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Title: Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework

An ultrahigh proton conductivity of 2.91 × 10 −2 S cm −1 and an ultralow activation energy of 0.10 eV were observed in an anionic lanthanide-organic framework. Both values approach the records for proton-conducting MOF materials.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ; ORCiD logo [1]
  1. State Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China
Publication Date:
Grant/Contract Number:
SC0016568
Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 54 Journal Issue: 35; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1434138

Wang, Xia, Wang, Yanlong, Silver, Mark A., Gui, Daxiang, Bai, Zhuanling, Wang, Yaxing, Liu, Wei, Chen, Lanhua, Diwu, Juan, Chai, Zhifang, and Wang, Shuao. Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework. United Kingdom: N. p., Web. doi:10.1039/C8CC00572A.
Wang, Xia, Wang, Yanlong, Silver, Mark A., Gui, Daxiang, Bai, Zhuanling, Wang, Yaxing, Liu, Wei, Chen, Lanhua, Diwu, Juan, Chai, Zhifang, & Wang, Shuao. Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework. United Kingdom. doi:10.1039/C8CC00572A.
Wang, Xia, Wang, Yanlong, Silver, Mark A., Gui, Daxiang, Bai, Zhuanling, Wang, Yaxing, Liu, Wei, Chen, Lanhua, Diwu, Juan, Chai, Zhifang, and Wang, Shuao. 2018. "Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework". United Kingdom. doi:10.1039/C8CC00572A.
@article{osti_1434138,
title = {Superprotonic conduction through one-dimensional ordered alkali metal ion chains in a lanthanide-organic framework},
author = {Wang, Xia and Wang, Yanlong and Silver, Mark A. and Gui, Daxiang and Bai, Zhuanling and Wang, Yaxing and Liu, Wei and Chen, Lanhua and Diwu, Juan and Chai, Zhifang and Wang, Shuao},
abstractNote = {An ultrahigh proton conductivity of 2.91 × 10 −2 S cm −1 and an ultralow activation energy of 0.10 eV were observed in an anionic lanthanide-organic framework. Both values approach the records for proton-conducting MOF materials.},
doi = {10.1039/C8CC00572A},
journal = {Chemical Communications},
number = 35,
volume = 54,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Single-crystal structure validation with the program PLATON
journal, January 2003