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Title: Electrokinetic desalination of brackish water and associated challenges in the water and energy nexus


This article presents the challenges and opportunities of electrokinetic desalination for brackish water and its recent development and prospective.

ORCiD logo [1];  [2];  [3]; ORCiD logo [4]
  1. Energy Systems Division, Argonne National Laboratory, Argonne, USA, Carbon Cycle Research Center
  2. Clean Energy and Transportation, Idaho National Laboratory, Idaho Falls, USA
  3. Energy Systems Division, Argonne National Laboratory, Argonne, USA
  4. Carbon Cycle Research Center, National Taiwan University, Taipei City, Republic of China, Graduate Institute of Environmental Engineering
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Grant/Contract Number:  
AC07-05ID14517; AC02-06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Environmental Science: Water Research & Technology
Additional Journal Information:
Journal Name: Environmental Science: Water Research & Technology Journal Volume: 4 Journal Issue: 5; Journal ID: ISSN 2053-1400
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom

Citation Formats

Pan, Shu-Yuan, Snyder, Seth W., Lin, Yupo J., and Chiang, Pen-Chi. Electrokinetic desalination of brackish water and associated challenges in the water and energy nexus. United Kingdom: N. p., 2018. Web. doi:10.1039/C7EW00550D.
Pan, Shu-Yuan, Snyder, Seth W., Lin, Yupo J., & Chiang, Pen-Chi. Electrokinetic desalination of brackish water and associated challenges in the water and energy nexus. United Kingdom. doi:10.1039/C7EW00550D.
Pan, Shu-Yuan, Snyder, Seth W., Lin, Yupo J., and Chiang, Pen-Chi. Mon . "Electrokinetic desalination of brackish water and associated challenges in the water and energy nexus". United Kingdom. doi:10.1039/C7EW00550D.
title = {Electrokinetic desalination of brackish water and associated challenges in the water and energy nexus},
author = {Pan, Shu-Yuan and Snyder, Seth W. and Lin, Yupo J. and Chiang, Pen-Chi},
abstractNote = {This article presents the challenges and opportunities of electrokinetic desalination for brackish water and its recent development and prospective.},
doi = {10.1039/C7EW00550D},
journal = {Environmental Science: Water Research & Technology},
number = 5,
volume = 4,
place = {United Kingdom},
year = {2018},
month = {1}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C7EW00550D

Citation Metrics:
Cited by: 6 works
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Works referenced in this record:

Selective lithium recovery from aqueous solution using a modified membrane capacitive deionization system
journal, November 2017

Capacitive Deionization Technology™: An alternative desalination solution
journal, November 2005

Use of bipolar membranes for generation of acid and base — an engineering and economic analysis
journal, January 1977

Influence of different resins on the amino acid recovery by resin-filling electrodialysis
journal, October 2015

Water osmosis in separating acidic HCl/glyphosate liquor by continuous diffusion dialysis
journal, May 2017

Limitation of Charge Efficiency in Capacitive Deionization
journal, January 2009

  • Avraham, Eran; Bouhadana, Yaniv; Soffer, Abraham
  • Journal of The Electrochemical Society, Vol. 156, Issue 6
  • DOI: 10.1149/1.3115463

Electrodeionization: Principles, Strategies and Applications
journal, June 2014

Advanced carbon aerogels for energy applications
journal, January 2011

  • Biener, Juergen; Stadermann, Michael; Suss, Matthew
  • Energy & Environmental Science, Vol. 4, Issue 3, p. 656-667
  • DOI: 10.1039/c0ee00627k

Accelerating Innovation that Enhances Resource Recovery in the Wastewater Sector: Advancing a National Testbed Network
journal, June 2017

  • Mihelcic, James R.; Ren, Zhiyong Jason; Cornejo, Pablo K.
  • Environmental Science & Technology, Vol. 51, Issue 14
  • DOI: 10.1021/acs.est.6b05917

Electrochemical selective ion separation in capacitive deionization with sodium manganese oxide
journal, November 2017

Development of a selective electrodialysis for nutrient recovery and desalination during secondary effluent treatment
journal, August 2017

Decentralized desalination of brackish water using an electrodialysis system directly powered by wind energy
journal, January 2016

Application of electro-electrodialysis for processing of sodium sulphate waste solutions containing organic compounds: Preliminary study
journal, January 2017

Removal and recovery of Ni2+ from electroplating rinse water using electrodeionization reversal
journal, September 2014

Water desalination via capacitive deionization: what is it and what can we expect from it?
journal, January 2015

  • Suss, M. E.; Porada, S.; Sun, X.
  • Energy & Environmental Science, Vol. 8, Issue 8
  • DOI: 10.1039/C5EE00519A

TiO2 nanorod-intercalated reduced graphene oxide as high performance electrode material for membrane capacitive deionization
journal, April 2015

Electrode configuration optimization of capacitive deionization cells based on zero charge potential of the electrodes
journal, December 2017

Two-Dimensional Porous Electrode Model for Capacitive Deionization
journal, October 2015

  • Hemmatifar, Ali; Stadermann, Michael; Santiago, Juan G.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 44
  • DOI: 10.1021/acs.jpcc.5b05847

Removal of low concentrations of hardness ions from aqueous solutions using electrodeionization process
journal, August 2009

Cocoon derived nitrogen enriched activated carbon fiber networks for capacitive deionization
journal, November 2017

Investigation of Current Routes in Electrodeionization System Resin Beds During Chromium Removal
journal, November 2015

Variable effects on electrodeionization for removal of Cs+ ions from simulated wastewater
journal, July 2014

Emerging desalination technologies for water treatment: A critical review
journal, May 2015

Characterization of Resistances of a Capacitive Deionization System
journal, August 2015

  • Qu, Yatian; Baumann, Theodore F.; Santiago, Juan G.
  • Environmental Science & Technology, Vol. 49, Issue 16
  • DOI: 10.1021/acs.est.5b02542

Ultrahigh Desalinization Performance of Asymmetric Flow-Electrode Capacitive Deionization Device with an Improved Operation Voltage of 1.8 V
journal, December 2016

Direct prediction of the desalination performance of porous carbon electrodes for capacitive deionization
journal, January 2013

  • Porada, S.; Borchardt, L.; Oschatz, M.
  • Energy & Environmental Science, Vol. 6, Issue 12
  • DOI: 10.1039/c3ee42209g

Preparation and desalination performance of multiwall carbon nanotubes
journal, June 2006

Electrodialysis: An application for the environmental protection in shale-gas extraction
journal, March 2016

Single module flow-electrode capacitive deionization for continuous water desalination
journal, November 2015

Effect of electrode thickness variation on operation of capacitive deionization
journal, July 2012

Energy storage materials derived from Prussian blue analogues
journal, March 2017

The effect of restriction membranes on mass transfer in an electrodialysis with filtration membrane process
journal, March 2017

Highly porous activated carbons from resource-recovered Leucaena leucocephala wood as capacitive deionization electrodes
journal, December 2015

Brackish water desalination using electrodeionization reversal
journal, June 2016

  • Sun, Xiaohan; Lu, Huixia; Wang, Jianyou
  • Chemical Engineering and Processing: Process Intensification, Vol. 104
  • DOI: 10.1016/j.cep.2016.03.014

Hydrogen Production from Semiconductor-based Photocatalysis via Water Splitting
journal, October 2012

  • Liao, Chi-Hung; Huang, Chao-Wei; Wu, Jeffrey C. S.
  • Catalysts, Vol. 2, Issue 4
  • DOI: 10.3390/catal2040490

Citric acid production using a biological electrodialysis with bipolar membrane
journal, February 2017

ZIF-8 Derived, Nitrogen-Doped Porous Electrodes of Carbon Polyhedron Particles for High-Performance Electrosorption of Salt Ions
journal, July 2016

  • Liu, Nei-Ling; Dutta, Saikat; Salunkhe, Rahul R.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep28847

On the cost of electrodialysis for the desalination of high salinity feeds
journal, December 2014

Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
journal, September 2006

Potential ion exchange membranes and system performance in reverse electrodialysis for power generation: A review
journal, July 2015

Development of an electrodeionization process for removal of nitrate from drinking water Part 2: Multi-species testing
journal, May 2005

Flexible Nano-felts of Carbide-Derived Carbon with Ultra-high Power Handling Capability
journal, April 2011

  • Presser, Volker; Zhang, Lifeng; Niu, Jun Jie
  • Advanced Energy Materials, Vol. 1, Issue 3
  • DOI: 10.1002/aenm.201100047

A win-win strategy for the reclamation of waste acid and conversion of organic acid by a modified electrodialysis
journal, October 2016

Desalination of an industrial saline water with conventional and bipolar membrane electrodialysis
journal, June 2013

Influence of temperature on the electrosorption of ions from aqueous solutions using mesoporous carbon materials
journal, September 2013

Feasibility study of an electrodialysis system for in-home water desalination in urban India
journal, January 2017

Comparison of electrodialysis reversal (EDR) and electrodeionization reversal (EDIR) for water softening
journal, April 2013

Chemically exfoliated MoS 2 for capacitive deionization of saline water
journal, January 2017

Comparative Efficacy Study of Different Types of Ion Exchange Membranes for Production of Ultrapure Water via Electrodeionization
journal, October 2015

  • Bhadja, Vaibhavee; Makwana, Babubhai S.; Maiti, Subarna
  • Industrial & Engineering Chemistry Research, Vol. 54, Issue 44
  • DOI: 10.1021/acs.iecr.5b03043

Highly selective extraction of metal ions from dilute solutions by hybrid electrodialysis technology
journal, March 2017

Removal of metal ions from electroplating effluent by EDI process and recycle of purified water
journal, October 2007

Resin-enhanced rolling activated carbon electrode for efficient capacitive deionization
journal, October 2017

Influence of voltage and flow rate on electrodeionization (EDI) process efficiency
journal, May 2006

Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques
journal, January 2014

  • Lee, Jaehan; Kim, Seoni; Kim, Choonsoo
  • Energy Environ. Sci., Vol. 7, Issue 11
  • DOI: 10.1039/C4EE02378A

Radioactive iodine waste treatment using electrodialysis with an anion exchange paper membrane
journal, December 2004

Cr(VI) removal by continuous electrodeionization: Study of its basic technologies
journal, November 2009

Energy consumption and water production cost of conventional and renewable-energy-powered desalination processes
journal, August 2013

Carbide-Derived Carbon Monoliths with Hierarchical Pore Architectures
journal, June 2012

  • Oschatz, Martin; Borchardt, Lars; Thommes, Matthias
  • Angewandte Chemie International Edition, Vol. 51, Issue 30
  • DOI: 10.1002/anie.201200024

The production of high purity water by continuous electrodeionization with bipolar membranes: Influence of the anion-exchange membrane permselectivity
journal, September 2006

Membrane-free electrodeionization for high purity water production
journal, November 2013

Performance and energy cost evaluation of an integrated NH 3 -based CO 2 capture-capacitive deionization process
journal, November 2017

  • Ullah, Asad; Saleem, Muhammad Wajid; Kim, Woo-Seung
  • International Journal of Greenhouse Gas Control, Vol. 66
  • DOI: 10.1016/j.ijggc.2017.09.013

Preparation of activated mesoporous carbons for electrosorption of ions from aqueous solutions
journal, January 2010

  • Wang, Xiqing; Lee, Je Seung; Tsouris, Costas
  • Journal of Materials Chemistry, Vol. 20, Issue 22, p. 4602-4608
  • DOI: 10.1039/b925957k

Use of a Liter-Scale Microbial Desalination Cell As a Platform to Study Bioelectrochemical Desalination with Salt Solution or Artificial Seawater
journal, May 2011

  • Jacobson, Kyle S.; Drew, David M.; He, Zhen
  • Environmental Science & Technology, Vol. 45, Issue 10
  • DOI: 10.1021/es200127p

Membrane-free electrodeionization without electrode polarity reversal for high purity water production
journal, July 2014

Electrosorptive desalination by carbon nanotubes and nanofibres electrodes and ion-exchange membranes
journal, December 2008

Electrodialysis of highly concentrated brines: Effects of calcium
journal, March 2017

Nonlinear dynamics of capacitive charging and desalination by porous electrodes
journal, March 2010

Performance evaluation of electrodeionization process based on ionic equilibrium with plate and frame modules
journal, March 2008

Direct seawater desalination by ion concentration polarization
journal, March 2010

  • Kim, Sung Jae; Ko, Sung Hee; Kang, Kwan Hyoung
  • Nature Nanotechnology, Vol. 5, Issue 4, p. 297-301
  • DOI: 10.1038/nnano.2010.34

Enhanced capacitive deionization performance of graphene/carbon nanotube composites
journal, January 2012

  • Zhang, Dengsong; Yan, Tingting; Shi, Liyi
  • Journal of Materials Chemistry, Vol. 22, Issue 29
  • DOI: 10.1039/c2jm31393f

Development of multi-walled carbon nanotube/poly(vinyl alcohol) composite as electrode for capacitive deionization
journal, June 2014

Characterization of electroregeneration and determination of optimal current density in continuous electrodeionization
journal, March 2007

Science and technology for water purification in the coming decades
journal, March 2008

  • Shannon, Mark A.; Bohn, Paul W.; Elimelech, Menachem
  • Nature, Vol. 452, Issue 7185, p. 301-310
  • DOI: 10.1038/nature06599

Desalination by Capacitive Deionization with Carbon-Based Materials as Electrode: a Review
journal, December 2013

Review on the science and technology of water desalination by capacitive deionization
journal, October 2013

Desalination energy minimization using thin film nanocomposite membranes
journal, October 2014

A Desalination Battery
journal, January 2012

  • Pasta, Mauro; Wessells, Colin D.; Cui, Yi
  • Nano Letters, Vol. 12, Issue 2
  • DOI: 10.1021/nl203889e

Optimization of salt adsorption rate in membrane capacitive deionization
journal, April 2013

Application of Capacitive Deionisation in water desalination: A review
journal, June 2014

Optimization of sulfate removal from brackish water by membrane capacitive deionization (MCDI)
journal, September 2017

Production of ultrapure water by continuous electrodeionization
journal, January 2010

The removal of silicon and boron from ultra-pure water by electrodeionization
journal, September 2005

Development of a Resin Wafer Electrodeionization Process for Impaired Water Desalination with High Energy Efficiency and Productivity
journal, March 2017

Limitations of Charge Efficiency in Capacitive Deionization
journal, January 2009

  • Avraham, Eran; Noked, Malachi; Bouhadana, Yaniv
  • Journal of The Electrochemical Society, Vol. 156, Issue 10
  • DOI: 10.1149/1.3193709

Removal of Cu2+ ions by a micro-flow electrodeionization (EDI) system
journal, August 2011

Advances in Membrane Distillation for Water Desalination and Purification Applications
journal, January 2013

  • Camacho, Lucy; Dumée, Ludovic; Zhang, Jianhua
  • Water, Vol. 5, Issue 1
  • DOI: 10.3390/w5010094

Na2FeP2O7 as a Novel Material for Hybrid Capacitive Deionization
journal, June 2016

Exergy and sensitivity analysis of electrodialysis reversal desalination plants
journal, September 2016

Energy consumption analysis of constant voltage and constant current operations in capacitive deionization
journal, December 2016

Electrodeionization: An Efficient Way for Removal of Fluoride from Tap Water Using an Aluminum Form of Phosphomethylated Resin
journal, January 2015

  • Gahlot, Swati; Sharma, Saroj; Kulshrestha, Vaibhav
  • Industrial & Engineering Chemistry Research, Vol. 54, Issue 16
  • DOI: 10.1021/acs.iecr.5b00369

Potential upgrading of bio-refinery streams by electrodialysis
journal, August 2017

Solar Water Splitting Cells
journal, November 2010

  • Walter, Michael G.; Warren, Emily L.; McKone, James R.
  • Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
  • DOI: 10.1021/cr1002326

Capacitive desalination with flow-through electrodes
journal, January 2012

  • Suss, Matthew E.; Baumann, Theodore F.; Bourcier, William L.
  • Energy & Environmental Science, Vol. 5, Issue 11
  • DOI: 10.1039/c2ee21498a

Capacitive neutralization deionization with flow electrodes
journal, October 2016

The Separative Bioreactor: A Continuous Separation Process for the Simultaneous Production and Direct Capture of Organic Acids
journal, July 2007

  • Arora, M. B.; Hestekin, J. A.; Snyder, S. W.
  • Separation Science and Technology, Vol. 42, Issue 11
  • DOI: 10.1080/01496390701477238

Nafion-AC-based asymmetric capacitive deionization
journal, January 2017

Capacitive Deionization Using Alternating Polarization: Effect of Surface Charge on Salt Removal
journal, April 2017

Alternative preparative route for efficient and stable anion-exchange membrane for water desalination by electrodialysis
journal, July 2017

Desalting by Means of Porous Carbon Electrodes
journal, January 1971

  • Johnson, A. M.; Newman, John
  • Journal of The Electrochemical Society, Vol. 118, Issue 3
  • DOI: 10.1149/1.2408094

Enhanced desalination performance of capacitive deionization using zirconium oxide nanoparticles-doped graphene oxide as a novel and effective electrode
journal, October 2016

  • Yasin, Ahmed S.; Mohamed, Hend Omar; Mohamed, Ibrahim M. A.
  • Separation and Purification Technology, Vol. 171
  • DOI: 10.1016/j.seppur.2016.07.014

Enhancement of hardness and chloride removal and reduction of Cl2 release and corrosion in electrodeionization units
journal, April 2015

A comparative study on electrosorptive behavior of carbon nanotubes and graphene for capacitive deionization
journal, April 2011

Surface charge enhanced carbon electrodes for stable and efficient capacitive deionization using inverted adsorption–desorption behavior
journal, January 2015

  • Gao, Xin; Omosebi, Ayokunle; Landon, James
  • Energy & Environmental Science, Vol. 8, Issue 3
  • DOI: 10.1039/C4EE03172E

Studies and characterisations of various activated carbons used for carbon/carbon supercapacitors
journal, October 2001

Energy breakdown in capacitive deionization
journal, November 2016

Na-Ion Desalination (NID) Enabled by Na-Blocking Membranes and Symmetric Na-Intercalation: Porous-Electrode Modeling
journal, January 2016

  • Smith, Kyle C.; Dmello, Rylan
  • Journal of The Electrochemical Society, Vol. 163, Issue 3
  • DOI: 10.1149/2.0761603jes

Mechanistic insights into the use of oxide nanoparticles coated asymmetric electrodes for capacitive deionization
journal, February 2013

Potential of electrodialytic techniques in brackish desalination and recovery of industrial process water for reuse
journal, May 2017

The Future of Seawater Desalination: Energy, Technology, and the Environment
journal, August 2011

Valorization of desalination brines by electrodialysis with bipolar membranes using nanocomposite anion exchange membranes
journal, March 2017

A feasibility study on water softening by electrodeionization with the periodic polarity change
journal, January 2012

Water purification by shock electrodialysis: Deionization, filtration, separation, and disinfection
journal, February 2015

Membrane capacitive deionization
journal, January 2010

Performance of electrodialysis reversal and reverse osmosis for reclaiming wastewater from high-tech industrial parks in Taiwan: A pilot-scale study
journal, February 2017

Electrodialysis, a mature technology with a multitude of new applications
journal, December 2010

Sustainable desalination using a microbial capacitive desalination cell
journal, January 2012

  • Forrestal, Casey; Xu, Pei; Ren, Zhiyong
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21121a

Life cycle assessment of environmental impacts and energy demand for capacitive deionization technology
journal, December 2016

Investigation of the performance determinants in the treatment of arsenic-contaminated water by continuous electrodeionization
journal, May 2017

Study of fouling and scaling in capacitive deionisation by using dissolved organic and inorganic salts
journal, January 2013

Membrane-based seawater desalination: Present and future prospects
journal, January 2017

Desalination techniques — A review of the opportunities for desalination in agriculture
journal, May 2015

Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology
journal, May 2008

Carbon electrodes for capacitive deionization
journal, January 2017

  • Huang, Zheng-Hong; Yang, Zhiyu; Kang, Feiyu
  • Journal of Materials Chemistry A, Vol. 5, Issue 2
  • DOI: 10.1039/C6TA06733F

Energy Recovery in Membrane Capacitive Deionization
journal, April 2013

  • Długołęcki, Piotr; van der Wal, Albert
  • Environmental Science & Technology, Vol. 47, Issue 9
  • DOI: 10.1021/es3053202

Fluorination effect of activated carbons on performance of asymmetric capacitive deionization
journal, July 2017

Au nanoparticles@MoS 2 core-shell structures with moderate MoS 2 coverage for efficient photocatalytic water splitting
journal, June 2017

Indirect desalination of Red Sea water with forward osmosis and low pressure reverse osmosis for water reuse
journal, October 2011

The potential versus current state of water splitting with hematite
journal, January 2015

  • Zandi, Omid; Hamann, Thomas W.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 35
  • DOI: 10.1039/C5CP04267D

The near-future integration of microbial desalination cells with reverse osmosis technology
journal, January 2014

  • ElMekawy, Ahmed; Hegab, Hanaa M.; Pant, Deepak
  • Energy Environ. Sci., Vol. 7, Issue 12
  • DOI: 10.1039/C4EE02208D

Removal of nitrate by asymmetric capacitive deionization
journal, August 2017

  • Lado, Julio J.; Pérez-Roa, Rodolfo E.; Wouters, Jesse J.
  • Separation and Purification Technology, Vol. 183
  • DOI: 10.1016/j.seppur.2017.03.071

Hybrid capacitive deionization with Ag coated carbon composite electrode
journal, November 2017

A study of the electrodeionization process — high-purity water production with a RO/EDI system
journal, December 2000

Concentration of Radioactive Aqueous Wastes. Electromigration Through Ion-Exchange Membranes
journal, January 1955

  • Walters, W. R.; Weiser, D. W.; Marek, L. J.
  • Industrial & Engineering Chemistry, Vol. 47, Issue 1
  • DOI: 10.1021/ie50541a027

Bench scale electrodeionization for high pressure boiler feed water
journal, April 2013

Charge Efficiency: A Functional Tool to Probe the Double-Layer Structure Inside of Porous Electrodes and Application in the Modeling of Capacitive Deionization
journal, November 2009

  • Zhao, R.; Biesheuvel, P. M.; Miedema, H.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 1
  • DOI: 10.1021/jz900154h