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Title: From a Au-rich core/PtNi-rich shell to a Ni-rich core/PtAu-rich shell: an effective thermochemical pathway to nanoengineering catalysts for fuel cells

Abstract

A major challenge for the design of noble metal nanocatalysts is the ability of surface engineering to enhance the activity and stability with minimum use of the noble metals.

Authors:
 [1];  [2]; ORCiD logo [1];  [1];  [2];  [2];  [2];  [2]; ORCiD logo [1];  [1];  [1];  [1];  [2];  [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [2]
  1. Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Department of Materials Science and Engineering, College of Materials, Xiamen University
  2. Department of Chemistry, State University of New York at Binghamton, Binghamton, USA
  3. Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, USA
  4. Department of Physics, Central Michigan University, Mt Pleasant, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1434128
Grant/Contract Number:  
SC0006877
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry A Journal Volume: 6 Journal Issue: 12; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lu, Aolin, Wu, Zhi-Peng, Chen, Binghui, Peng, Dong-Liang, Yan, Shan, Shan, Shiyao, Skeete, Zakiya, Chang, Fangfang, Chen, Yuanzhi, Zheng, Hongfei, Zeng, Deqian, Yang, Lefu, Sharma, Anju, Luo, Jin, Wang, Lichang, Petkov, Valeri, and Zhong, Chuan-Jian. From a Au-rich core/PtNi-rich shell to a Ni-rich core/PtAu-rich shell: an effective thermochemical pathway to nanoengineering catalysts for fuel cells. United Kingdom: N. p., 2018. Web. doi:10.1039/C8TA00025E.
Lu, Aolin, Wu, Zhi-Peng, Chen, Binghui, Peng, Dong-Liang, Yan, Shan, Shan, Shiyao, Skeete, Zakiya, Chang, Fangfang, Chen, Yuanzhi, Zheng, Hongfei, Zeng, Deqian, Yang, Lefu, Sharma, Anju, Luo, Jin, Wang, Lichang, Petkov, Valeri, & Zhong, Chuan-Jian. From a Au-rich core/PtNi-rich shell to a Ni-rich core/PtAu-rich shell: an effective thermochemical pathway to nanoengineering catalysts for fuel cells. United Kingdom. doi:10.1039/C8TA00025E.
Lu, Aolin, Wu, Zhi-Peng, Chen, Binghui, Peng, Dong-Liang, Yan, Shan, Shan, Shiyao, Skeete, Zakiya, Chang, Fangfang, Chen, Yuanzhi, Zheng, Hongfei, Zeng, Deqian, Yang, Lefu, Sharma, Anju, Luo, Jin, Wang, Lichang, Petkov, Valeri, and Zhong, Chuan-Jian. Mon . "From a Au-rich core/PtNi-rich shell to a Ni-rich core/PtAu-rich shell: an effective thermochemical pathway to nanoengineering catalysts for fuel cells". United Kingdom. doi:10.1039/C8TA00025E.
@article{osti_1434128,
title = {From a Au-rich core/PtNi-rich shell to a Ni-rich core/PtAu-rich shell: an effective thermochemical pathway to nanoengineering catalysts for fuel cells},
author = {Lu, Aolin and Wu, Zhi-Peng and Chen, Binghui and Peng, Dong-Liang and Yan, Shan and Shan, Shiyao and Skeete, Zakiya and Chang, Fangfang and Chen, Yuanzhi and Zheng, Hongfei and Zeng, Deqian and Yang, Lefu and Sharma, Anju and Luo, Jin and Wang, Lichang and Petkov, Valeri and Zhong, Chuan-Jian},
abstractNote = {A major challenge for the design of noble metal nanocatalysts is the ability of surface engineering to enhance the activity and stability with minimum use of the noble metals.},
doi = {10.1039/C8TA00025E},
journal = {Journal of Materials Chemistry A},
number = 12,
volume = 6,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8TA00025E

Citation Metrics:
Cited by: 2 works
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Works referenced in this record:

Rapid Microwave-Assisted Polyol Reduction for the Preparation of Highly Active PtNi/CNT Electrocatalysts for Methanol Oxidation
journal, June 2014

  • Nassr, Abu Bakr Ahmed Amine; Sinev, Ilya; Pohl, Marga-Martina
  • ACS Catalysis, Vol. 4, Issue 8
  • DOI: 10.1021/cs401140g

New PtRu Alloy Colloids as Precursors for Fuel Cell Catalysts
journal, October 2000

  • Paulus, U. A.; Endruschat, U.; Feldmeyer, G. J.
  • Journal of Catalysis, Vol. 195, Issue 2
  • DOI: 10.1006/jcat.2000.2998

Structure-dependent surface core level shifts for the Au(111), (100), and (110) surfaces
journal, May 1981


Core/Shell Au/CuPt Nanoparticles and Their Dual Electrocatalysis for Both Reduction and Oxidation Reactions
journal, April 2014

  • Sun, Xiaolian; Li, Dongguo; Ding, Yong
  • Journal of the American Chemical Society, Vol. 136, Issue 15
  • DOI: 10.1021/ja500590n

Surface relaxation and stress of fcc metals: Cu, Ag, Au, Ni, Pd, Pt, Al and Pb
journal, January 1999

  • Wan, Jun; Fan, Y. L.; Gong, D. W.
  • Modelling and Simulation in Materials Science and Engineering, Vol. 7, Issue 2
  • DOI: 10.1088/0965-0393/7/2/005

Role of Support–Nanoalloy Interactions in the Atomic-Scale Structural and Chemical Ordering for Tuning Catalytic Sites
journal, August 2012

  • Yang, Lefu; Shan, Shiyao; Loukrakpam, Rameshwori
  • Journal of the American Chemical Society, Vol. 134, Issue 36
  • DOI: 10.1021/ja3060035

Characterization of Carbon-Supported AuPt Nanoparticles for Electrocatalytic Methanol Oxidation Reaction
journal, March 2006

  • Luo, Jin; Njoki, Peter N.; Lin, Yan
  • Langmuir, Vol. 22, Issue 6
  • DOI: 10.1021/la0529557

Novel electrocatalysts for direct methanol fuel cells
journal, June 2002


A first principles comparison of the mechanism and site requirements for the electrocatalytic oxidation of methanol and formic acid over Pt
journal, January 2009

  • Neurock, Matthew; Janik, Michael; Wieckowski, Andrzej
  • Faraday Discuss., Vol. 140
  • DOI: 10.1039/B804591G

Synergistic activity of gold-platinum alloy nanoparticle catalysts
journal, April 2007


Pt–Au Alloying at the Nanoscale
journal, July 2012

  • Petkov, Valeri; Wanjala, Bridgid N.; Loukrakpam, Rameshwori
  • Nano Letters, Vol. 12, Issue 8
  • DOI: 10.1021/nl302329n

Electronegativities of the Elements
journal, February 1956

  • Gordy, Walter; Thomas, W. J. Orville
  • The Journal of Chemical Physics, Vol. 24, Issue 2
  • DOI: 10.1063/1.1742493

Composition- and Structure-Tunable Gold–Cobalt Nanoparticles and Electrocatalytic Synergy for Oxygen Evolution Reaction
journal, July 2016

  • Lu, Aolin; Peng, Dong-Liang; Chang, Fangfang
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 31
  • DOI: 10.1021/acsami.6b06087

Investigation of Methanol Oxidation over Au/Catalysts Using Operando IR Spectroscopy: Determination of the Active Sites, Intermediate/Spectator Species, and Reaction Mechanism
journal, August 2010

  • Rousseau, Séverine; Marie, Olivier; Bazin, Philippe
  • Journal of the American Chemical Society, Vol. 132, Issue 31
  • DOI: 10.1021/ja1028809

Electrocatalysis of methanol oxidation
journal, August 2002


Sophisticated Construction of Au Islands on Pt–Ni: An Ideal Trimetallic Nanoframe Catalyst
journal, August 2014

  • Wu, Yuen; Wang, Dingsheng; Zhou, Gang
  • Journal of the American Chemical Society, Vol. 136, Issue 33
  • DOI: 10.1021/ja5058532

Core/Shell Nanoparticles as Electrocatalysts for Fuel Cell Reactions
journal, November 2008


Nanoengineered PtCo and PtNi Catalysts for Oxygen Reduction Reaction: An Assessment of the Structural and Electrocatalytic Properties
journal, December 2010

  • Loukrakpam, Rameshwori; Luo, Jin; He, Ting
  • The Journal of Physical Chemistry C, Vol. 115, Issue 5
  • DOI: 10.1021/jp109630n

Structure-Induced Enhancement in Electrooxidation of Trimetallic FePtAu Nanoparticles
journal, March 2012

  • Zhang, Sen; Guo, Shaojun; Zhu, Huiyuan
  • Journal of the American Chemical Society, Vol. 134, Issue 11
  • DOI: 10.1021/ja300708j

Controlled synthesis of platinum catalysts on Au nanoparticles and their electrocatalytic property for methanol oxidation
journal, November 2004


One-Pot Fabrication of Mesoporous Core–Shell Au@PtNi Ternary Metallic Nanoparticles and Their Enhanced Efficiency for Oxygen Reduction Reaction
journal, February 2016

  • Shi, Qiurong; Zhu, Chengzhou; Fu, Shaofang
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 7
  • DOI: 10.1021/acsami.5b12407

Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks
journal, January 2017

  • Barkholtz, Heather M.; Liu, Di-Jia
  • Materials Horizons, Vol. 4, Issue 1
  • DOI: 10.1039/C6MH00344C

Dual Path Mechanism in Methanol Electrooxidation on a Platinum Electrode
journal, June 1995

  • Herrero, E.; Chrzanowski, W.; Wieckowski, A.
  • The Journal of Physical Chemistry, Vol. 99, Issue 25
  • DOI: 10.1021/j100025a054

Electrocatalytic oxidation of methanol: carbon-supported gold–platinum nanoparticle catalysts prepared by two-phase protocol
journal, January 2005


Multimetallic Core/Interlayer/Shell Nanostructures as Advanced Electrocatalysts
journal, October 2014

  • Kang, Yijin; Snyder, Joshua; Chi, Miaofang
  • Nano Letters, Vol. 14, Issue 11
  • DOI: 10.1021/nl5028205

Interface Controlled Oxidation States in Layered Cobalt Oxide Nanoislands on Gold
journal, February 2015


Heterogeneous electrocatalysis: a core field of interfacial science
journal, March 2000


Ternary NiAuPt Nanoparticles on Reduced Graphene Oxide as Catalysts toward the Electrochemical Oxidation Reaction of Ethanol
journal, January 2015

  • Dutta, Abhijit; Ouyang, Jianyong
  • ACS Catalysis, Vol. 5, Issue 2
  • DOI: 10.1021/cs501365y

Well-Dispersed PtAu Nanoparticles Loaded into Anodic Titania Nanotubes:  A High Antipoison and Stable Catalyst System for Methanol Oxidation in Alkaline Media
journal, November 2007

  • Yang, Lixia; Yang, Wenyue; Cai, Qingyun
  • The Journal of Physical Chemistry C, Vol. 111, Issue 44
  • DOI: 10.1021/jp0727695

Anchoring Effect of Exfoliated-Montmorillonite-Supported Pd Catalyst for the Oxygen Reduction Reaction
journal, May 2013

  • Xia, Meirong; Ding, Wei; Xiong, Kun
  • The Journal of Physical Chemistry C, Vol. 117, Issue 20
  • DOI: 10.1021/jp402367g

Yttrium Oxide/Gadolinium Oxide-Modified Platinum Nanoparticles as Cathodes for the Oxygen Reduction Reaction
journal, May 2014


Gold-platinum nanoparticles: alloying and phase segregation
journal, January 2011

  • Wanjala, Bridgid Nekesa; Luo, Jin; Fang, Bin
  • J. Mater. Chem., Vol. 21, Issue 12
  • DOI: 10.1039/C0JM02682D

Nanoporous PtCo and PtNi alloy ribbons for methanol electrooxidation
journal, July 2012


Methanol Oxidation at Pt−Cu, Pt−Ni, and Pt−Co Electrode Coatings Prepared by a Galvanic Replacement Process
journal, March 2010

  • Papadimitriou, Sofia; Armyanov, Stephan; Valova, Eugenia
  • The Journal of Physical Chemistry C, Vol. 114, Issue 11
  • DOI: 10.1021/jp911568g

High catalytic activity of chemically activated gold electrodes towards electro-oxidation of methanol
journal, July 2004


Formation of carbon-supported PtM alloys for low temperature fuel cells: a review
journal, February 2003


Magnetic metal phosphide nanorods as effective hydrogen-evolution electrocatalysts
journal, November 2014


Stabilization of Platinum Oxygen-Reduction Electrocatalysts Using Gold Clusters
journal, January 2007


Oxygen Electroreduction by Single PtPd Nanocubes Encaged in Hollow Carbon Nanospheres: Improved Durability and Strong Effect of Carbon-Shell Thickness
journal, March 2017

  • Zhang, Chunmei; Zhang, Ruizhong; Li, Lei
  • Particle & Particle Systems Characterization, Vol. 34, Issue 5
  • DOI: 10.1002/ppsc.201700034

Methanol electrooxidation at Pt–Ru–W sputter deposited on Au substrate
journal, September 2004


Surface chemistry of catalysis by gold
journal, March 2004

  • Meyer, R.; Lemire, C.; Shaikhutdinov, Sh. K.
  • Gold Bulletin, Vol. 37, Issue 1-2
  • DOI: 10.1007/BF03215519

Core–Shell Nanostructured Au@Ni m Pt 2 Electrocatalysts with Enhanced Activity and Durability for Oxygen Reduction Reaction
journal, February 2016


Multimetallic Au/FePt 3 Nanoparticles as Highly Durable Electrocatalyst
journal, March 2011

  • Wang, Chao; van der Vliet, Dennis; More, Karren L.
  • Nano Letters, Vol. 11, Issue 3
  • DOI: 10.1021/nl102369k

Recent advances in direct methanol fuel cells at Los Alamos National Laboratory
journal, March 2000


The 3D Nanoscale Evolution of Platinum-Niobium Oxide Fuel Cell Catalysts via Identical Location Electron Tomography
journal, June 2017

  • Rossouw, David; Chinchilla, Lidia; Kremliakova, Natalia
  • Particle & Particle Systems Characterization, Vol. 34, Issue 7
  • DOI: 10.1002/ppsc.201700051

One-Step Seeding Growth of Magnetically Recyclable Au@Co Core−Shell Nanoparticles: Highly Efficient Catalyst for Hydrolytic Dehydrogenation of Ammonia Borane
journal, April 2010

  • Yan, Jun-Min; Zhang, Xin-Bo; Akita, Tomoki
  • Journal of the American Chemical Society, Vol. 132, Issue 15
  • DOI: 10.1021/ja910513h

Chemical and Electronic Effects of Ni in Pt/Ni and Pt/Ru/Ni Alloy Nanoparticles in Methanol Electrooxidation
journal, February 2002

  • Park, Kyung-Won; Choi, Jong-Ho; Kwon, Boo-Kil
  • The Journal of Physical Chemistry B, Vol. 106, Issue 8
  • DOI: 10.1021/jp013168v

Superior anti-CO poisoning capability: Au-decorated PtFe nanocatalysts for high-performance methanol oxidation
journal, January 2016

  • Cai, Zhao; Lu, Zhiyi; Bi, Yongmin
  • Chemical Communications, Vol. 52, Issue 20
  • DOI: 10.1039/C5CC10513G

Modification of the surface electronic and chemical properties of Pt(111) by subsurface 3d transition metals
journal, June 2004

  • Kitchin, J. R.; Nørskov, J. K.; Barteau, M. A.
  • The Journal of Chemical Physics, Vol. 120, Issue 21
  • DOI: 10.1063/1.1737365

Noble-transition metal nanoparticle breathing in a reactive gas atmosphere
journal, January 2013

  • Petkov, Valeri; Shan, Shiyao; Chupas, Peter
  • Nanoscale, Vol. 5, Issue 16
  • DOI: 10.1039/c3nr02582a

Nanostructured PtVFe catalysts: Electrocatalytic performance in proton exchange membrane fuel cells
journal, June 2009


Surface Composition Tuning of Au–Pt Bimetallic Nanoparticles for Enhanced Carbon Monoxide and Methanol Electro-oxidation
journal, May 2013

  • Suntivich, Jin; Xu, Zhichuan; Carlton, Christopher E.
  • Journal of the American Chemical Society, Vol. 135, Issue 21
  • DOI: 10.1021/ja402072r

Pt–Au–Co Alloy Electrocatalysts Demonstrating Enhanced Activity and Durability toward the Oxygen Reduction Reaction
journal, February 2015

  • Tan, XueHai; Prabhudev, Sagar; Kohandehghan, Alireza
  • ACS Catalysis, Vol. 5, Issue 3
  • DOI: 10.1021/cs501710b

Nitrogen and Fluorine‐Codoped Carbon Nanowire Aerogels as Metal‐Free Electrocatalysts for Oxygen Reduction Reaction
journal, July 2017

  • Fu, Shaofang; Zhu, Chengzhou; Song, Junhua
  • Chemistry – A European Journal, Vol. 23, Issue 43
  • DOI: 10.1002/chem.201701969

Core−Shell Gold Nanoparticle Assembly as Novel Electrocatalyst of CO Oxidation
journal, September 2000

  • Maye, Mathew M.; Lou, Yongbing; Zhong, Chuan-Jian
  • Langmuir, Vol. 16, Issue 19
  • DOI: 10.1021/la000503i

Nanoscale Alloying, Phase-Segregation, and Core−Shell Evolution of Gold−Platinum Nanoparticles and Their Electrocatalytic Effect on Oxygen Reduction Reaction
journal, July 2010

  • Wanjala, Bridgid N.; Luo, Jin; Loukrakpam, Rameshwori
  • Chemistry of Materials, Vol. 22, Issue 14
  • DOI: 10.1021/cm101109e

Early Stages of NiO Growth on Ag(001):  A Study by LEIS, XPS, and LEED
journal, July 2004

  • Caffio, M.; Cortigiani, B.; Rovida, G.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 28
  • DOI: 10.1021/jp037805o