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Title: Use of an ion mobility spectrometer for detecting uranium compounds

Abstract

The safeguards community currently lacks a method to rapidly determine the chemical form of radioactive and non-radioactive compounds in real time during inspection activities. Chemical speciation identification can provide important information on both the types of materials that are collected during environmental sampling and can inform inspectors as to where to focus efforts during inspections or complementary access visits. Ion Mobility Spectrometry (IMS) is an established field technique for the detection of explosives, narcotics, and other organic compounds. More recently, electrospray ionization (ESI) has been used to introduce inorganic compounds to IMS instruments for analysis. These techniques have shown the ability to supply chemical information about the compounds being analyzed. Although these laboratory based instruments use a liquid-based injection system, there is evidence in the literature of unaltered and intact pharmaceutical tablets being volatilized and ionized in open atmosphere using heat and a Ni-63 source. Lastly, this work determined that a commercial-off-the-shelf (COTS) IMS could be used for the identification of solid uranium compounds directly after sampling using a COTS sample swipe.

Authors:
 [1];  [1];  [1]
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  1. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1433059
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Talanta
Additional Journal Information:
Journal Volume: 184; Journal Issue: C; Journal ID: ISSN 0039-9140
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; Safeguards; Ion Mobility Spectrometry; Rapid Analysis; Uranium

Citation Formats

McLain, Derek R., Steeb, Jennifer L., and Smith, Nicholas A. Use of an ion mobility spectrometer for detecting uranium compounds. United States: N. p., 2018. Web. doi:10.1016/j.talanta.2018.03.020.
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McLain, Derek R., Steeb, Jennifer L., & Smith, Nicholas A. Use of an ion mobility spectrometer for detecting uranium compounds. United States. https://doi.org/10.1016/j.talanta.2018.03.020
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McLain, Derek R., Steeb, Jennifer L., and Smith, Nicholas A. Fri . "Use of an ion mobility spectrometer for detecting uranium compounds". United States. https://doi.org/10.1016/j.talanta.2018.03.020. https://www.osti.gov/servlets/purl/1433059.
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@article{osti_1433059,
title = {Use of an ion mobility spectrometer for detecting uranium compounds},
author = {McLain, Derek R. and Steeb, Jennifer L. and Smith, Nicholas A.},
abstractNote = {The safeguards community currently lacks a method to rapidly determine the chemical form of radioactive and non-radioactive compounds in real time during inspection activities. Chemical speciation identification can provide important information on both the types of materials that are collected during environmental sampling and can inform inspectors as to where to focus efforts during inspections or complementary access visits. Ion Mobility Spectrometry (IMS) is an established field technique for the detection of explosives, narcotics, and other organic compounds. More recently, electrospray ionization (ESI) has been used to introduce inorganic compounds to IMS instruments for analysis. These techniques have shown the ability to supply chemical information about the compounds being analyzed. Although these laboratory based instruments use a liquid-based injection system, there is evidence in the literature of unaltered and intact pharmaceutical tablets being volatilized and ionized in open atmosphere using heat and a Ni-63 source. Lastly, this work determined that a commercial-off-the-shelf (COTS) IMS could be used for the identification of solid uranium compounds directly after sampling using a COTS sample swipe.},
doi = {10.1016/j.talanta.2018.03.020},
journal = {Talanta},
number = C,
volume = 184,
place = {United States},
year = {2018},
month = {3}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1016/j.talanta.2018.03.020
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Figures / Tables:

Table 1 Table 1: Common instruments used for detecting uranium contamination, along with their detection method, typical background activity, and the corresponding mass of DU.
All figures and tables (9 total)
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Works referenced in this record:

Dopant-Assisted Negative Photoionization Ion Mobility Spectrometry for Sensitive Detection of Explosives
journal, December 2012

  • Cheng, Shasha; Dou, Jian; Wang, Weiguo
  • Analytical Chemistry, Vol. 85, Issue 1
  • DOI: 10.1021/ac302836f

Beta electron-assisted direct chemical ionization (BADCI) probe for ambient mass spectrometry
journal, January 2009

  • Steeb, Jennifer; Galhena, Asiri S.; Nyadong, Leonard
  • Chemical Communications, Issue 31
  • DOI: 10.1039/b909072j

Development, optimization, and use of an APCI source with temperature-controlled vaporization of solid and liquid samples
journal, November 2012

  • Krieger, Sonja; von Trotha, Alexandra; Leung, Kelvin Sze-Yin
  • Analytical and Bioanalytical Chemistry, Vol. 405, Issue 4
  • DOI: 10.1007/s00216-012-6531-4

Direct inlet probe ion mobility spectrometry
journal, April 2018

Interfacing an Ion Mobility Spectrometry Based Explosive Trace Detector to a Triple Quadrupole Mass Spectrometer
journal, November 2011

  • Kozole, Joseph; Stairs, Jason R.; Cho, Inho
  • Analytical Chemistry, Vol. 83, Issue 22
  • DOI: 10.1021/ac201999a

Limits for qualitative detection and quantitative determination. Application to radiochemistry
journal, March 1968

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    Works referencing / citing this record:

    Rapid paper spray mass spectrometry characterization of uranium and exemplar molecular species
    journal, October 2019

    • Coopersmith, Kaitlin; Cody, Robert B.; Mannion, Joseph M.
    • Rapid Communications in Mass Spectrometry, Vol. 33, Issue 22
    • DOI: 10.1002/rcm.8517
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      Figures / Tables found in this record:

      Table 1 (p. 4)table
      Table 2 (p. 7)table
      Table 3 (p. 7)table
      Figure 1 (p. 9)figure
      Figure 2 (p. 10)figure
      Figure 3 (p. 11)figure
      Figure 4 (p. 12)figure
      Figure 5 (p. 13)figure
      Figure 6 (p. 14)figure
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