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Title: An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes

Journal Article · · Nature Chemistry
 [1];  [2];  [1];  [3];  [4];  [1];  [2];  [5];  [5];  [1]
  1. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  2. Univ. of Maryland, College Park, MD (United States)
  3. Colorado School of Mines, Golden, CO (United States)
  4. National Renewable Energy Lab. (NREL), Golden, CO (United States); Colorado School of Mines, Golden, CO (United States)
  5. Army Research Lab., Adelphi, MD (United States)
+ Show Author Affiliations

Magnesium-based batteries possess potential advantages over their lithium counterparts. However, reversible Mg chemistry requires a thermodynamically stable electrolyte at low potential, which is usually achieved with corrosive components and at the expense of stability against oxidation. In lithium-ion batteries the conflict between the cathodic and anodic stabilities of the electrolytes is resolved by forming an anode interphase that shields the electrolyte from being reduced. This strategy cannot be applied to Mg batteries because divalent Mg2+ cannot penetrate such interphases. Here, we engineer an artificial Mg2+-conductive interphase on the Mg anode surface, which successfully decouples the anodic and cathodic requirements for electrolytes and demonstrate highly reversible Mg chemistry in oxidation-resistant electrolytes. The artificial interphase enables the reversible cycling of a Mg/V2O5 full-cell in the water-containing, carbonate-based electrolyte. This approach provides a new avenue not only for Mg but also for other multivalent-cation batteries facing the same problems, taking a step towards their use in energy-storage applications.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), NREL Laboratory Directed Research and Development (LDRD)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1432192
Report Number(s):
NREL/JA-5900-66801; TRN: US1802409
Journal Information:
Nature Chemistry, Vol. 10, Issue 5; ISSN 1755-4330
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 299 works
Citation information provided by
Web of Science

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Highly Branched VS 4 Nanodendrites with 1D Atomic-Chain Structure as a Promising Cathode Material for Long-Cycling Magnesium Batteries journal June 2018
A Stable Solid Electrolyte Interphase for Magnesium Metal Anode Evolved from a Bulky Anion Lithium Salt journal December 2019
Interphases, Interfaces, and Surfaces of Active Materials in Rechargeable Batteries and Perovskite Solar Cells journal January 2020
Progress in Rechargeable Aqueous Zinc- and Aluminum-Ion Battery Electrodes: Challenges and Outlook journal October 2018
Graphite as a Long‐Life Ca 2+ ‐Intercalation Anode and its Implementation for Rocking‐Chair Type Calcium‐Ion Batteries journal October 2019
One‐Step Synthesis of 2‐Ethylhexylamine Pillared Vanadium Disulfide Nanoflowers with Ultralarge Interlayer Spacing for High‐Performance Magnesium Storage journal April 2019
Room‐Temperature Rechargeable Ca‐Ion Based Hybrid Batteries with High Rate Capability and Long‐Term Cycling Life journal June 2019
The Origin of the Reduced Reductive Stability of Ion–Solvent Complexes on Alkali and Alkaline Earth Metal Anodes journal December 2018
Halogenid‐basierte Materialien und Chemie für wiederaufladbare Batterien journal January 2020
A Metal–Organic Framework Thin Film for Selective Mg 2+ Transport journal September 2019
How Water Accelerates Bivalent Ion Diffusion at the Electrolyte/Electrode Interface journal August 2018
Halide‐Based Materials and Chemistry for Rechargeable Batteries journal January 2020
A Metal–Organic Framework Thin Film for Selective Mg 2+ Transport journal October 2019
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review journal January 2019
Electrolytes for Batteries with Earth-Abundant Metal Anodes journal November 2018
Water in Rechargeable Multivalent-Ion Batteries: An Electrochemical Pandora's Box journal January 2019
Recent Progress in Multivalent Metal (Mg, Zn, Ca, and Al) and Metal‐Ion Rechargeable Batteries with Organic Materials as Promising Electrodes journal March 2019
Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation journal November 2019
Bridging the academic and industrial metrics for next-generation practical batteries journal February 2019
Advances in sodium secondary batteries utilizing ionic liquid electrolytes journal January 2019
Using CoS cathode materials with 3D hierarchical porosity and an ionic liquid (IL) as an electrolyte additive for high capacity rechargeable magnesium batteries journal January 2019
Rechargeable aqueous hybrid ion batteries: developments and prospects journal January 2019
Ab initio modeling and design of vanadia-based electrode materials for post-lithium batteries journal December 2019
Post-Li batteries: promises and challenges
  • Ponrouch, Alexandre; Palacín, M. Rosa
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2152 https://doi.org/10.1098/rsta.2018.0297
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How Water Accelerates Bivalent Ion Diffusion at the Electrolyte/Electrode Interface journal August 2018
The Origin of the Reduced Reductive Stability of Ion–Solvent Complexes on Alkali and Alkaline Earth Metal Anodes journal December 2018
Elucidating Solvation Structures for Rational Design of Multivalent Electrolytes—A Review journal April 2018
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Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation journal November 2019

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