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Title: An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes

A single electron reduction of an iron bis(verdazyl) complex results in a large change in spin multiplicity resulting from a combination of spin crossover and exceptionally strong ferromagnetic exchange.
Authors:
ORCiD logo [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [2] ; ORCiD logo [2] ;  [3] ; ORCiD logo [4]
  1. Department of Chemistry, San José State University, San José, USA
  2. Department of Physics, University of South Florida, Tampa, USA
  3. Department of Physics and Astronomy, San José State University, San José, USA
  4. Bruker AXS Inc., Madison, USA
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 18; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1434164

Brook, David J. R., Fleming, Connor, Chung, Dorothy, Richardson, Cardius, Ponce, Servando, Das, Raja, Srikanth, Hariharan, Heindl, Ranko, and Noll, Bruce C.. An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes. United Kingdom: N. p., Web. doi:10.1039/C8DT00805A.
Brook, David J. R., Fleming, Connor, Chung, Dorothy, Richardson, Cardius, Ponce, Servando, Das, Raja, Srikanth, Hariharan, Heindl, Ranko, & Noll, Bruce C.. An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes. United Kingdom. doi:10.1039/C8DT00805A.
Brook, David J. R., Fleming, Connor, Chung, Dorothy, Richardson, Cardius, Ponce, Servando, Das, Raja, Srikanth, Hariharan, Heindl, Ranko, and Noll, Bruce C.. 2018. "An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes". United Kingdom. doi:10.1039/C8DT00805A.
@article{osti_1434164,
title = {An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes},
author = {Brook, David J. R. and Fleming, Connor and Chung, Dorothy and Richardson, Cardius and Ponce, Servando and Das, Raja and Srikanth, Hariharan and Heindl, Ranko and Noll, Bruce C.},
abstractNote = {A single electron reduction of an iron bis(verdazyl) complex results in a large change in spin multiplicity resulting from a combination of spin crossover and exceptionally strong ferromagnetic exchange.},
doi = {10.1039/C8DT00805A},
journal = {Dalton Transactions},
number = 18,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}

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