Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers

Ferreira, Timothy; Heald, Steve M.; Smith, Mark. D.; zur Loye, Hans-Conrad

doi:10.1021/acs.inorgchem.8b00249

Title: Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba₄Ni₂Ir₂O₁₂ Containing Ir₂NiO₁₂ Mixed-Metal-Cation Trimers

Abstract

In this paper, the crystal chemistry and magnetic properties of two hexagonal nickel(IV)-containing perovskites, Ba₄Ni_1.94Ir_2.06O₁₂ and BaNiO₃, are reported. The 12R perovskite, Ba₄Ni_1.94Ir_2.06O₁₂, possesses an unexpected coexistence of nickel(II) and nickel(IV). This quadruple perovskite structure contains Ir₂NiO₁₂ mixed-metal-cation units in which direct metal–metal bonding between nickel(IV) and iridium(V) is inferred. Finally, X-ray absorption near-edge spectroscopy and X-ray photoelectron spectroscopy measurements were conducted to confirm the simultaneous presence of nickel(II) and nickel(IV).

Authors:

Ferreira, Timothy ^[1]; Heald, Steve M. ^[2]; Smith, Mark. D. ^[1];

^[1]

Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemistry and Biochemistry
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division, Advanced Photon Source (APS)

Publication Date:: 2018-03-02

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of South Carolina, Columbia, SC (United States)

Sponsoring Org.:: USDOE Office of Science (SC); National Science Foundation (NSF)

OSTI Identifier:: 1433915

Grant/Contract Number:: AC02-06CH11357; DMR-1301757; OIA-1655740

Resource Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Volume: 57; Journal Issue: 6; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Ferreira, Timothy, Heald, Steve M., Smith, Mark. D., and zur Loye, Hans-Conrad. Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers.  United States: N. p., 2018. 
Web.  doi:10.1021/acs.inorgchem.8b00249.

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                    Ferreira, Timothy, Heald, Steve M., Smith, Mark. D., & zur Loye, Hans-Conrad. Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers.  United States.  https://doi.org/10.1021/acs.inorgchem.8b00249

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                    Ferreira, Timothy, Heald, Steve M., Smith, Mark. D., and zur Loye, Hans-Conrad. Fri .  
"Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers".  United States.  https://doi.org/10.1021/acs.inorgchem.8b00249.  https://www.osti.gov/servlets/purl/1433915.

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@article{osti_1433915,

  title        = {Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers},

  author       = {Ferreira, Timothy and Heald, Steve M. and Smith, Mark. D. and zur Loye, Hans-Conrad},

  abstractNote = {In this paper, the crystal chemistry and magnetic properties of two hexagonal nickel(IV)-containing perovskites, Ba4Ni1.94Ir2.06O12 and BaNiO3, are reported. The 12R perovskite, Ba4Ni1.94Ir2.06O12, possesses an unexpected coexistence of nickel(II) and nickel(IV). This quadruple perovskite structure contains Ir2NiO12 mixed-metal-cation units in which direct metal–metal bonding between nickel(IV) and iridium(V) is inferred. Finally, X-ray absorption near-edge spectroscopy and X-ray photoelectron spectroscopy measurements were conducted to confirm the simultaneous presence of nickel(II) and nickel(IV).},

  doi          = {10.1021/acs.inorgchem.8b00249},

  journal      = {Inorganic Chemistry},

  number       = 6,

  volume       = 57,

  place        = {United States},

  year         = {2018},

  month        = {3}

}

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https://doi.org/10.1021/acs.inorgchem.8b00249

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Cited by: 3 works

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Figure 1: (Left) Polyhedral representation of Ba₄Ni_1.94Ir_2.06O₁₂ with Ni(II) shown in light green, Ni(IV) shown in dark green, Ir(V) shown in grey, Ba shown in blue and O shown in red. (Right) Local coordination environment of Ni(IV) octahedra, shown in dark green, face shared to two distorted Ir(V) octahedra, shownmore »

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Works referenced in this record:

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Ferromagnetism Induced by Substitution of the Iron(IV) Ion by an Unusual High-Valence Nickel(IV) Ion in Antiferromagnetic SrFeO ₃
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Title: Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers

Abstract

Citation Formats

Figures / Tables:

Observation of a d-wave gap in electron-doped Sr2IrO4 journal, October 2015

Mott physics and band topology in materials with strong spin–orbit interaction journal, March 2010

Spin-Liquid State in the S = 1 / 2 Hyperkagome Antiferromagnet Na 4 Ir 3 O 8 journal, September 2007

Pressure Tuning of the Spin-Orbit Coupled Ground State in Sr 2 IrO 4 journal, July 2012

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Crystal Structures and Characterizations of Mixed Valence 12 l -Perovskites Ba 4 EuM 3 O 12 (M = Ru and Ir) journal, September 2009

Low temperature structural phase transition of Ba3NaIr2O9 journal, March 2009

The crystal growth and magnetic properties of Ln2LiIrO6 (Ln=La, Pr, Nd, Sm, Eu) journal, January 2005

La2.50K1.50IrO7: An example of an member of the [AnBn−1O3n][] family of perovskite-related oxides journal, October 2005

Prediction of the crystal structures of perovskites using the software program SPuDS journal, November 2001

Ferromagnetism Induced by Substitution of the Iron(IV) Ion by an Unusual High-Valence Nickel(IV) Ion in Antiferromagnetic SrFeO 3 journal, December 2015

Title: Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba₄Ni₂Ir₂O₁₂ Containing Ir₂NiO₁₂ Mixed-Metal-Cation Trimers

Observation of a d-wave gap in electron-doped Sr2IrO4
journal, October 2015

Mott physics and band topology in materials with strong spin–orbit interaction
journal, March 2010

Spin-Liquid State in the $S = 1 / 2$ Hyperkagome Antiferromagnet ${Na}_{4} {Ir}_{3} O_{8}$
journal, September 2007

Pressure Tuning of the Spin-Orbit Coupled Ground State in ${Sr}_{2} {IrO}_{4}$
journal, July 2012

Spin-Orbit Physics Giving Rise to Novel Phases in Correlated Systems: Iridates and Related Materials
journal, March 2016

Crystal Structures and Characterizations of Mixed Valence 12 l -Perovskites Ba ₄ EuM ₃ O ₁₂ (M = Ru and Ir)
journal, September 2009

Low temperature structural phase transition of Ba3NaIr2O9
journal, March 2009

The crystal growth and magnetic properties of Ln2LiIrO6 (Ln=La, Pr, Nd, Sm, Eu)
journal, January 2005

La2.50K1.50IrO7: An example of an member of the [AnBn−1O3n][] family of perovskite-related oxides
journal, October 2005

Prediction of the crystal structures of perovskites using the software program SPuDS
journal, November 2001

Ferromagnetism Induced by Substitution of the Iron(IV) Ion by an Unusual High-Valence Nickel(IV) Ion in Antiferromagnetic SrFeO ₃
journal, December 2015