Use of an ion mobility spectrometer for detecting uranium compounds
Abstract
The safeguards community currently lacks a method to rapidly determine the chemical form of radioactive and non-radioactive compounds in real time during inspection activities. Chemical speciation identification can provide important information on both the types of materials that are collected during environmental sampling and can inform inspectors as to where to focus efforts during inspections or complementary access visits. Ion Mobility Spectrometry (IMS) is an established field technique for the detection of explosives, narcotics, and other organic compounds. More recently, electrospray ionization (ESI) has been used to introduce inorganic compounds to IMS instruments for analysis. These techniques have shown the ability to supply chemical information about the compounds being analyzed. Although these laboratory based instruments use a liquid-based injection system, there is evidence in the literature of unaltered and intact pharmaceutical tablets being volatilized and ionized in open atmosphere using heat and a Ni-63 source. Lastly, this work determined that a commercial-off-the-shelf (COTS) IMS could be used for the identification of solid uranium compounds directly after sampling using a COTS sample swipe.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1433059
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Talanta
- Additional Journal Information:
- Journal Volume: 184; Journal Issue: C; Journal ID: ISSN 0039-9140
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; Safeguards; Ion Mobility Spectrometry; Rapid Analysis; Uranium
Citation Formats
McLain, Derek R., Steeb, Jennifer L., and Smith, Nicholas A. Use of an ion mobility spectrometer for detecting uranium compounds. United States: N. p., 2018.
Web. doi:10.1016/j.talanta.2018.03.020.
McLain, Derek R., Steeb, Jennifer L., & Smith, Nicholas A. Use of an ion mobility spectrometer for detecting uranium compounds. United States. https://doi.org/10.1016/j.talanta.2018.03.020
McLain, Derek R., Steeb, Jennifer L., and Smith, Nicholas A. Fri .
"Use of an ion mobility spectrometer for detecting uranium compounds". United States. https://doi.org/10.1016/j.talanta.2018.03.020. https://www.osti.gov/servlets/purl/1433059.
@article{osti_1433059,
title = {Use of an ion mobility spectrometer for detecting uranium compounds},
author = {McLain, Derek R. and Steeb, Jennifer L. and Smith, Nicholas A.},
abstractNote = {The safeguards community currently lacks a method to rapidly determine the chemical form of radioactive and non-radioactive compounds in real time during inspection activities. Chemical speciation identification can provide important information on both the types of materials that are collected during environmental sampling and can inform inspectors as to where to focus efforts during inspections or complementary access visits. Ion Mobility Spectrometry (IMS) is an established field technique for the detection of explosives, narcotics, and other organic compounds. More recently, electrospray ionization (ESI) has been used to introduce inorganic compounds to IMS instruments for analysis. These techniques have shown the ability to supply chemical information about the compounds being analyzed. Although these laboratory based instruments use a liquid-based injection system, there is evidence in the literature of unaltered and intact pharmaceutical tablets being volatilized and ionized in open atmosphere using heat and a Ni-63 source. Lastly, this work determined that a commercial-off-the-shelf (COTS) IMS could be used for the identification of solid uranium compounds directly after sampling using a COTS sample swipe.},
doi = {10.1016/j.talanta.2018.03.020},
journal = {Talanta},
number = C,
volume = 184,
place = {United States},
year = {Fri Mar 09 00:00:00 EST 2018},
month = {Fri Mar 09 00:00:00 EST 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Ion Mobility Spectrometry: Principles and Applications
journal, August 2006
- Borsdorf, Helko; Eiceman, Gary A.
- Applied Spectroscopy Reviews, Vol. 41, Issue 4
Dopant-Assisted Negative Photoionization Ion Mobility Spectrometry for Sensitive Detection of Explosives
journal, December 2012
- Cheng, Shasha; Dou, Jian; Wang, Weiguo
- Analytical Chemistry, Vol. 85, Issue 1
A critical review of ion mobility spectrometry for the detection of explosives and explosive related compounds
journal, May 2001
- Ewing, R.
- Talanta, Vol. 54, Issue 3
Ion Mobility Spectrometry
journal, December 1990
- Hill, Herbert H.; Siems, William F.; Louis, Robert H. St.
- Analytical Chemistry, Vol. 62, Issue 23
Comparison of reactant and analyte ions for 63Nickel, corona discharge, and secondary electrospray ionization sources with ion mobility-mass spectrometry
journal, March 2013
- Crawford, C. L.; Hill, H. H.
- Talanta, Vol. 107
Detection of inorganic ions from water by electrospray ionization-ion mobility spectrometry
journal, July 2002
- Dion, H.
- Talanta, Vol. 57, Issue 6
The novel analysis of uranyl compounds by electrospray-ion mobility-mass spectrometry
journal, January 2013
- Crawford, Christina L.; Fugate, Glenn A.; Cable-Dunlap, Paula R.
- International Journal of Mass Spectrometry, Vol. 333
Stabilization of gas-phase uranyl complexes enables rapid speciation using electrospray ionization and ion mobility-mass spectrometry
journal, January 2018
- Davis, Austen L.; Clowers, Brian H.
- Talanta, Vol. 176
A review of recent, unconventional applications of ion mobility spectrometry (IMS)
journal, October 2011
- Armenta, Sergio; Alcala, Manel; Blanco, Marcelo
- Analytica Chimica Acta, Vol. 703, Issue 2
Beta electron-assisted direct chemical ionization (BADCI) probe for ambient mass spectrometry
journal, January 2009
- Steeb, Jennifer; Galhena, Asiri S.; Nyadong, Leonard
- Chemical Communications, Issue 31
Development, optimization, and use of an APCI source with temperature-controlled vaporization of solid and liquid samples
journal, November 2012
- Krieger, Sonja; von Trotha, Alexandra; Leung, Kelvin Sze-Yin
- Analytical and Bioanalytical Chemistry, Vol. 405, Issue 4
Direct inlet probe ion mobility spectrometry
journal, April 2018
- Kuklya, Andriy; Coban, Lokman; Uteschil, Florian
- Talanta, Vol. 180
Interfacing an Ion Mobility Spectrometry Based Explosive Trace Detector to a Triple Quadrupole Mass Spectrometer
journal, November 2011
- Kozole, Joseph; Stairs, Jason R.; Cho, Inho
- Analytical Chemistry, Vol. 83, Issue 22
Limits for qualitative detection and quantitative determination. Application to radiochemistry
journal, March 1968
- Currie, Lloyd A.
- Analytical Chemistry, Vol. 40, Issue 3
Review on Ion Mobility Spectrometry. Part 1: current instrumentation
journal, January 2015
- Cumeras, R.; Figueras, E.; Davis, C. E.
- The Analyst, Vol. 140, Issue 5
Works referencing / citing this record:
Rapid paper spray mass spectrometry characterization of uranium and exemplar molecular species
journal, October 2019
- Coopersmith, Kaitlin; Cody, Robert B.; Mannion, Joseph M.
- Rapid Communications in Mass Spectrometry, Vol. 33, Issue 22
Figures / Tables found in this record: