3D Nanofabrication via Chemo-Mechanical Transformation of Nanocrystal/Bulk Heterostructures
Abstract
In this paper, planar nanocrystal/bulk heterostructures are transformed into 3D architectures by taking advantage of the different chemical and mechanical properties of nanocrystal and bulk thin films. Nanocrystal/bulk heterostructures are fabricated via bottom-up assembly and top-down fabrication. The nanocrystals are capped by long ligands introduced in their synthesis, and therefore their surfaces are chemically addressable, and their assemblies are mechanically “soft,” in contrast to the bulk films. Chemical modification of the nanocrystal surface, exchanging the long ligands for more compact chemistries, triggers large volume shrinkage of the nanocrystal layer and drives bending of the nanocrystal/bulk heterostructures. Finally, exploiting the differential chemo-mechanical properties of nanocrystal and bulk materials, the scalable fabrication of designed 3D, cell-sized nanocrystal/bulk superstructures is demonstrated, which possess unique functions derived from nanocrystal building blocks.
- Authors:
-
[1];
[1]
- Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Electrical and Systems Engineering. Dept. of Chemistry. Dept. of Materials Science and Engineering
- Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering
- Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Chemistry
- Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Electrical and Systems Engineering
- Karlsruhe Inst. of Technology (KIT) (Germany). Karlsruhe Nano Micro Facility. Inst. of Nanotechnology
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
- Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Chemistry. Dept. of Materials Science and Engineering
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Brookhaven National Laboratory (BNL), Upton, NY (United States); Univ. of Pennsylvania, Philadelphia, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Chinese Scholarship Counsel (CSC)
- OSTI Identifier:
- 1464114
- Alternate Identifier(s):
- OSTI ID: 1433271
- Report Number(s):
- BNL-207949-2018-JAAM
Journal ID: ISSN 0935-9648
- Grant/Contract Number:
- SC0012704; SC0001004; CMMI-1562884; NSF-561658; DMR-1720530
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 30; Journal Issue: 22; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 3D patterning; folding; ligand chemistry; nanocrystal; nanoimprint lithography
Citation Formats
Zhang, Mingliang, Guo, Jiacen, Yu, Yao, Wu, Yaoting, Yun, Hongseok, Jishkariani, Davit, Chen, Wenxiang, Greybush, Nicholas J., Kübel, Christian, Stein, Aaron, Murray, Christopher B., and Kagan, Cherie R. 3D Nanofabrication via Chemo-Mechanical Transformation of Nanocrystal/Bulk Heterostructures. United States: N. p., 2018.
Web. doi:10.1002/adma.201800233.
Zhang, Mingliang, Guo, Jiacen, Yu, Yao, Wu, Yaoting, Yun, Hongseok, Jishkariani, Davit, Chen, Wenxiang, Greybush, Nicholas J., Kübel, Christian, Stein, Aaron, Murray, Christopher B., & Kagan, Cherie R. 3D Nanofabrication via Chemo-Mechanical Transformation of Nanocrystal/Bulk Heterostructures. United States. https://doi.org/10.1002/adma.201800233
Zhang, Mingliang, Guo, Jiacen, Yu, Yao, Wu, Yaoting, Yun, Hongseok, Jishkariani, Davit, Chen, Wenxiang, Greybush, Nicholas J., Kübel, Christian, Stein, Aaron, Murray, Christopher B., and Kagan, Cherie R. Sun .
"3D Nanofabrication via Chemo-Mechanical Transformation of Nanocrystal/Bulk Heterostructures". United States. https://doi.org/10.1002/adma.201800233. https://www.osti.gov/servlets/purl/1464114.
@article{osti_1464114,
title = {3D Nanofabrication via Chemo-Mechanical Transformation of Nanocrystal/Bulk Heterostructures},
author = {Zhang, Mingliang and Guo, Jiacen and Yu, Yao and Wu, Yaoting and Yun, Hongseok and Jishkariani, Davit and Chen, Wenxiang and Greybush, Nicholas J. and Kübel, Christian and Stein, Aaron and Murray, Christopher B. and Kagan, Cherie R.},
abstractNote = {In this paper, planar nanocrystal/bulk heterostructures are transformed into 3D architectures by taking advantage of the different chemical and mechanical properties of nanocrystal and bulk thin films. Nanocrystal/bulk heterostructures are fabricated via bottom-up assembly and top-down fabrication. The nanocrystals are capped by long ligands introduced in their synthesis, and therefore their surfaces are chemically addressable, and their assemblies are mechanically “soft,” in contrast to the bulk films. Chemical modification of the nanocrystal surface, exchanging the long ligands for more compact chemistries, triggers large volume shrinkage of the nanocrystal layer and drives bending of the nanocrystal/bulk heterostructures. Finally, exploiting the differential chemo-mechanical properties of nanocrystal and bulk materials, the scalable fabrication of designed 3D, cell-sized nanocrystal/bulk superstructures is demonstrated, which possess unique functions derived from nanocrystal building blocks.},
doi = {10.1002/adma.201800233},
journal = {Advanced Materials},
number = 22,
volume = 30,
place = {United States},
year = {Sun Apr 15 00:00:00 EDT 2018},
month = {Sun Apr 15 00:00:00 EDT 2018}
}
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