In operando X-ray diffraction strain measurement in Ni3Sn2 – Coated inverse opal nanoscaffold anodes for Li-ion batteries
Abstract
Volume changes associated with the (de)lithiation of a nanostructured Ni3Sn2 coated nickel inverse opal scaffold anode create mismatch stresses and strains between the Ni3Sn2 anode material and its mechanically supporting Ni scaffold. By using in operando synchrotron x-ray diffraction measurements, elastic strains in the Ni scaffold are determined during cyclic (dis)charging of the Ni3Sn2 anode. These strains are characterized using both the center position of the Ni diffraction peaks, to quantify the average strain, and the peak breadth, which describes the distribution of strain in the measured volume. Upon lithiation (half-cell discharging) or delithiation (half-cell charging), compressive strains and peak breadth linearly increase or decrease, respectively, with charge. The evolution of the average strains and peak breadths suggests that some irreversible plastic deformation and/or delamination occurs during cycling, which can result in capacity fade in the anode. The strain behavior associated with cycling of the Ni3Sn2 anode is similar to that observed in recent studies on a Ni inverse-opal supported amorphous Si anode and demonstrates that the (de)lithiation-induced deformation and damage mechanisms are likely equivalent in both anodes, even though the magnitude of mismatch strain in the Ni3Sn2 is lower due to the lower (de)lithiation-induced contraction/expansion.
- Authors:
-
[1];
- Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering; Exponent Inc., Menlo Park, CA (United States). Materials and Corrosion Engineering Practice
- Univ. of Illinois, Urbana, IL (United States). Dept. of Materials Science and Engineering
- Univ. of Illinois, Urbana, IL (United States). Dept. of Materials Science and Engineering; Korea Basic Science Inst., Gangneung (Korea, Republic of). Gangneung Center
- Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
- Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1432952
- Alternate Identifier(s):
- OSTI ID: 1549316; OSTI ID: 1875504
- Grant/Contract Number:
- AC02-06CH11357; FG02-07ER46471
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 367; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; Tin anodes; In operando; Lithiation strain; Intermetallic alloying anode; Microbattery
Citation Formats
Glazer, Matthew P. B., Wang, Junjie, Cho, Jiung, Almer, Jonathan D., Okasinski, John S., Braun, Paul V., and Dunand, David C. In operando X-ray diffraction strain measurement in Ni3Sn2 – Coated inverse opal nanoscaffold anodes for Li-ion batteries. United States: N. p., 2017.
Web. doi:10.1016/j.jpowsour.2017.09.040.
Glazer, Matthew P. B., Wang, Junjie, Cho, Jiung, Almer, Jonathan D., Okasinski, John S., Braun, Paul V., & Dunand, David C. In operando X-ray diffraction strain measurement in Ni3Sn2 – Coated inverse opal nanoscaffold anodes for Li-ion batteries. United States. https://doi.org/10.1016/j.jpowsour.2017.09.040
Glazer, Matthew P. B., Wang, Junjie, Cho, Jiung, Almer, Jonathan D., Okasinski, John S., Braun, Paul V., and Dunand, David C. Wed .
"In operando X-ray diffraction strain measurement in Ni3Sn2 – Coated inverse opal nanoscaffold anodes for Li-ion batteries". United States. https://doi.org/10.1016/j.jpowsour.2017.09.040. https://www.osti.gov/servlets/purl/1432952.
@article{osti_1432952,
title = {In operando X-ray diffraction strain measurement in Ni3Sn2 – Coated inverse opal nanoscaffold anodes for Li-ion batteries},
author = {Glazer, Matthew P. B. and Wang, Junjie and Cho, Jiung and Almer, Jonathan D. and Okasinski, John S. and Braun, Paul V. and Dunand, David C.},
abstractNote = {Volume changes associated with the (de)lithiation of a nanostructured Ni3Sn2 coated nickel inverse opal scaffold anode create mismatch stresses and strains between the Ni3Sn2 anode material and its mechanically supporting Ni scaffold. By using in operando synchrotron x-ray diffraction measurements, elastic strains in the Ni scaffold are determined during cyclic (dis)charging of the Ni3Sn2 anode. These strains are characterized using both the center position of the Ni diffraction peaks, to quantify the average strain, and the peak breadth, which describes the distribution of strain in the measured volume. Upon lithiation (half-cell discharging) or delithiation (half-cell charging), compressive strains and peak breadth linearly increase or decrease, respectively, with charge. The evolution of the average strains and peak breadths suggests that some irreversible plastic deformation and/or delamination occurs during cycling, which can result in capacity fade in the anode. The strain behavior associated with cycling of the Ni3Sn2 anode is similar to that observed in recent studies on a Ni inverse-opal supported amorphous Si anode and demonstrates that the (de)lithiation-induced deformation and damage mechanisms are likely equivalent in both anodes, even though the magnitude of mismatch strain in the Ni3Sn2 is lower due to the lower (de)lithiation-induced contraction/expansion.},
doi = {10.1016/j.jpowsour.2017.09.040},
journal = {Journal of Power Sources},
number = C,
volume = 367,
place = {United States},
year = {Wed Nov 01 00:00:00 EDT 2017},
month = {Wed Nov 01 00:00:00 EDT 2017}
}
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