Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X‐ray Scintillators

Wang, Yaxing; Yin, Xuemiao; Liu, Wei; Xie, Jian; Chen, Junfeng; Silver, Mark A.; Sheng, Daopeng; Chen, Lanhua; Diwu, Juan; Liu, Ning; Chai, Zhifang; Albrecht‐Schmitt, Thomas E.; Wang, Shuao

doi:10.1002/anie.201802865

Title: Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X‐ray Scintillators

Abstract

Abstract The combination of high atomic number and high oxidation state in U ^VI materials gives rise to both high X‐ray attenuation efficiency and intense green luminescence originating from ligand‐to‐metal charge transfer. These two features suggest that U ^VI materials might act as superior X‐ray scintillators, but this postulate has remained substantially untested. Now the first observation of intense X‐ray scintillation in a uranyl–organic framework ( SCU‐9 ) that is observable by the naked eye is reported. Combining the advantage in minimizing the non‐radiative relaxation during the X‐ray excitation process over those of inorganic salts of uranium, SCU‐9 exhibits a very efficient X‐ray to green light luminescence conversion. The luminescence intensity shows an essentially linear correlation with the received X‐ray intensity, and is comparable with that of commercially available CsI:Tl. SCU‐9 possesses an improved X‐ray attenuation efficiency ( E >20 keV) as well as enhanced radiation resistance and decreased hygroscopy compared to CsI:Tl.

Authors:

^[1]; Yin, Xuemiao ^[2]; Liu, Wei ^[2]; Xie, Jian ^[2]; Chen, Junfeng ^[3]; Silver, Mark A. ^[2]; Sheng, Daopeng ^[2]; Chen, Lanhua ^[2]; Diwu, Juan ^[2]; Liu, Ning ^[4]; Chai, Zhifang ^[2]; Albrecht‐Schmitt, Thomas E. ^[5];

^[2]

State Key Laboratory of Radiation Medicine and Protection School for Radiological and interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions Soochow University Suzhou 215123 China, Key Laboratory of Radiation Physics and Technology Ministry of Education Institute of Nuclear Science and Technology Sichuan University Chengdu 610064 China
State Key Laboratory of Radiation Medicine and Protection School for Radiological and interdisciplinary Sciences (RAD-X) Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions Soochow University Suzhou 215123 China
Key Laboratory of Transparent Opto-functional Inorganic Materials Chinese Academy of Sciences Shanghai Institute of Ceramics Chinese Academy of Sciences Shanghai 201899 China
Key Laboratory of Radiation Physics and Technology Ministry of Education Institute of Nuclear Science and Technology Sichuan University Chengdu 610064 China
Department of Chemistry and Biochemistry Florida State University 95 Chieftain Way Tallahassee FL 32306 USA

Publication Date:: Fri Apr 20 00:00:00 EDT 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1434070

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: Journal Name: Angewandte Chemie (International Edition) Journal Volume: 57 Journal Issue: 26; Journal ID: ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Wang, Yaxing, Yin, Xuemiao, Liu, Wei, Xie, Jian, Chen, Junfeng, Silver, Mark A., Sheng, Daopeng, Chen, Lanhua, Diwu, Juan, Liu, Ning, Chai, Zhifang, Albrecht‐Schmitt, Thomas E., and Wang, Shuao. Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X‐ray Scintillators.  Germany: N. p., 2018. 
Web.  doi:10.1002/anie.201802865.

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                    Wang, Yaxing, Yin, Xuemiao, Liu, Wei, Xie, Jian, Chen, Junfeng, Silver, Mark A., Sheng, Daopeng, Chen, Lanhua, Diwu, Juan, Liu, Ning, Chai, Zhifang, Albrecht‐Schmitt, Thomas E., & Wang, Shuao. Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X‐ray Scintillators.  Germany.  https://doi.org/10.1002/anie.201802865

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                    Wang, Yaxing, Yin, Xuemiao, Liu, Wei, Xie, Jian, Chen, Junfeng, Silver, Mark A., Sheng, Daopeng, Chen, Lanhua, Diwu, Juan, Liu, Ning, Chai, Zhifang, Albrecht‐Schmitt, Thomas E., and Wang, Shuao. Fri .  
"Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X‐ray Scintillators".  Germany.  https://doi.org/10.1002/anie.201802865.

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@article{osti_1434070,

  title        = {Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X‐ray Scintillators},

  author       = {Wang, Yaxing and Yin, Xuemiao and Liu, Wei and Xie, Jian and Chen, Junfeng and Silver, Mark A. and Sheng, Daopeng and Chen, Lanhua and Diwu, Juan and Liu, Ning and Chai, Zhifang and Albrecht‐Schmitt, Thomas E. and Wang, Shuao},

  abstractNote = {Abstract The combination of high atomic number and high oxidation state in U VI materials gives rise to both high X‐ray attenuation efficiency and intense green luminescence originating from ligand‐to‐metal charge transfer. These two features suggest that U VI materials might act as superior X‐ray scintillators, but this postulate has remained substantially untested. Now the first observation of intense X‐ray scintillation in a uranyl–organic framework ( SCU‐9 ) that is observable by the naked eye is reported. Combining the advantage in minimizing the non‐radiative relaxation during the X‐ray excitation process over those of inorganic salts of uranium, SCU‐9 exhibits a very efficient X‐ray to green light luminescence conversion. The luminescence intensity shows an essentially linear correlation with the received X‐ray intensity, and is comparable with that of commercially available CsI:Tl. SCU‐9 possesses an improved X‐ray attenuation efficiency ( E >20 keV) as well as enhanced radiation resistance and decreased hygroscopy compared to CsI:Tl.},

  doi          = {10.1002/anie.201802865},

  journal      = {Angewandte Chemie (International Edition)},

  number       = 26,

  volume       = 57,

  place        = {Germany},

  year         = {Fri Apr 20 00:00:00 EDT 2018},

  month        = {Fri Apr 20 00:00:00 EDT 2018}

}

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Title: Emergence of Uranium as a Distinct Metal Center for Building Intrinsic X‐ray Scintillators

Abstract

Citation Formats

Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with U VI ═O–Ln III Bonding (Ln = Ce, Nd) journal, December 2011

Scintillator materials for x-ray detectors and beam monitors journal, June 2017

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Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework journal, May 2017

Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds journal, July 2011

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Scintillation detectors for x-rays journal, February 2006

Detection of X-ray photons by solution-processed lead halide perovskites journal, May 2015

Bottom-up construction of a superstructure in a porous uranium-organic crystal journal, April 2017

Uranium and manganese assembled in a wheel-shaped nanoscale single-molecule magnet with high spin-reversal barrier journal, November 2012

Single-Molecule Magnetism in a Single-Ion Triamidoamine Uranium(V) Terminal Mono-Oxo Complex journal, April 2013

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A Flexible Microporous Hydrogen-Bonded Organic Framework for Gas Sorption and Separation journal, July 2015

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The Chemistry of the Actinide and Transactinide Elements book, January 2006

Strong coupling between local moments and superconducting ‘heavy’ electrons in UPd2Al3 journal, March 2001

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Recent Developments in the Field of Inorganic Phosphors
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Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework
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Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds
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Bottom-up construction of a superstructure in a porous uranium-organic crystal
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