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This content will become publicly available on April 6, 2019

Title: An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes

A single electron reduction of an iron bis(verdazyl) complex results in a large change in spin multiplicity resulting from a combination of spin crossover and exceptionally strong ferromagnetic exchange.
Authors:
ORCiD logo [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [2] ; ORCiD logo [2] ;  [3] ; ORCiD logo [4]
  1. Department of Chemistry, San José State University, San José, USA
  2. Department of Physics, University of South Florida, Tampa, USA
  3. Department of Physics and Astronomy, San José State University, San José, USA
  4. Bruker AXS Inc., Madison, USA
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 18; Related Information: CHORUS Timestamp: 2018-05-08 04:45:19; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1434164