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Title: Hydrogenated TiO 2@reduced graphene oxide sandwich-like nanosheets for high voltage supercapacitor applications

Abstract

Hydrogenated TiO 2 has recently attracted considerable attention as potential electrode materials for supercapacitors due to its abundance, low cost, high conductivity, remarkable rate capability, and outstanding long-term cycling stability. In this paper, we demonstrate the synthesis of hydrogenated TiO 2 nanoparticles anchored on reduced graphene oxide nanosheets (HTG) in the form of sandwich-like nanosheet composites. Further, we explored their implementation as electrode materials for high voltage, symmetric supercapacitors, operating in the voltage window of 0–1.8 V. The HTGs were prepared by a sol-gel method, followed by hydrogenation in the temperature range 300–500 °C. Of the prepared composites, HTG prepared at 400 °C exhibited the largest specific capacitance of 51 F g -1 at the current density of 1.0 A g -1 and excellent rate capability with 82.5% capacitance retention as the current density increased 40-fold, from 0.5 to 20.0 A g -1. HTG's excellent rate capability was attributed to its sandwich-like nanostructure, in which ultrasmall hydrogenated TiO 2 nanoparticles densely anchored onto both surfaces of the two-dimensional reduced graphene oxide sheets. Moreover, HTG-based supercapacitors also exhibited long-term cycling stability with the retention over 80% of its initial capacitance after 10,000 cycles. Finally, these properties suggest that HTG is amore » promising electrode material for the scalable manufacture of high-performance supercapacitors.« less

Authors:
ORCiD logo [1];  [2];  [1];  [3];  [3]; ORCiD logo [1]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
  2. Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry
  3. Univ. of Ulsan (Korea, Republic of). School of Chemical Engineering
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1433973
Alternate Identifier(s):
OSTI ID: 1564389
Report Number(s):
BNL-203508-2018-JAAM
Journal ID: ISSN 0008-6223
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Carbon
Additional Journal Information:
Journal Volume: 126; Journal ID: ISSN 0008-6223
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; graphene; TiO2; supercapacitor; energy storage

Citation Formats

Pham, Viet Hung, Nguyen-Phan, Thuy-Duong, Tong, Xiao, Rajagopalan, Balasubramaniyan, Chung, Jin Suk, and Dickerson, James H. Hydrogenated TiO2@reduced graphene oxide sandwich-like nanosheets for high voltage supercapacitor applications. United States: N. p., 2017. Web. doi:10.1016/j.carbon.2017.10.026.
Pham, Viet Hung, Nguyen-Phan, Thuy-Duong, Tong, Xiao, Rajagopalan, Balasubramaniyan, Chung, Jin Suk, & Dickerson, James H. Hydrogenated TiO2@reduced graphene oxide sandwich-like nanosheets for high voltage supercapacitor applications. United States. doi:10.1016/j.carbon.2017.10.026.
Pham, Viet Hung, Nguyen-Phan, Thuy-Duong, Tong, Xiao, Rajagopalan, Balasubramaniyan, Chung, Jin Suk, and Dickerson, James H. Mon . "Hydrogenated TiO2@reduced graphene oxide sandwich-like nanosheets for high voltage supercapacitor applications". United States. doi:10.1016/j.carbon.2017.10.026. https://www.osti.gov/servlets/purl/1433973.
@article{osti_1433973,
title = {Hydrogenated TiO2@reduced graphene oxide sandwich-like nanosheets for high voltage supercapacitor applications},
author = {Pham, Viet Hung and Nguyen-Phan, Thuy-Duong and Tong, Xiao and Rajagopalan, Balasubramaniyan and Chung, Jin Suk and Dickerson, James H.},
abstractNote = {Hydrogenated TiO2 has recently attracted considerable attention as potential electrode materials for supercapacitors due to its abundance, low cost, high conductivity, remarkable rate capability, and outstanding long-term cycling stability. In this paper, we demonstrate the synthesis of hydrogenated TiO2 nanoparticles anchored on reduced graphene oxide nanosheets (HTG) in the form of sandwich-like nanosheet composites. Further, we explored their implementation as electrode materials for high voltage, symmetric supercapacitors, operating in the voltage window of 0–1.8 V. The HTGs were prepared by a sol-gel method, followed by hydrogenation in the temperature range 300–500 °C. Of the prepared composites, HTG prepared at 400 °C exhibited the largest specific capacitance of 51 F g-1 at the current density of 1.0 A g-1 and excellent rate capability with 82.5% capacitance retention as the current density increased 40-fold, from 0.5 to 20.0 A g-1. HTG's excellent rate capability was attributed to its sandwich-like nanostructure, in which ultrasmall hydrogenated TiO2 nanoparticles densely anchored onto both surfaces of the two-dimensional reduced graphene oxide sheets. Moreover, HTG-based supercapacitors also exhibited long-term cycling stability with the retention over 80% of its initial capacitance after 10,000 cycles. Finally, these properties suggest that HTG is a promising electrode material for the scalable manufacture of high-performance supercapacitors.},
doi = {10.1016/j.carbon.2017.10.026},
journal = {Carbon},
number = ,
volume = 126,
place = {United States},
year = {2017},
month = {10}
}

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