and dynamic constructs that both alter, and are altered by, their external environment.

• Sponsoring Organization: USDOE
• Grant/Contract Number: AC02-05CH11231
• OSTI ID: 1434175
• Journal Information: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 16 Vol. 30; ISSN 0935-9648
• Publisher: Wiley Blackwell (John Wiley & Sons)Copyright Statement
• Country of Publication: Germany
• Language: English