skip to main content

DOE PAGESDOE PAGES

This content will become publicly available on April 10, 2019

Title: A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water

An artificial metalloenzyme reduces CO 2 to CO using light, suggesting intramolecular electron transfer and secondary sphere effects modulate catalytic selectivity.
Authors:
 [1] ;  [1] ;  [2] ; ORCiD logo [3]
  1. Ohio State Biochemistry Program, The Ohio State University, Columbus, USA
  2. Department of Chemistry and Biochemistry, The Ohio State University, Columbus, USA
  3. Ohio State Biochemistry Program, The Ohio State University, Columbus, USA, Department of Chemistry and Biochemistry
Publication Date:
Grant/Contract Number:
SC0018020
Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 54 Journal Issue: 37; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1434123

Schneider, Camille R., Manesis, Anastasia C., Stevenson, Michael J., and Shafaat, Hannah S.. A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water. United Kingdom: N. p., Web. doi:10.1039/C8CC01297K.
Schneider, Camille R., Manesis, Anastasia C., Stevenson, Michael J., & Shafaat, Hannah S.. A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water. United Kingdom. doi:10.1039/C8CC01297K.
Schneider, Camille R., Manesis, Anastasia C., Stevenson, Michael J., and Shafaat, Hannah S.. 2018. "A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water". United Kingdom. doi:10.1039/C8CC01297K.
@article{osti_1434123,
title = {A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO 2 reduction in water},
author = {Schneider, Camille R. and Manesis, Anastasia C. and Stevenson, Michael J. and Shafaat, Hannah S.},
abstractNote = {An artificial metalloenzyme reduces CO 2 to CO using light, suggesting intramolecular electron transfer and secondary sphere effects modulate catalytic selectivity.},
doi = {10.1039/C8CC01297K},
journal = {Chemical Communications},
number = 37,
volume = 54,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Basic Research Needs: Catalysis for Energy
report, March 2008
  • Bell, Alexis T.; Gates, Bruce C.; Ray, Douglas
  • PNNL--17214
  • DOI: 10.2172/927492