Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers

Ferreira, Timothy; Heald, Steve M.; Smith, Mark. D.; zur Loye, Hans-Conrad

doi:10.1021/acs.inorgchem.8b00249

Title: Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba₄Ni₂Ir₂O₁₂ Containing Ir₂NiO₁₂ Mixed-Metal-Cation Trimers

Journal Article · 02 March 2018 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.8b00249 · OSTI ID:1433915

Ferreira, Timothy ^[1]; Heald, Steve M. ^[2]; Smith, Mark. D. ^[1];

^[1]

Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemistry and Biochemistry
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division, Advanced Photon Source (APS)

In this paper, the crystal chemistry and magnetic properties of two hexagonal nickel(IV)-containing perovskites, Ba₄Ni_1.94Ir_2.06O₁₂ and BaNiO₃, are reported. The 12R perovskite, Ba₄Ni_1.94Ir_2.06O₁₂, possesses an unexpected coexistence of nickel(II) and nickel(IV). This quadruple perovskite structure contains Ir₂NiO₁₂ mixed-metal-cation units in which direct metal–metal bonding between nickel(IV) and iridium(V) is inferred. Finally, X-ray absorption near-edge spectroscopy and X-ray photoelectron spectroscopy measurements were conducted to confirm the simultaneous presence of nickel(II) and nickel(IV).

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Univ. of South Carolina, Columbia, SC (United States)

Sponsoring Organization:: USDOE Office of Science (SC); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357; DMR-1301757; OIA-1655740

OSTI ID:: 1433915

Journal Information:: Inorganic Chemistry, Vol. 57, Issue 6; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers

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