Photocatalytic CO2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO2, CO, or Proton
Abstract
Trigonal-bipyramidal Co(II) complexes are used for photochemical carbon dioxide (CO2) reduction with Ru(bpy)32+ as a photosensitizer, tri-p-tolylamine (TTA) as a reversible quencher, and triethylamine (TEA) as a sacrificial electron donor to produce carbon monoxide and dihydrogen. Here, the CO2 reduction is slow because of the large structural changes, spin flipping in the cobalt catalytic intermediates, and an uphill reaction for reduction to catalytically active Co(0) by the photoproduced [Ru(bpy)3]+.
- Authors:
-
[2];
[3];
[3]
- Brookhaven National Lab. (BNL), Upton, NY (United States); Saitama Univ., Saitama (Japan)
- Saitama Univ., Saitama (Japan)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1433980
- Report Number(s):
- BNL-203518-2018-JAAM
Journal ID: ISSN 0020-1669
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 57; Journal Issue: 9; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Citation Formats
Shimoda, Tomoe, Morishima, Takeshi, Kodama, Koichi, Hirose, Takuji, Polyansky, Dmitry E., Manbeck, Gerald F., Muckerman, James T., and Fujita, Etsuko. Photocatalytic CO2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO2, CO, or Proton. United States: N. p., 2018.
Web. doi:10.1021/acs.inorgchem.8b00433.
Shimoda, Tomoe, Morishima, Takeshi, Kodama, Koichi, Hirose, Takuji, Polyansky, Dmitry E., Manbeck, Gerald F., Muckerman, James T., & Fujita, Etsuko. Photocatalytic CO2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO2, CO, or Proton. United States. https://doi.org/10.1021/acs.inorgchem.8b00433
Shimoda, Tomoe, Morishima, Takeshi, Kodama, Koichi, Hirose, Takuji, Polyansky, Dmitry E., Manbeck, Gerald F., Muckerman, James T., and Fujita, Etsuko. Thu .
"Photocatalytic CO2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO2, CO, or Proton". United States. https://doi.org/10.1021/acs.inorgchem.8b00433. https://www.osti.gov/servlets/purl/1433980.
@article{osti_1433980,
title = {Photocatalytic CO2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO2, CO, or Proton},
author = {Shimoda, Tomoe and Morishima, Takeshi and Kodama, Koichi and Hirose, Takuji and Polyansky, Dmitry E. and Manbeck, Gerald F. and Muckerman, James T. and Fujita, Etsuko},
abstractNote = {Trigonal-bipyramidal Co(II) complexes are used for photochemical carbon dioxide (CO2) reduction with Ru(bpy)32+ as a photosensitizer, tri-p-tolylamine (TTA) as a reversible quencher, and triethylamine (TEA) as a sacrificial electron donor to produce carbon monoxide and dihydrogen. Here, the CO2 reduction is slow because of the large structural changes, spin flipping in the cobalt catalytic intermediates, and an uphill reaction for reduction to catalytically active Co(0) by the photoproduced [Ru(bpy)3]+.},
doi = {10.1021/acs.inorgchem.8b00433},
journal = {Inorganic Chemistry},
number = 9,
volume = 57,
place = {United States},
year = {Thu Apr 26 00:00:00 EDT 2018},
month = {Thu Apr 26 00:00:00 EDT 2018}
}
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