First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries
Abstract
All-solid-state Li-ion batteries based on ceramic solid electrolyte materials are a promising next-generation energy storage technology with high energy density and enhanced cycle life. The poor interfacial conductance is one of the key limitations in enabling all-solid-state Li-ion batteries. However, the origin of this poor conductance has not been understood, and there is limited knowledge about the solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries. In this paper, we performed first principles calculations to evaluate the thermodynamics of the interfaces between solid electrolyte and electrode materials and to identify the chemical and electrochemical stabilities of these interfaces. Our computation results reveal that many solid electrolyte–electrode interfaces have limited chemical and electrochemical stability, and that the formation of interphase layers is thermodynamically favorable at these interfaces. These formed interphase layers with different properties significantly affect the electrochemical performance of all-solid-state Li-ion batteries. The mechanisms of applying interfacial coating layers to stabilize the interface and to reduce interfacial resistance are illustrated by our computation. This study demonstrates a computational scheme to evaluate the chemical and electrochemical stability of heterogeneous solid interfaces. Finally, the enhanced understanding of the interfacial phenomena provides the strategies of interface engineering to improve performances of all-solid-state Li-ion batteries.
- Authors:
-
- Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering
- Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering. Energy Research Center
- Publication Date:
- Research Org.:
- Univ. of Maryland, College Park, MD (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Science Foundation (NSF)
- OSTI Identifier:
- 1433677
- Grant/Contract Number:
- EE0006860; TG-DMR130142
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 9; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Zhu, Yizhou, He, Xingfeng, and Mo, Yifei. First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries. United States: N. p., 2015.
Web. doi:10.1039/c5ta08574h.
Zhu, Yizhou, He, Xingfeng, & Mo, Yifei. First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries. United States. https://doi.org/10.1039/c5ta08574h
Zhu, Yizhou, He, Xingfeng, and Mo, Yifei. Fri .
"First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries". United States. https://doi.org/10.1039/c5ta08574h. https://www.osti.gov/servlets/purl/1433677.
@article{osti_1433677,
title = {First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries},
author = {Zhu, Yizhou and He, Xingfeng and Mo, Yifei},
abstractNote = {All-solid-state Li-ion batteries based on ceramic solid electrolyte materials are a promising next-generation energy storage technology with high energy density and enhanced cycle life. The poor interfacial conductance is one of the key limitations in enabling all-solid-state Li-ion batteries. However, the origin of this poor conductance has not been understood, and there is limited knowledge about the solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries. In this paper, we performed first principles calculations to evaluate the thermodynamics of the interfaces between solid electrolyte and electrode materials and to identify the chemical and electrochemical stabilities of these interfaces. Our computation results reveal that many solid electrolyte–electrode interfaces have limited chemical and electrochemical stability, and that the formation of interphase layers is thermodynamically favorable at these interfaces. These formed interphase layers with different properties significantly affect the electrochemical performance of all-solid-state Li-ion batteries. The mechanisms of applying interfacial coating layers to stabilize the interface and to reduce interfacial resistance are illustrated by our computation. This study demonstrates a computational scheme to evaluate the chemical and electrochemical stability of heterogeneous solid interfaces. Finally, the enhanced understanding of the interfacial phenomena provides the strategies of interface engineering to improve performances of all-solid-state Li-ion batteries.},
doi = {10.1039/c5ta08574h},
journal = {Journal of Materials Chemistry. A},
number = 9,
volume = 4,
place = {United States},
year = {2015},
month = {12}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 538 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Microstructure of the LiCoO2 (cathode)/La2/3−xLi3xTiO3 (electrolyte) interface and its influences on the electrochemical properties
journal, August 2007
- Kishida, K.; Wada, N.; Adachi, H.
- Acta Materialia, Vol. 55, Issue 14
Nanoscale Interface Modification of LiCoO 2 by Al 2 O 3 Atomic Layer Deposition for Solid-State Li Batteries
journal, January 2012
- Woo, Jae Ha; Trevey, James E.; Cavanagh, Andrew S.
- Journal of The Electrochemical Society, Vol. 159, Issue 7
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
Fast Solid-State Li Ion Conducting Garnet-Type Structure Metal Oxides for Energy Storage
journal, January 2015
- Thangadurai, Venkataraman; Pinzaru, Dana; Narayanan, Sumaletha
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 2
Interphase formation on lithium solid electrolytes—An in situ approach to study interfacial reactions by photoelectron spectroscopy
journal, October 2015
- Wenzel, Sebastian; Leichtweiss, Thomas; Krüger, Dominik
- Solid State Ionics, Vol. 278
Solid Electrolyte: the Key for High-Voltage Lithium Batteries
journal, October 2014
- Li, Juchuan; Ma, Cheng; Chi, Miaofang
- Advanced Energy Materials, Vol. 5, Issue 4
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations
journal, October 2015
- Zhu, Yizhou; He, Xingfeng; Mo, Yifei
- ACS Applied Materials & Interfaces, Vol. 7, Issue 42
Improvement of electrochemical performance of all-solid-state lithium secondary batteries by surface modification of LiMn2O4 positive electrode
journal, June 2011
- Kitaura, Hirokazu; Hayashi, Akitoshi; Tadanaga, Kiyoharu
- Solid State Ionics, Vol. 192, Issue 1
Progress and prospective of solid-state lithium batteries
journal, February 2013
- Takada, Kazunori
- Acta Materialia, Vol. 61, Issue 3, p. 759-770
A lithium superionic conductor
journal, July 2011
- Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
- Nature Materials, Vol. 10, Issue 9, p. 682-686
All-solid-state lithium batteries with Li3PS4 glass as active material
journal, October 2015
- Hakari, Takashi; Nagao, Motohiro; Hayashi, Akitoshi
- Journal of Power Sources, Vol. 293
Structural and Microstructural Studies of the Series La2/3−xLi3x□1/3−2xTiO3
journal, December 1996
- Fourquet, J. L.; Duroy, H.; Crosnier-Lopez, M. P.
- Journal of Solid State Chemistry, Vol. 127, Issue 2
Inorganic solid Li ion conductors: An overview
journal, June 2009
- Knauth, Philippe
- Solid State Ionics, Vol. 180, Issue 14-16, p. 911-916
First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material
journal, December 2011
- Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand
- Chemistry of Materials, Vol. 24, Issue 1, p. 15-17
Neutron Diffraction Analysis of NASICON-type Li 1+ x Al x Ti 2- x P 3 O 12 : Neutron Diffraction Analysis of NASICON-type Li
journal, July 2014
- Dashjav, Enkhtsetseg; Tietz, Frank
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 640, Issue 15
Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification
journal, September 2006
- Ohta, N.; Takada, K.; Zhang, L.
- Advanced Materials, Vol. 18, Issue 17, p. 2226-2229
Preparation, structure and ionic conductivity of lithium phosphide
journal, April 1989
- Nazri, G.
- Solid State Ionics, Vol. 34, Issue 1-2
Depth-resolved X-ray absorption spectroscopic study on nanoscale observation of the electrode–solid electrolyte interface for all solid state lithium ion batteries
journal, January 2011
- Okumura, Toyoki; Nakatsutsumi, Takayuki; Ina, Toshiaki
- Journal of Materials Chemistry, Vol. 21, Issue 27
Electrochemical Characterizations of Commercial LiCoO[sub 2] Powders with Surface Modified by Li[sub 3]PO[sub 4] Nanoparticles
journal, January 2006
- Jin, Y.; Li, N.; Chen, C. H.
- Electrochemical and Solid-State Letters, Vol. 9, Issue 6
A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride
journal, January 1997
- Yu, Xiaohua; Bates, J. B.; Jellison, G. E.
- Journal of The Electrochemical Society, Vol. 144, Issue 2, p. 524-532
First-Principles Studies on Cation Dopants and Electrolyte|Cathode Interphases for Lithium Garnets
journal, May 2015
- Miara, Lincoln J.; Richards, William Davidson; Wang, Yan E.
- Chemistry of Materials, Vol. 27, Issue 11
High voltage stability of LiCoO2 particles with a nano-scale Lipon coating
journal, July 2011
- Kim, Yoongu; Veith, Gabriel M.; Nanda, Jagjit
- Electrochimica Acta, Vol. 56, Issue 19
Interface reactions between LiPON and lithium studied by in-situ X-ray photoemission
journal, May 2015
- Schwöbel, André; Hausbrand, René; Jaegermann, Wolfram
- Solid State Ionics, Vol. 273
High lithium ion conductivity glass-ceramics in Li2O–Al2O3–TiO2–P2O5 from nanoscaled glassy powders by mechanical milling
journal, October 2006
- Xu, X.; Wen, Z.; Yang, X.
- Solid State Ionics, Vol. 177, Issue 26-32
Solid-state thin-film rechargeable batteries
journal, February 2005
- Dudney, N.J.
- Materials Science and Engineering: B, Vol. 116, Issue 3, p. 245-249
Interfacial modification for high-power solid-state lithium batteries
journal, September 2008
- Takada, Kazunori; Ohta, Narumi; Zhang, Lianqi
- Solid State Ionics, Vol. 179, Issue 27-32
Reduction of charge transfer resistance at the lithium phosphorus oxynitride/lithium cobalt oxide interface by thermal treatment
journal, August 2005
- Iriyama, Yasutoshi; Kako, Tomonori; Yada, Chihiro
- Journal of Power Sources, Vol. 146, Issue 1-2
Bendable and Thin Sulfide Solid Electrolyte Film: A New Electrolyte Opportunity for Free-Standing and Stackable High-Energy All-Solid-State Lithium-Ion Batteries
journal, April 2015
- Nam, Young Jin; Cho, Sung-Ju; Oh, Dae Yang
- Nano Letters, Vol. 15, Issue 5
Chemical stability of cubic Li7La3Zr2O12 with molten lithium at elevated temperature
journal, April 2013
- Wolfenstine, J.; Allen, J. L.; Read, J.
- Journal of Materials Science, Vol. 48, Issue 17
Accuracy of density functional theory in predicting formation energies of ternary oxides from binary oxides and its implication on phase stability
journal, April 2012
- Hautier, Geoffroy; Ong, Shyue Ping; Jain, Anubhav
- Physical Review B, Vol. 85, Issue 15
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12
journal, October 2007
- Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
- Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781
Investigation of the local structure of LiPON thin films to better understand the role of nitrogen on their performance
journal, March 2011
- Fleutot, B.; Pecquenard, B.; Martinez, H.
- Solid State Ionics, Vol. 186, Issue 1
Sol–gel synthesis and lithium ion conductivity of Li7La3Zr2O12 with garnet-related type structure
journal, March 2011
- Kokal, I.; Somer, M.; Notten, P. H. L.
- Solid State Ionics, Vol. 185, Issue 1
Ionic conductivity in Li 3 N single crystals
journal, June 1977
- Alpen, U. v.; Rabenau, A.; Talat, G. H.
- Applied Physics Letters, Vol. 30, Issue 12
A new crystalline LiPON electrolyte: Synthesis, properties, and electronic structure
journal, February 2013
- Senevirathne, Keerthi; Day, Cynthia S.; Gross, Michael D.
- Solid State Ionics, Vol. 233
Crystal structure and phase transitions of the lithium ionic conductor Li3PS4
journal, February 2011
- Homma, Kenji; Yonemura, Masao; Kobayashi, Takeshi
- Solid State Ionics, Vol. 182, Issue 1
On the La2/3−xLi3xTiO3/Al2O3 composite solid-electrolyte for Li-ion conduction
journal, November 2013
- Zhang, Hui; Liu, Xingbo; Qi, Yue
- Journal of Alloys and Compounds, Vol. 577
Interfacial Observation between LiCoO 2 Electrode and Li 2 S−P 2 S 5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy †
journal, February 2010
- Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Chemistry of Materials, Vol. 22, Issue 3
First-Order Localized-Electron Collective-Electron Transition in LaCo
journal, March 1967
- Raccah, P. M.; Goodenough, J. B.
- Physical Review, Vol. 155, Issue 3
In-situ Li7La3Zr2O12/LiCoO2 interface modification for advanced all-solid-state battery
journal, August 2014
- Kato, Takehisa; Hamanaka, Tadashi; Yamamoto, Kazuo
- Journal of Power Sources, Vol. 260
Crystal Structure of Fast Lithium-ion-conducting Cubic Li 7 La 3 Zr 2 O 12
journal, January 2011
- Awaka, Junji; Takashima, Akira; Kataoka, Kunimitsu
- Chemistry Letters, Vol. 40, Issue 1
A Battery Made from a Single Material
journal, April 2015
- Han, Fudong; Gao, Tao; Zhu, Yujie
- Advanced Materials, Vol. 27, Issue 23
Compatibility of Li[sub 7]La[sub 3]Zr[sub 2]O[sub 12] Solid Electrolyte to All-Solid-State Battery Using Li Metal Anode
journal, January 2010
- Kotobuki, Masashi; Munakata, Hirokazu; Kanamura, Kiyoshi
- Journal of The Electrochemical Society, Vol. 157, Issue 10
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013
- Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
- APL Materials, Vol. 1, Issue 1
Co 9 S 8 nanoflakes on graphene (Co 9 S 8 /G) nanocomposites for high performance supercapacitors
journal, January 2014
- Ramachandran, Rajendran; Saranya, Murugan; Santhosh, Chella
- RSC Adv., Vol. 4, Issue 40
Li−Fe−P−O 2 Phase Diagram from First Principles Calculations
journal, February 2008
- Ong, Shyue Ping; Wang, Lei; Kang, Byoungwoo
- Chemistry of Materials, Vol. 20, Issue 5
Formation enthalpies by mixing GGA and GGA calculations
journal, July 2011
- Jain, Anubhav; Hautier, Geoffroy; Ong, Shyue Ping
- Physical Review B, Vol. 84, Issue 4
A high-throughput infrastructure for density functional theory calculations
journal, June 2011
- Jain, Anubhav; Hautier, Geoffroy; Moore, Charles J.
- Computational Materials Science, Vol. 50, Issue 8
An Iodide-Based Li 7 P 2 S 8 I Superionic Conductor
journal, January 2015
- Rangasamy, Ezhiylmurugan; Liu, Zengcai; Gobet, Mallory
- Journal of the American Chemical Society, Vol. 137, Issue 4
5 V Class All-Solid-State Composite Lithium Battery with Li[sub 3]PO[sub 4] Coated LiNi[sub 0.5]Mn[sub 1.5]O[sub 4]
journal, January 2003
- Kobayashi, Yo; Miyashiro, Hajime; Takei, Katsuhito
- Journal of The Electrochemical Society, Vol. 150, Issue 12
LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries
journal, July 2007
- Ohta, Narumi; Takada, Kazunori; Sakaguchi, Isao
- Electrochemistry Communications, Vol. 9, Issue 7
Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes
journal, October 2013
- Hartmann, Pascal; Leichtweiss, Thomas; Busche, Martin R.
- The Journal of Physical Chemistry C, Vol. 117, Issue 41
Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries
journal, December 2011
- Ruzmetov, Dmitry; Oleshko, Vladimir P.; Haney, Paul M.
- Nano Letters, Vol. 12, Issue 1
Enhanced electrochemical properties of nano-Li3PO4 coated on the LiMn2O4 cathode material for lithium ion battery at 55°C
journal, January 2012
- Li, Xiaowei; Yang, Rui; Cheng, Bin
- Materials Letters, Vol. 66, Issue 1
On the Mechanism of Nonaqueous Li–O 2 Electrochemistry on C and Its Kinetic Overpotentials: Some Implications for Li–Air Batteries
journal, November 2012
- McCloskey, Bryan D.; Scheffler, Rouven; Speidel, Angela
- The Journal of Physical Chemistry C, Vol. 116, Issue 45
Electrochemical performance of an all-solid-state lithium ion battery with garnet-type oxide electrolyte
journal, March 2012
- Ohta, Shingo; Kobayashi, Tetsuro; Seki, Juntaro
- Journal of Power Sources, Vol. 202
Ionic conductivity, lithium insertion and extraction of lanthanum lithium titanate
journal, September 2001
- Chen, C.
- Solid State Ionics, Vol. 144, Issue 1-2
Investigation of the solid-state electrolyte/cathode LiPON/LiCoO2 interface by photoelectron spectroscopy
journal, October 2010
- Jacke, Susanne; Song, Jie; Cherkashinin, Gennady
- Ionics, Vol. 16, Issue 9
Oxidation energies of transition metal oxides within the framework
journal, May 2006
- Wang, Lei; Maxisch, Thomas; Ceder, Gerbrand
- Physical Review B, Vol. 73, Issue 19
Characterization of the interface between LiCoO2 and Li7La3Zr2O12 in an all-solid-state rechargeable lithium battery
journal, January 2011
- Kim, Ki Hyun; Iriyama, Yasutoshi; Yamamoto, Kazuo
- Journal of Power Sources, Vol. 196, Issue 2
Lithium conductivity and lithium diffusion in NASICON-type Li1+xTi2–xAlx(PO4)3 (x= 0; 0.3) prepared by mechanical activation
journal, January 2008
- Kosova, N. V.; Devyatkina, E. T.; Stepanov, A. P.
- Ionics, Vol. 14, Issue 4
Enhanced electrochemical properties of Li(Ni0.4Co0.3Mn0.3)O2 cathode by surface modification using Li3PO4-based materials
journal, August 2011
- Song, Han Gab; Kim, Je Young; Kim, Ki Tae
- Journal of Power Sources, Vol. 196, Issue 16
Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility
journal, January 2008
- Deiseroth, Hans-Jörg; Kong, Shiao-Tong; Eckert, Hellmut
- Angewandte Chemie International Edition, Vol. 47, Issue 4
Lithium Lanthanum Titanates: A Review
journal, October 2003
- Stramare, S.; Thangadurai, V.; Weppner, W.
- Chemistry of Materials, Vol. 15, Issue 21
Improvement of High-Rate Performance of All-Solid-State Lithium Secondary Batteries Using LiCoO[sub 2] Coated with Li[sub 2]O–SiO[sub 2] Glasses
journal, January 2008
- Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi
- Electrochemical and Solid-State Letters, Vol. 11, Issue 1
Anomalous High Ionic Conductivity of Nanoporous β-Li3PS4
journal, January 2013
- Liu, Zengcai; Fu, Wujun; Payzant, E. Andrew
- Journal of the American Chemical Society, Vol. 135, Issue 3, p. 975-978
Preparation and Electrical Properties of Some Thiospinels
journal, May 1965
- Bouchard, R. J.; Russo, P. A.; Wold, A.
- Inorganic Chemistry, Vol. 4, Issue 5
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12.
journal, December 2007
- Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
- ChemInform, Vol. 38, Issue 50
Lithium Lanthanum Titanates: A Review
journal, December 2003
- Stramare, S.; Thangadurai, V.; Weppner, W.
- ChemInform, Vol. 34, Issue 52
Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility
journal, January 2008
- Deiseroth, Hans-Jörg; Kong, Shiao-Tong; Eckert, Hellmut
- Angewandte Chemie, Vol. 120, Issue 4
Works referencing / citing this record:
Borohydride-Scaffolded Li/Na/Mg Fast Ionic Conductors for Promising Solid-State Electrolytes
journal, October 2018
- Cuan, Jing; Zhou, You; Zhou, Tengfei
- Advanced Materials, Vol. 31, Issue 1
Sulfide‐Based Solid‐State Electrolytes: Synthesis, Stability, and Potential for All‐Solid‐State Batteries
journal, August 2019
- Zhang, Qing; Cao, Daxian; Ma, Yi
- Advanced Materials, Vol. 31, Issue 44
Advances in Interfaces between Li Metal Anode and Electrolyte
journal, December 2017
- Zhang, Xue-Qiang; Cheng, Xin-Bing; Zhang, Qiang
- Advanced Materials Interfaces, Vol. 5, Issue 2
The Ab Initio Calculations on the Areal Specific Resistance of Li‐Metal/Li 7 La 3 Zr 2 O 12 Interphase
journal, April 2019
- Gao, Jian; Guo, Xuyun; Li, Yutao
- Advanced Theory and Simulations
Strategies Based on Nitride Materials Chemistry to Stabilize Li Metal Anode
journal, March 2017
- Zhu, Yizhou; He, Xingfeng; Mo, Yifei
- Advanced Science, Vol. 4, Issue 8
Ni‐Rich Layered Cathode Materials with Electrochemo‐Mechanically Compliant Microstructures for All‐Solid‐State Li Batteries
journal, December 2019
- Jung, Sung Hoo; Kim, Un‐Hyuck; Kim, Jae‐Hyung
- Advanced Energy Materials, Vol. 10, Issue 6
Solid Electrolytes: Extremely Fast Charge Carriers in Garnet-Type Li 6 La 3 ZrTaO 12 Single Crystals : Solid Electrolytes: Extremely Fast Charge Carriers in Garnet-Type Li6La3ZrTaO12 Single Crystals
journal, September 2017
- Stanje, Bernhard; Rettenwander, Daniel; Breuer, Stefan
- Annalen der Physik, Vol. 529, Issue 12
Anisotropically Electrochemical–Mechanical Evolution in Solid‐State Batteries and Interfacial Tailored Strategy
journal, November 2019
- Sun, Nan; Liu, Qingsong; Cao, Yi
- Angewandte Chemie, Vol. 131, Issue 51
Graphitic Carbon Nitride (g‐C 3 N 4 ): An Interface Enabler for Solid‐State Lithium Metal Batteries
journal, January 2020
- Huang, Ying; Chen, Bo; Duan, Jian
- Angewandte Chemie, Vol. 132, Issue 9
Transient Behavior of the Metal Interface in Lithium Metal-Garnet Batteries
journal, October 2017
- Fu, Kun Kelvin; Gong, Yunhui; Fu, Zhezhen
- Angewandte Chemie International Edition, Vol. 56, Issue 47
Anisotropically Electrochemical–Mechanical Evolution in Solid‐State Batteries and Interfacial Tailored Strategy
journal, November 2019
- Sun, Nan; Liu, Qingsong; Cao, Yi
- Angewandte Chemie International Edition, Vol. 58, Issue 51
Graphitic Carbon Nitride (g‐C 3 N 4 ): An Interface Enabler for Solid‐State Lithium Metal Batteries
journal, January 2020
- Huang, Ying; Chen, Bo; Duan, Jian
- Angewandte Chemie International Edition, Vol. 59, Issue 9
A novel organic/inorganic composite solid electrolyte with functionalized layers for improved room‐temperature rate performance of solid‐state lithium battery
journal, July 2019
- Chen, Hao; Jing, Mao‐xiang; Han, Chong
- International Journal of Energy Research, Vol. 43, Issue 11
High Voltage, Flexible and Low Cost All‐Solid‐State Lithium Metal Batteries with a Wide Working Temperature Range
journal, January 2020
- Zhang, Yuchan; Fei, Huifang; An, Yongling
- ChemistrySelect, Vol. 5, Issue 3
Key Aspects of Lithium Metal Anodes for Lithium Metal Batteries
journal, March 2019
- Ghazi, Zahid Ali; Sun, Zhenhua; Sun, Chengguo
- Small, Vol. 15, Issue 32
Strain‐Stabilized Ceramic‐Sulfide Electrolytes
journal, July 2019
- Fitzhugh, William; Wu, Fan; Ye, Luhan
- Small
Lithium ion, lithium metal, and alternative rechargeable battery technologies: the odyssey for high energy density
journal, May 2017
- Placke, Tobias; Kloepsch, Richard; Dühnen, Simon
- Journal of Solid State Electrochemistry, Vol. 21, Issue 7
Relevance of solid electrolytes for lithium-based batteries: A realistic view
journal, June 2017
- Lotsch, Bettina V.; Maier, Joachim
- Journal of Electroceramics, Vol. 38, Issue 2-4
Mechanistic understanding and strategies to design interfaces of solid electrolytes: insights gained from transmission electron microscopy
journal, May 2019
- Hood, Zachary D.; Chi, Miaofang
- Journal of Materials Science, Vol. 54, Issue 15
Electrical and complex dielectric behaviour of composite polymer electrolyte based on PEO, alumina and tetrapropylammonium iodide
journal, February 2017
- Bandara, T. M. W. J.; Karunathilaka, D. G. N.; Ratnasekera, J. L.
- Ionics, Vol. 23, Issue 7
Cell Concepts of Metal–Sulfur Batteries (Metal = Li, Na, K, Mg): Strategies for Using Sulfur in Energy Storage Applications
journal, September 2017
- Medenbach, Lukas; Adelhelm, Philipp
- Topics in Current Chemistry, Vol. 375, Issue 5
High-throughput computational design of cathode coatings for Li-ion batteries
journal, December 2016
- Aykol, Muratahan; Kim, Soo; Hegde, Vinay I.
- Nature Communications, Vol. 7, Issue 1
A solid future for battery development
journal, September 2016
- Janek, Jürgen; Zeier, Wolfgang G.
- Nature Energy, Vol. 1, Issue 9
Fundamentals of inorganic solid-state electrolytes for batteries
journal, August 2019
- Famprikis, Theodosios; Canepa, Pieremanuele; Dawson, James A.
- Nature Materials, Vol. 18, Issue 12
Understanding interface stability in solid-state batteries
journal, December 2019
- Xiao, Yihan; Wang, Yan; Bo, Shou-Hang
- Nature Reviews Materials, Vol. 5, Issue 2
Three-dimensional bilayer garnet solid electrolyte based high energy density lithium metal–sulfur batteries
journal, January 2017
- Fu, Kun (Kelvin); Gong, Yunhui; Hitz, Gregory T.
- Energy & Environmental Science, Vol. 10, Issue 7
Enhanced Li + conduction in perovskite Li 3x La 2/3−x □ 1/3−2x TiO 3 solid-electrolytes via microstructural engineering
journal, January 2017
- Kwon, Woo Ju; Kim, Hyeongil; Jung, Kyu-Nam
- Journal of Materials Chemistry A, Vol. 5, Issue 13
Sur-/interfacial regulation in all-solid-state rechargeable Li-ion batteries based on inorganic solid-state electrolytes: advances and perspectives
journal, January 2019
- Liang, Longwei; Sun, Xuan; Zhang, Jinyang
- Materials Horizons, Vol. 6, Issue 5
A theoretical approach to address interfacial problems in all-solid-state lithium ion batteries: tuning materials chemistry for electrolyte and buffer coatings based on Li 6 PA 5 Cl hali-chalcogenides
journal, January 2019
- Xu, Hongjie; Yu, Yuran; Wang, Zhuo
- Journal of Materials Chemistry A, Vol. 7, Issue 10
Tailored high cycling performance in a solid polymer electrolyte with perovskite-type Li 0.33 La 0.557 TiO 3 nanofibers for all-solid-state lithium ion batteries
journal, January 2019
- He, Kang-Qiang; Zha, Jun-Wei; Du, Peng
- Dalton Transactions, Vol. 48, Issue 10
Solution-based synthesis of lithium thiophosphate superionic conductors for solid-state batteries: a chemistry perspective
journal, January 2019
- Ghidiu, Michael; Ruhl, Justine; Culver, Sean P.
- Journal of Materials Chemistry A, Vol. 7, Issue 30
Oriented porous LLZO 3D structures obtained by freeze casting for battery applications
journal, January 2019
- Shen, Hao; Yi, Eongyu; Amores, Marco
- Journal of Materials Chemistry A, Vol. 7, Issue 36
Research Update: The materials genome initiative: Data sharing and the impact of collaborative ab initio databases
journal, March 2016
- Jain, Anubhav; Persson, Kristin A.; Ceder, Gerbrand
- APL Materials, Vol. 4, Issue 5
Recent progress for all solid state battery using sulfide and oxide solid electrolytes
journal, January 2019
- Shoji, Mao; Cheng, Eric Jianfeng; Kimura, Takeshi
- Journal of Physics D: Applied Physics, Vol. 52, Issue 10
In Situ Scanning Electron Microscope Observations of Li Plating/Stripping Reactions with Pt Current Collectors on LiPON Electrolyte
journal, January 2018
- Motoyama, Munekazu; Ejiri, Makoto; Yamamoto, Takayuki
- Journal of The Electrochemical Society, Vol. 165, Issue 7
Effect of Microstructure on the Ionic Conductivity of an All Solid-State Battery Electrode
journal, January 2019
- Froboese, Linus; Sichel, Jan Felix van der; Loellhoeffel, Thomas
- Journal of The Electrochemical Society, Vol. 166, Issue 2
Computational Screening of Anode Materials for Sodium-Ion Batteries
journal, January 2019
- Yu, Seungho; Kim, Sang-Ok; Kim, Hyung-Seok
- Journal of The Electrochemical Society, Vol. 166, Issue 10
Lithium Metal Penetration Induced by Electrodeposition through Solid Electrolytes: Example in Single-Crystal Li 6 La 3 ZrTaO 12 Garnet
journal, January 2018
- Swamy, Tushar; Park, Richard; Sheldon, Brian W.
- Journal of The Electrochemical Society, Vol. 165, Issue 16
Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries
journal, January 2017
- Kerman, Kian; Luntz, Alan; Viswanathan, Venkatasubramanian
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Theoretical study of cubic-Li7La3Zr2O12(001)/LiCoO2(10–14) interface
journal, March 2018
- Panahian Jand, Sara; Kaghazchi, Payam
- MRS Communications, Vol. 8, Issue 02
In situ surface protection for enhancing stability and performance of conversion-type cathodes
journal, January 2017
- Wu, Feixiang; Borodin, Oleg; Yushin, Gleb
- MRS Energy & Sustainability, Vol. 4
Processing of Advanced Battery Materials—Laser Cutting of Pure Lithium Metal Foils
journal, August 2018
- Jansen, Tobias; Blass, David; Hartwig, Sven
- Batteries, Vol. 4, Issue 3
Reducing Interfacial Resistance between Garnet-Structured Solid-State Electrolyte and Li-Metal Anode by a Germanium Layer
journal, April 2017
- Luo, Wei; Gong, Yunhui; Zhu, Yizhou
- Advanced Materials, Vol. 29, Issue 22
Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries
journal, February 2018
- Gao, Zhonghui; Sun, Huabin; Fu, Lin
- Advanced Materials, Vol. 30, Issue 17
Electrochemical and Structural Analysis in All‐Solid‐State Lithium Batteries by Analytical Electron Microscopy: Progress and Perspectives
journal, October 2019
- Zhang, Chunchen; Feng, Yuzhang; Han, Zhen
- Advanced Materials
In Situ Direct Lithium Distribution Analysis Around Interfaces in an All‐Solid‐State Rechargeable Lithium Battery by Combined Ion‐Beam Method
journal, April 2019
- Tsuchiya, Bun; Ohnishi, Junji; Sasaki, Yoshitaka
- Advanced Materials Interfaces, Vol. 6, Issue 14
Fabrication of Sub-Micrometer-Thick Solid Electrolyte Membranes of β-Li 3 PS 4 via Tiled Assembly of Nanoscale, Plate-Like Building Blocks
journal, May 2018
- Hood, Zachary D.; Wang, Hui; Pandian, Amaresh Samuthira
- Advanced Energy Materials, Vol. 8, Issue 21
Sulfide Solid Electrolytes for Lithium Battery Applications
journal, August 2018
- Lau, Jonathan; DeBlock, Ryan H.; Butts, Danielle M.
- Advanced Energy Materials, Vol. 8, Issue 27
Origin of Degradation in Si-Based All-Solid-State Li-Ion Microbatteries
journal, September 2018
- Chen, Chunguang; Oudenhoven, Jos F. M.; Danilov, Dmitri L.
- Advanced Energy Materials, Vol. 8, Issue 30
Dopant‐Dependent Stability of Garnet Solid Electrolyte Interfaces with Lithium Metal
journal, January 2019
- Zhu, Yisi; Connell, Justin G.; Tepavcevic, Sanja
- Advanced Energy Materials, Vol. 9, Issue 12
Unraveling the Intra and Intercycle Interfacial Evolution of Li 6 PS 5 Cl‐Based All‐Solid‐State Lithium Batteries
journal, December 2019
- Zhang, Jun; Zheng, Chao; Li, Lujie
- Advanced Energy Materials, Vol. 10, Issue 4
Transient Behavior of the Metal Interface in Lithium Metal-Garnet Batteries
journal, October 2017
- Fu, Kun Kelvin; Gong, Yunhui; Fu, Zhezhen
- Angewandte Chemie, Vol. 129, Issue 47
Lithium Chlorides and Bromides as Promising Solid‐State Chemistries for Fast Ion Conductors with Good Electrochemical Stability
journal, May 2019
- Wang, Shuo; Bai, Qiang; Nolan, Adelaide M.
- Angewandte Chemie, Vol. 131, Issue 24
A Ceramic-PVDF Composite Membrane with Modified Interfaces as an Ion-Conducting Electrolyte for Solid-State Lithium-Ion Batteries Operating at Room Temperature
journal, July 2018
- Yu, Jing; Kwok, Stephen C. T.; Lu, Ziheng
- ChemElectroChem, Vol. 5, Issue 19
Computational screening of anode materials for potassium‐ion batteries
journal, August 2019
- Yu, Seungho; Kim, Sang‐Ok; Kim, Hyung‐Seok
- International Journal of Energy Research
Electrochemically primed functional redox mediator generator from the decomposition of solid state electrolyte
journal, April 2019
- Li, Matthew; Bai, Zhengyu; Li, Yejing
- Nature Communications, Vol. 10, Issue 1
Oxysulfide LiAlSO: A Lithium Superionic Conductor from First Principles
journal, May 2017
- Wang, Xuelong; Xiao, Ruijuan; Li, Hong
- Physical Review Letters, Vol. 118, Issue 19
Dense freeze-cast Li 7 La 3 Zr 2 O 12 solid electrolytes with oriented open porosity and contiguous ceramic scaffold
journal, August 2018
- Buannic, Lucienne; Naviroj, Maninpat; Miller, Sarah M.
- Journal of the American Ceramic Society, Vol. 102, Issue 3
Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface
journal, April 2017
- Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang
- Science Advances, Vol. 3, Issue 4
Interfaces Between Cathode and Electrolyte in Solid State Lithium Batteries: Challenges and Perspectives
journal, December 2018
- Nie, Kaihui; Hong, Yanshuai; Qiu, Jiliang
- Frontiers in Chemistry, Vol. 6
Challenges and prospects of the role of solid electrolytes in the revitalization of lithium metal batteries
text, January 2016
- Varzi, A.; Raccichini, R.; Passerini, S.
- Karlsruhe
A High‐Throughput Search for Functionally Stable Interfaces in Sulfide Solid‐State Lithium Ion Conductors
journal, April 2019
- Fitzhugh, William; Wu, Fan; Ye, Luhan
- Advanced Energy Materials, Vol. 9, Issue 21
Simulation of the Effect of Contact Area Loss in All-Solid-State Li-Ion Batteries
journal, January 2017
- Tian, Hong-Kang; Qi, Yue
- Journal of The Electrochemical Society, Vol. 164, Issue 11
Strategies Based on Nitride Materials Chemistry to Stabilize Li Metal Anode
text, January 2017
- Zhu, Yizhou; He, Xingfeng; Mo, Yifei
- Digital Repository at the University of Maryland
Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All-Solid-State Batteries
journal, April 2018
- Park, Kern Ho; Bai, Qiang; Kim, Dong Hyeon
- Advanced Energy Materials, Vol. 8, Issue 18
Lithium Chlorides and Bromides as Promising Solid‐State Chemistries for Fast Ion Conductors with Good Electrochemical Stability
journal, June 2019
- Wang, Shuo; Bai, Qiang; Nolan, Adelaide M.
- Angewandte Chemie International Edition, Vol. 58, Issue 24
High throughput identification of Li ion diffusion pathways in typical solid state electrolytes and electrode materials by BV-Ewald method
journal, January 2019
- Chen, Dajun; Jie, Jianshu; Weng, Mouyi
- Journal of Materials Chemistry A, Vol. 7, Issue 3
Theoretical tuning of Ruddlesden–Popper type anti-perovskite phases as superb ion conductors and cathodes for solid sodium ion batteries
journal, January 2019
- Yu, Yuran; Wang, Zhuo; Shao, Guosheng
- Journal of Materials Chemistry A, Vol. 7, Issue 17
Fabrication of a Dendrite‐Free all Solid‐State Li Metal Battery via Polymer Composite/Garnet/Polymer Composite Layered Electrolyte
journal, May 2019
- Pervez, Syed Atif; Ganjeh‐Anzabi, Pejman; Farooq, Umer
- Advanced Materials Interfaces