skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A Hexahomotrioxacalix[3]arene-Based Ditopic Receptor for Alkylammonium Ions Controlled by Ag + Ions

Abstract

A receptor cone-1 based on a hexahomotrioxacalix[3]arene bearing three pyridyl groups was successfully synthesized, which has a C 3-symmetric conformation and is capable of binding alkylammonium and metal ions simultaneously in a cooperative fashion. It can bind alkylammonium ions through the π-cavity formed by three aryl rings. This behaviour is consistent with the cone-in/cone-out conformational rearrangement needed to reorganize the cavity for endo-complexation. As a C 3-symmetrical pyridyl-substituted calixarene, receptor cone-1 can also bind an Ag + ion, and the nitrogen atoms are turned towards the inside of the cavity and interact with Ag +. After complexation of tris(2-pyridylamide) derivative receptor cone-1 with Ag +, the original C 3-symmetry was retained and higher complexation selectivity for n-BuNH 3 + versus t-BuNH 3 + was observed. Thus, it is believed that this receptor will have a role to play in the sensing, detection, and recognition of Ag + and n-BuNH 3 + ions.

Authors:
 [1];  [1];  [1];  [2];  [2];  [3];  [4];  [5];  [6];  [1]
  1. Saga Univ., Saga (Japan). Dept. of Applied Chemistry, Faculty of Science and Engineering
  2. Memorial Univ. of Newfoundland, St. John’s, NL (United States). Dept. of Chemistry
  3. Guizhou Univ., Guiyang (China). Key Lab. of Macrocyclic and Supramolecular Chemistry of Guizhou Province
  4. Loughborough Univ., Loughborough (United States). Chemistry Dept.
  5. Univ. of Hull, Hull, Yorkshire (United States). School of Mathematics and Physical Sciences
  6. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1434008
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Molecules
Additional Journal Information:
Journal Volume: 23; Journal Issue: 2; Journal ID: ISSN 1420-3049
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; hexahomotrioxacalix[3]arene; alkylammonium ions; metal ions; ditopic receptor; allosteric effects

Citation Formats

Jiang, Xue-Kai, Ikejiri, Yusuke, Wu, Chong, Rahman, Shofiur, Georghiou, Paris E., Zeng, Xi, Elsegood, Mark, Redshaw, Carl, Teat, Simon, and Yamato, Takehiko. A Hexahomotrioxacalix[3]arene-Based Ditopic Receptor for Alkylammonium Ions Controlled by Ag+ Ions. United States: N. p., 2018. Web. doi:10.3390/molecules23020467.
Jiang, Xue-Kai, Ikejiri, Yusuke, Wu, Chong, Rahman, Shofiur, Georghiou, Paris E., Zeng, Xi, Elsegood, Mark, Redshaw, Carl, Teat, Simon, & Yamato, Takehiko. A Hexahomotrioxacalix[3]arene-Based Ditopic Receptor for Alkylammonium Ions Controlled by Ag+ Ions. United States. doi:10.3390/molecules23020467.
Jiang, Xue-Kai, Ikejiri, Yusuke, Wu, Chong, Rahman, Shofiur, Georghiou, Paris E., Zeng, Xi, Elsegood, Mark, Redshaw, Carl, Teat, Simon, and Yamato, Takehiko. Wed . "A Hexahomotrioxacalix[3]arene-Based Ditopic Receptor for Alkylammonium Ions Controlled by Ag+ Ions". United States. doi:10.3390/molecules23020467. https://www.osti.gov/servlets/purl/1434008.
@article{osti_1434008,
title = {A Hexahomotrioxacalix[3]arene-Based Ditopic Receptor for Alkylammonium Ions Controlled by Ag+ Ions},
author = {Jiang, Xue-Kai and Ikejiri, Yusuke and Wu, Chong and Rahman, Shofiur and Georghiou, Paris E. and Zeng, Xi and Elsegood, Mark and Redshaw, Carl and Teat, Simon and Yamato, Takehiko},
abstractNote = {A receptor cone-1 based on a hexahomotrioxacalix[3]arene bearing three pyridyl groups was successfully synthesized, which has a C3-symmetric conformation and is capable of binding alkylammonium and metal ions simultaneously in a cooperative fashion. It can bind alkylammonium ions through the π-cavity formed by three aryl rings. This behaviour is consistent with the cone-in/cone-out conformational rearrangement needed to reorganize the cavity for endo-complexation. As a C3-symmetrical pyridyl-substituted calixarene, receptor cone-1 can also bind an Ag + ion, and the nitrogen atoms are turned towards the inside of the cavity and interact with Ag+. After complexation of tris(2-pyridylamide) derivative receptor cone-1 with Ag+, the original C3-symmetry was retained and higher complexation selectivity for n-BuNH3+ versus t-BuNH3+ was observed. Thus, it is believed that this receptor will have a role to play in the sensing, detection, and recognition of Ag+ and n-BuNH3+ ions.},
doi = {10.3390/molecules23020467},
journal = {Molecules},
number = 2,
volume = 23,
place = {United States},
year = {2018},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Figures / Tables:

Scheme 1 Scheme 1: Synthesis of receptor cone-1.

Save / Share:

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Calixarenes: from biomimetic receptors to multivalent ligands for biomolecular recognition
journal, January 2010

  • Sansone, Francesco; Baldini, Laura; Casnati, Alessandro
  • New Journal of Chemistry, Vol. 34, Issue 12
  • DOI: 10.1039/c0nj00285b

Interlocked Macromolecules
journal, July 1999

  • Raymo, Françisco M.; Stoddart, J. Fraser
  • Chemical Reviews, Vol. 99, Issue 7
  • DOI: 10.1021/cr970081q

Inclusion of [60]Fullerene in a Homooxacalix[3]arene-Based Dimeric Capsule Cross-Linked by a Pd II −Pyridine Interaction
journal, May 1999

  • Ikeda, Atsushi; Yoshimura, Makoto; Udzu, Hiromi
  • Journal of the American Chemical Society, Vol. 121, Issue 17
  • DOI: 10.1021/ja984396e

Synthesis and Inclusion Properties ofC3-Symmetrically Capped Hexahomotrioxacalix[3]arenes with Ester Groups on the Lower Rim
journal, March 2001


A pyrene-functionalized triazole-linked hexahomotrioxacalix[3]arene as a fluorescent chemosensor for Zn2+ ions
journal, June 2016


Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
journal, January 1985

  • Hay, P. Jeffrey; Wadt, Willard R.
  • The Journal of Chemical Physics, Vol. 82, Issue 1, p. 299-310
  • DOI: 10.1063/1.448975

Synthesis, Complexation, and Membrane Transport Studies of 1,3-Alternate Calix[4]arene-crown-6 Conformers: A New Class of Cesium Selective Ionophores
journal, March 1995

  • Casnati, Alessandro; Pochini, Andrea; Ungaro, Rocco
  • Journal of the American Chemical Society, Vol. 117, Issue 10
  • DOI: 10.1021/ja00115a012

Alkyl Ammonium Ion Selectivity of Hexahomotrioxacalix[3]arene Triamide Derivative having the Intramolecular Hydrogen-Bonding Group
journal, November 2005

  • Yamato, Takehiko; Kitajima, Fumika; Gil, Jeong Tae
  • Journal of inclusion phenomena and macrocyclic chemistry, Vol. 53, Issue 3-4
  • DOI: 10.1007/s10847-005-2632-4

Modification of the Upper Rim of Homooxacalix[3]arenes and Complexation between a Nitrohomooxacalix[3]arene Derivative and n -Hexylamine
journal, November 2002

  • Tsubaki, Kazunori; Otsubo, Tadamune; Morimoto, Tatsuya
  • The Journal of Organic Chemistry, Vol. 67, Issue 23
  • DOI: 10.1021/jo026152p

Optical Chemosensor for Ag + , Fe 3+ , and Cysteine: Information Processing at Molecular Level
journal, February 2011

  • Kumar, Manoj; Kumar, Rajesh; Bhalla, Vandana
  • Organic Letters, Vol. 13, Issue 3
  • DOI: 10.1021/ol102543e

A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes
journal, July 2002


Recognition of 1,2-diazines by a bidentate Lewis acid
journal, January 1998

  • Gabbaï, François P.; Schier, Annette; Riede, Jürgen
  • Chemical Communications, Issue 8
  • DOI: 10.1039/a800413g

Efficient Photocurrent Generation in Novel Self-Assembled Multilayers Comprised of [60]Fullerene−Cationic Homooxacalix[3]arene Inclusion Complex and Anionic Porphyrin Polymer
journal, May 2001

  • Ikeda, Atsushi; Hatano, Tsukasa; Shinkai, Seiji
  • Journal of the American Chemical Society, Vol. 123, Issue 20
  • DOI: 10.1021/ja015596k

Thiacalixarenes
journal, December 2006

  • Morohashi, Naoya; Narumi, Fumitaka; Iki, Nobuhiko
  • Chemical Reviews, Vol. 106, Issue 12, p. 5291-5316
  • DOI: 10.1021/cr050565j

Synthesis and ion selectivity of conformers derived from hexahomotrioxacalix[3]arene
journal, October 1993

  • Araki, Koji; Hashimoto, Norifumi; Otsuka, Hideyuki
  • The Journal of Organic Chemistry, Vol. 58, Issue 22
  • DOI: 10.1021/jo00074a021

BYPASS: an effective method for the refinement of crystal structures containing disordered solvent regions
journal, March 1990

  • van der Sluis, P.; Spek, A. L.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 46, Issue 3
  • DOI: 10.1107/S0108767389011189

Calixarene-Derived Fluorescent Probes
journal, September 2007

  • Kim, Jong Seung; Quang, Duong Tuan
  • Chemical Reviews, Vol. 107, Issue 9
  • DOI: 10.1021/cr068046j

Synthesis of Mono- O -alkylated Homooxacalix[3]arene and a Protection–Deprotection Strategy for Homooxacalix[3]arene
journal, December 2016


Novel Cavity Design Using Calix[ n ]arene Skeletons:  Toward Molecular Recognition and Metal Binding
journal, August 1997

  • Ikeda, Atsushi; Shinkai, Seiji
  • Chemical Reviews, Vol. 97, Issue 5
  • DOI: 10.1021/cr960385x

Pyrene-Linked Triazole-Modified Homooxacalix[3]arene: A Unique C 3 Symmetry Ratiometric Fluorescent Chemosensor for Pb 2+
journal, February 2011

  • Ni, Xin-Long; Wang, Shi; Zeng, Xi
  • Organic Letters, Vol. 13, Issue 4
  • DOI: 10.1021/ol102914t

Novel Fluorometric Sensing of Ammonium Ions by Pyrene Functionalized Homotrioxacalix[3]arenes
journal, January 1994

  • Takeshita, Michinori; Shinkai, Seiji
  • Chemistry Letters, Vol. 23, Issue 1
  • DOI: 10.1246/cl.1994.125

Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)]
journal, February 1997


Synthesis and inclusion properties of O-tris(benzyloxy)hexahomotrioxacalix[3]arenes
journal, August 2006

  • Yamato, Takehiko; Rahman, Shofiur; Kitajima, Fumika
  • Journal of Chemical Research, Vol. 2006, Issue 8
  • DOI: 10.3184/030823406778256351

A Self-Assembled Homooxacalix[3]arene-based Dimeric Capsule Constructed by a Pd II −Pyridine Interaction Which Shows a Novel Chiral Twisting Motion in Response to Guest Inclusion
journal, May 2001

  • Ikeda, Atsushi; Udzu, Hiromi; Zhong, Zhenlin
  • Journal of the American Chemical Society, Vol. 123, Issue 17
  • DOI: 10.1021/ja003269r

Quantum Mechanical Calculations of Conformationally Relevant1H and13C NMR Chemical Shifts of N-, O-, and S-Substituted Calixarene Systems
journal, August 2007

  • Bifulco, Giuseppe; Riccio, Raffaele; Gaeta, Carmine
  • Chemistry - A European Journal, Vol. 13, Issue 25
  • DOI: 10.1002/chem.200700238

Exploitation of Na + -Selective Electrodes for Protein Solutions from Crown-Bridged Calix[4]quinones
journal, January 1996

  • Yamamoto, Hiromasa; Ueda, Keiko; Suenaga, Hikaru
  • Chemistry Letters, Vol. 25, Issue 1
  • DOI: 10.1246/cl.1996.39

Click synthesis of a quinoline-functionalized hexahomotrioxacalix[3]arene: A turn-on fluorescence chemosensor for Fe3+
journal, January 2018


Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg
journal, January 1985

  • Hay, P. Jeffrey; Wadt, Willard R.
  • The Journal of Chemical Physics, Vol. 82, Issue 1
  • DOI: 10.1063/1.448799

Synthesis and evaluation of a novel fluorescent sensor based on hexahomotrioxacalix[3]arene for Zn 2+ and Cd 2+
journal, August 2016


Artificial Organic Host Molecules for Anions
journal, August 1997

  • Schmidtchen, Franz P.; Berger, Michael
  • Chemical Reviews, Vol. 97, Issue 5
  • DOI: 10.1021/cr9603845

Ion and Molecular Recognition by Lower Rim 1,3-Di-conjugates of Calix[4]arene as Receptors
journal, August 2011

  • Joseph, Roymon; Rao, Chebrolu Pulla
  • Chemical Reviews, Vol. 111, Issue 8
  • DOI: 10.1021/cr1004524

Synthesis, structure and inclusion properties of cone-tris{[(5′-methyl-2,2′-bipyridyl)-5-yl]oxycarbonylmethoxy}hexahomotrioxacalix[3]arene
journal, March 2011

  • Ni, Xin-Long; Takimoto, Masashi; Xi, Zeng
  • Journal of Inclusion Phenomena and Macrocyclic Chemistry, Vol. 71, Issue 1-2
  • DOI: 10.1007/s10847-011-9936-3

Fifty years of oxacalix[3]arenes: A review
journal, January 2012

  • Cottet, Kevin; Marcos, Paula M.; Cragg, Peter J.
  • Beilstein Journal of Organic Chemistry, Vol. 8
  • DOI: 10.3762/bjoc.8.22

Complete asymmetric induction of supramolecular chirality in a hydrogen-bonded assembly
journal, April 1999

  • Prins, Leonard J.; Huskens, Jurriaan; de Jong, Feike
  • Nature, Vol. 398, Issue 6727
  • DOI: 10.1038/19053

Heteroditopic receptors tris(2-pyridylamide) derivatives derived from hexahomotrioxacalix[3]arene triacetic acid
journal, September 2010

  • Takimoto, Masashi; Ni, Xin-Long; Rahman, Shofuir
  • Journal of Inclusion Phenomena and Macrocyclic Chemistry, Vol. 70, Issue 1-2
  • DOI: 10.1007/s10847-010-9863-8

Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi
journal, January 1985

  • Wadt, Willard R.; Hay, P. Jeffrey
  • The Journal of Chemical Physics, Vol. 82, Issue 1
  • DOI: 10.1063/1.448800

Coumarin-Derived Cu 2+ -Selective Fluorescence Sensor: Synthesis, Mechanisms, and Applications in Living Cells
journal, February 2009

  • Jung, Hyo Sung; Kwon, Pil Seung; Lee, Jeong Won
  • Journal of the American Chemical Society, Vol. 131, Issue 5
  • DOI: 10.1021/ja808611d

Anion Recognition and Sensing: The State of the Art and Future Perspectives
journal, January 2001


Calixarene-Based Molecules for Cation Recognition
journal, October 2002


Recognition and binding of paraquat dichloride by cyclodextrin/calix[6]pyrrole binary host systems
journal, November 2002


Control of Structural Isomerism in Noncovalent Hydrogen-Bonded Assemblies Using Peripheral Chiral Information
journal, April 2000

  • Prins, Leonard J.; Jolliffe, Katrina A.; Hulst, Ron
  • Journal of the American Chemical Society, Vol. 122, Issue 15
  • DOI: 10.1021/ja9936262

    Works referencing / citing this record:

    Fifty years of oxacalix[3]arenes: A review
    journal, January 2012

    • Cottet, Kevin; Marcos, Paula M.; Cragg, Peter J.
    • Beilstein Journal of Organic Chemistry, Vol. 8
    • DOI: 10.3762/bjoc.8.22

    Click synthesis of a quinoline-functionalized hexahomotrioxacalix[3]arene: A turn-on fluorescence chemosensor for Fe3+
    journal, January 2018


    Alkyl Ammonium Ion Selectivity of Hexahomotrioxacalix[3]arene Triamide Derivative having the Intramolecular Hydrogen-Bonding Group
    journal, November 2005

    • Yamato, Takehiko; Kitajima, Fumika; Gil, Jeong Tae
    • Journal of inclusion phenomena and macrocyclic chemistry, Vol. 53, Issue 3-4
    • DOI: 10.1007/s10847-005-2632-4

    Synthesis, structure and inclusion properties of cone-tris{[(5′-methyl-2,2′-bipyridyl)-5-yl]oxycarbonylmethoxy}hexahomotrioxacalix[3]arene
    journal, March 2011

    • Ni, Xin-Long; Takimoto, Masashi; Xi, Zeng
    • Journal of Inclusion Phenomena and Macrocyclic Chemistry, Vol. 71, Issue 1-2
    • DOI: 10.1007/s10847-011-9936-3

    Synthesis, Complexation, and Membrane Transport Studies of 1,3-Alternate Calix[4]arene-crown-6 Conformers: A New Class of Cesium Selective Ionophores
    journal, March 1995

    • Casnati, Alessandro; Pochini, Andrea; Ungaro, Rocco
    • Journal of the American Chemical Society, Vol. 117, Issue 10
    • DOI: 10.1021/ja00115a012

    Novel Cavity Design Using Calix[ n ]arene Skeletons:  Toward Molecular Recognition and Metal Binding
    journal, August 1997

    • Ikeda, Atsushi; Shinkai, Seiji
    • Chemical Reviews, Vol. 97, Issue 5
    • DOI: 10.1021/cr960385x

    Efficient Photocurrent Generation in Novel Self-Assembled Multilayers Comprised of [60]Fullerene−Cationic Homooxacalix[3]arene Inclusion Complex and Anionic Porphyrin Polymer
    journal, May 2001

    • Ikeda, Atsushi; Hatano, Tsukasa; Shinkai, Seiji
    • Journal of the American Chemical Society, Vol. 123, Issue 20
    • DOI: 10.1021/ja015596k

    Synthesis and ion selectivity of conformers derived from hexahomotrioxacalix[3]arene
    journal, October 1993

    • Araki, Koji; Hashimoto, Norifumi; Otsuka, Hideyuki
    • The Journal of Organic Chemistry, Vol. 58, Issue 22
    • DOI: 10.1021/jo00074a021

    Heteroditopic receptors tris(2-pyridylamide) derivatives derived from hexahomotrioxacalix[3]arene triacetic acid
    journal, September 2010

    • Takimoto, Masashi; Ni, Xin-Long; Rahman, Shofuir
    • Journal of Inclusion Phenomena and Macrocyclic Chemistry, Vol. 70, Issue 1-2
    • DOI: 10.1007/s10847-010-9863-8

    Synthesis and inclusion properties of O-tris(benzyloxy)hexahomotrioxacalix[3]arenes
    journal, August 2006

    • Yamato, Takehiko; Rahman, Shofiur; Kitajima, Fumika
    • Journal of Chemical Research, Vol. 2006, Issue 8
    • DOI: 10.3184/030823406778256351

    Control of Structural Isomerism in Noncovalent Hydrogen-Bonded Assemblies Using Peripheral Chiral Information
    journal, April 2000

    • Prins, Leonard J.; Jolliffe, Katrina A.; Hulst, Ron
    • Journal of the American Chemical Society, Vol. 122, Issue 15
    • DOI: 10.1021/ja9936262

    Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
    journal, January 1985

    • Hay, P. Jeffrey; Wadt, Willard R.
    • The Journal of Chemical Physics, Vol. 82, Issue 1, p. 299-310
    • DOI: 10.1063/1.448975

    Synthesis and evaluation of a novel fluorescent sensor based on hexahomotrioxacalix[3]arene for Zn 2+ and Cd 2+
    journal, August 2016


    Coumarin-Derived Cu 2+ -Selective Fluorescence Sensor: Synthesis, Mechanisms, and Applications in Living Cells
    journal, February 2009

    • Jung, Hyo Sung; Kwon, Pil Seung; Lee, Jeong Won
    • Journal of the American Chemical Society, Vol. 131, Issue 5
    • DOI: 10.1021/ja808611d

    Calixarenes: from biomimetic receptors to multivalent ligands for biomolecular recognition
    journal, January 2010

    • Sansone, Francesco; Baldini, Laura; Casnati, Alessandro
    • New Journal of Chemistry, Vol. 34, Issue 12
    • DOI: 10.1039/c0nj00285b

    Inclusion of [60]Fullerene in a Homooxacalix[3]arene-Based Dimeric Capsule Cross-Linked by a Pd II −Pyridine Interaction
    journal, May 1999

    • Ikeda, Atsushi; Yoshimura, Makoto; Udzu, Hiromi
    • Journal of the American Chemical Society, Vol. 121, Issue 17
    • DOI: 10.1021/ja984396e

    Complete asymmetric induction of supramolecular chirality in a hydrogen-bonded assembly
    journal, April 1999

    • Prins, Leonard J.; Huskens, Jurriaan; de Jong, Feike
    • Nature, Vol. 398, Issue 6727
    • DOI: 10.1038/19053

    Ion and Molecular Recognition by Lower Rim 1,3-Di-conjugates of Calix[4]arene as Receptors
    journal, August 2011

    • Joseph, Roymon; Rao, Chebrolu Pulla
    • Chemical Reviews, Vol. 111, Issue 8
    • DOI: 10.1021/cr1004524

    Calixarene-Based Molecules for Cation Recognition
    journal, October 2002


    Modification of the Upper Rim of Homooxacalix[3]arenes and Complexation between a Nitrohomooxacalix[3]arene Derivative and n -Hexylamine
    journal, November 2002

    • Tsubaki, Kazunori; Otsubo, Tadamune; Morimoto, Tatsuya
    • The Journal of Organic Chemistry, Vol. 67, Issue 23
    • DOI: 10.1021/jo026152p

    Interlocked Macromolecules
    journal, July 1999

    • Raymo, Françisco M.; Stoddart, J. Fraser
    • Chemical Reviews, Vol. 99, Issue 7
    • DOI: 10.1021/cr970081q

    A Self-Assembled Homooxacalix[3]arene-based Dimeric Capsule Constructed by a Pd II −Pyridine Interaction Which Shows a Novel Chiral Twisting Motion in Response to Guest Inclusion
    journal, May 2001

    • Ikeda, Atsushi; Udzu, Hiromi; Zhong, Zhenlin
    • Journal of the American Chemical Society, Vol. 123, Issue 17
    • DOI: 10.1021/ja003269r

    Novel Fluorometric Sensing of Ammonium Ions by Pyrene Functionalized Homotrioxacalix[3]arenes
    journal, January 1994

    • Takeshita, Michinori; Shinkai, Seiji
    • Chemistry Letters, Vol. 23, Issue 1
    • DOI: 10.1246/cl.1994.125

    Thiacalixarenes
    journal, December 2006

    • Morohashi, Naoya; Narumi, Fumitaka; Iki, Nobuhiko
    • Chemical Reviews, Vol. 106, Issue 12, p. 5291-5316
    • DOI: 10.1021/cr050565j

    Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg
    journal, January 1985

    • Hay, P. Jeffrey; Wadt, Willard R.
    • The Journal of Chemical Physics, Vol. 82, Issue 1
    • DOI: 10.1063/1.448799

    Exploitation of Na + -Selective Electrodes for Protein Solutions from Crown-Bridged Calix[4]quinones
    journal, January 1996

    • Yamamoto, Hiromasa; Ueda, Keiko; Suenaga, Hikaru
    • Chemistry Letters, Vol. 25, Issue 1
    • DOI: 10.1246/cl.1996.39

    Calixarene-Derived Fluorescent Probes
    journal, September 2007

    • Kim, Jong Seung; Quang, Duong Tuan
    • Chemical Reviews, Vol. 107, Issue 9
    • DOI: 10.1021/cr068046j

    Pyrene-Linked Triazole-Modified Homooxacalix[3]arene: A Unique C 3 Symmetry Ratiometric Fluorescent Chemosensor for Pb 2+
    journal, February 2011

    • Ni, Xin-Long; Wang, Shi; Zeng, Xi
    • Organic Letters, Vol. 13, Issue 4
    • DOI: 10.1021/ol102914t

    Artificial Organic Host Molecules for Anions
    journal, August 1997

    • Schmidtchen, Franz P.; Berger, Michael
    • Chemical Reviews, Vol. 97, Issue 5
    • DOI: 10.1021/cr9603845

    A pyrene-functionalized triazole-linked hexahomotrioxacalix[3]arene as a fluorescent chemosensor for Zn2+ ions
    journal, June 2016


    Optical Chemosensor for Ag + , Fe 3+ , and Cysteine: Information Processing at Molecular Level
    journal, February 2011

    • Kumar, Manoj; Kumar, Rajesh; Bhalla, Vandana
    • Organic Letters, Vol. 13, Issue 3
    • DOI: 10.1021/ol102543e

    Recognition of 1,2-diazines by a bidentate Lewis acid
    journal, January 1998

    • Gabbaï, François P.; Schier, Annette; Riede, Jürgen
    • Chemical Communications, Issue 8
    • DOI: 10.1039/a800413g

    Quantum Mechanical Calculations of Conformationally Relevant1H and13C NMR Chemical Shifts of N-, O-, and S-Substituted Calixarene Systems
    journal, August 2007

    • Bifulco, Giuseppe; Riccio, Raffaele; Gaeta, Carmine
    • Chemistry - A European Journal, Vol. 13, Issue 25
    • DOI: 10.1002/chem.200700238

      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.