Sequence-Mandated, Distinct Assembly of Giant Molecules
Abstract
Although controlling the primary structure of synthetic polymers is itself a great challenge, the potential of sequence control for tailoring hierarchical structures remains to be exploited, especially in the creation of new and unconventional phases. A series of model amphiphilic chain-like giant molecules was designed and synthesized by interconnecting both hydrophobic and hydrophilic molecular nanoparticles in precisely defined sequence and composition to investigate their sequence-dependent phase structures. Not only compositional variation changed the self-assembled supramolecular phases, but also specific sequences induce unconventional phase formation, including Frank-Kasper phases. The formation mechanism was attributed to the conformational change driven by the collective hydrogen bonding and the sequence-mandated topology of the molecules. Lastly, these results show that sequence control in synthetic polymers can have a dramatic impact on polymer properties and self-assembly.
- Authors:
-
- Univ. of Akron, OH (United States). Dept. of Polymer Science, College of Polymer Science and Polymer Engineering
- Univ. of Akron, OH (United States). Dept. of Chemistry
- Univ. of Akron, OH (United States). Dept. of Polymer Science, College of Polymer Science and Polymer Engineering, and Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division; Northern Illinois Univ., DeKalb, IL (United States). Dept. of Chemistry and Biochemistry
- Peking Univ., Beijing (China). Key Lab. of Polymer Chemistry and Physics of the Ministry of Education, College of Chemistry and Molecular Engineering, Center for Soft Matter Science and Engineering
- Sichuan Univ., Chengdu (China). College of Polymer Science and Engineering, State Key Lab. of Polymer Materials Engineering
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Science Foundation (NSF); National Natural Science Foundation of China (NNSFC)
- OSTI Identifier:
- 1432999
- Alternate Identifier(s):
- OSTI ID: 1408927
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 56; Journal Issue: 47; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Frank-Kasper phase; POSS; polymer; sequence; supramolecular structure; polyhedral oligomeric silsesquioxane
Citation Formats
Zhang, Wei, Lu, Xinlin, Mao, Jialin, Hsu, Chih-Hao, Mu, Gaoyan, Huang, Mingjun, Guo, Qingyun, Liu, Hao, Wesdemiotis, Chrys, Li, Tao, Zhang, Wen-Bin, Li, Yiwen, and Cheng, Stephen Z.D. Sequence-Mandated, Distinct Assembly of Giant Molecules. United States: N. p., 2017.
Web. doi:10.1002/anie.201709354.
Zhang, Wei, Lu, Xinlin, Mao, Jialin, Hsu, Chih-Hao, Mu, Gaoyan, Huang, Mingjun, Guo, Qingyun, Liu, Hao, Wesdemiotis, Chrys, Li, Tao, Zhang, Wen-Bin, Li, Yiwen, & Cheng, Stephen Z.D. Sequence-Mandated, Distinct Assembly of Giant Molecules. United States. doi:10.1002/anie.201709354.
Zhang, Wei, Lu, Xinlin, Mao, Jialin, Hsu, Chih-Hao, Mu, Gaoyan, Huang, Mingjun, Guo, Qingyun, Liu, Hao, Wesdemiotis, Chrys, Li, Tao, Zhang, Wen-Bin, Li, Yiwen, and Cheng, Stephen Z.D. Tue .
"Sequence-Mandated, Distinct Assembly of Giant Molecules". United States. doi:10.1002/anie.201709354. https://www.osti.gov/servlets/purl/1432999.
@article{osti_1432999,
title = {Sequence-Mandated, Distinct Assembly of Giant Molecules},
author = {Zhang, Wei and Lu, Xinlin and Mao, Jialin and Hsu, Chih-Hao and Mu, Gaoyan and Huang, Mingjun and Guo, Qingyun and Liu, Hao and Wesdemiotis, Chrys and Li, Tao and Zhang, Wen-Bin and Li, Yiwen and Cheng, Stephen Z.D.},
abstractNote = {Although controlling the primary structure of synthetic polymers is itself a great challenge, the potential of sequence control for tailoring hierarchical structures remains to be exploited, especially in the creation of new and unconventional phases. A series of model amphiphilic chain-like giant molecules was designed and synthesized by interconnecting both hydrophobic and hydrophilic molecular nanoparticles in precisely defined sequence and composition to investigate their sequence-dependent phase structures. Not only compositional variation changed the self-assembled supramolecular phases, but also specific sequences induce unconventional phase formation, including Frank-Kasper phases. The formation mechanism was attributed to the conformational change driven by the collective hydrogen bonding and the sequence-mandated topology of the molecules. Lastly, these results show that sequence control in synthetic polymers can have a dramatic impact on polymer properties and self-assembly.},
doi = {10.1002/anie.201709354},
journal = {Angewandte Chemie (International Edition)},
number = 47,
volume = 56,
place = {United States},
year = {2017},
month = {10}
}
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