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Title: A combined crossed molecular beams and computational study on the formation of distinct resonantly stabilized C 5 H 3 radicals via chemically activated C 5 H 4 and C 6 H 6 intermediates

In a single-collision environment dicarbon reacts with 1-butyne to form resonantly stabilized C 5 H 3 radical products.
Authors:
ORCiD logo [1] ;  [1] ;  [1] ;  [1] ; ORCiD logo [1] ; ORCiD logo [2]
  1. Department of Chemistry, University of Hawai'i at Mānoa, Honolulu, USA
  2. Department of Chemistry and Biochemistry, Florida International University, Miami, USA
Publication Date:
Grant/Contract Number:
FG02-03ER15411; FG02-04ER15570
Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics Journal Volume: 20 Journal Issue: 16; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1434083

Thomas, Aaron M., Lucas, Michael, Zhao, Long, Liddiard, Jerid, Kaiser, Ralf I., and Mebel, Alexander M.. A combined crossed molecular beams and computational study on the formation of distinct resonantly stabilized C 5 H 3 radicals via chemically activated C 5 H 4 and C 6 H 6 intermediates. United Kingdom: N. p., Web. doi:10.1039/C8CP00357B.
Thomas, Aaron M., Lucas, Michael, Zhao, Long, Liddiard, Jerid, Kaiser, Ralf I., & Mebel, Alexander M.. A combined crossed molecular beams and computational study on the formation of distinct resonantly stabilized C 5 H 3 radicals via chemically activated C 5 H 4 and C 6 H 6 intermediates. United Kingdom. doi:10.1039/C8CP00357B.
Thomas, Aaron M., Lucas, Michael, Zhao, Long, Liddiard, Jerid, Kaiser, Ralf I., and Mebel, Alexander M.. 2018. "A combined crossed molecular beams and computational study on the formation of distinct resonantly stabilized C 5 H 3 radicals via chemically activated C 5 H 4 and C 6 H 6 intermediates". United Kingdom. doi:10.1039/C8CP00357B.
@article{osti_1434083,
title = {A combined crossed molecular beams and computational study on the formation of distinct resonantly stabilized C 5 H 3 radicals via chemically activated C 5 H 4 and C 6 H 6 intermediates},
author = {Thomas, Aaron M. and Lucas, Michael and Zhao, Long and Liddiard, Jerid and Kaiser, Ralf I. and Mebel, Alexander M.},
abstractNote = {In a single-collision environment dicarbon reacts with 1-butyne to form resonantly stabilized C 5 H 3 radical products.},
doi = {10.1039/C8CP00357B},
journal = {Physical Chemistry Chemical Physics},
number = 16,
volume = 20,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993
  • Becke, Axel D.
  • The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652
  • DOI: 10.1063/1.464913