Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet EuCo2-yAs2

Sangeetha, N. S.; Anand, V. K.; Cuervo-Reyes, Eduardo; Smetana, V.; Mudring, A. -V.; Johnston, D. C.

doi:10.1103/PhysRevB.97.144403

Title: Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet ${EuCo}_{2 - y} {As}_{2}$

Abstract

${EuCo}_{2 - y} {As}_{2}$ with the tetragonal ThCr₂Si₂ structure is known to contain Eu⁺² ions with spin S=$$\frac{7}{2}$$that order below a temperature T_N ≈ 47 K into an antiferromagnetic (AFM) proper helical structure with the ordered moments aligned in the tetragonal ab plane, perpendicular to the helix axis along the c axis, with no contribution from the Co atoms. Here we carry out a detailed investigation of the properties of single crystals. We consistently find about 5% vacancies on the Co site from energy-dispersive x-ray analysis and x-ray diffraction refinements. Enhanced ordered and effective moments of the Eu spins are found in most of our crystals. Electronic structure calculations indicate that the enhanced moments arise from polarization of the d bands, as occurs in ferromagnetic Gd metal. Electrical resistivity measurements indicate metallic behavior. The low-field in-plane magnetic susceptibilities $$\chi_{ab}$$ (T < T_N) for several crystals are reported that are fitted well by unified molecular field theory (MFT), and the Eu–Eu exchange interactions J_ij are extracted from the fits. High-field magnetization M data for magnetic fields H ∥ ab reveal what appears to be a first-order spin-flop transition followed at higher field by a second-order metamagnetic transition of unknown origin, and then by another second-order transition to the paramagnetic (PM) state. For H ∥ c , the magnetization shows only a second-order transition from the canted AFM to the PM state, as expected. The critical fields for the AFM to PM transition are in approximate agreement with the predictions of MFT. Heat capacity C_p measurements in zero and high H are reported. Phase diagrams for H ∥ c and H ∥ ab versus T are constructed from the high-field M (H ,T) and C_p (H,T) measurements. Lastly, the magnetic part C_mag (T,H = 0) of C_p (T,H= 0) is extracted and is fitted rather well below T_N by MFT, although dynamic short-range AFM order is apparent in C_mag (T) up to about 70 K, where the molar entropy attains its high- T limit of R ln 8.

Authors:

Sangeetha, N. S. ^[1]; Anand, V. K. ^[1]; Cuervo-Reyes, Eduardo ^[2]; Smetana, V. ^[3]; Mudring, A. -V. ^[3]; Johnston, D. C. ^[4]

Ames Lab. and Iowa State Univ., Ames, IA (United States)
Swiss Federal Laboratories for Materials Science and Technology (Empa), Dubendorf (Switzerland)
Stockholm Univ. (Sweden). Dept. of Materials and Environmental Chemistry
Ames Lab. and Iowa State Univ., Ames, IA (United States); Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy

Publication Date:: Fri Apr 06 00:00:00 EDT 2018

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1433661

Alternate Identifier(s):: OSTI ID: 1432098

Report Number(s):: IS-J-9613
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US1802387

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 97; Journal Issue: 14; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Sangeetha, N. S., Anand, V. K., Cuervo-Reyes, Eduardo, Smetana, V., Mudring, A. -V., and Johnston, D. C. Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet EuCo2-yAs2.  United States: N. p., 2018. 
Web.  doi:10.1103/PhysRevB.97.144403.

Copy to clipboard


                    Sangeetha, N. S., Anand, V. K., Cuervo-Reyes, Eduardo, Smetana, V., Mudring, A. -V., & Johnston, D. C. Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet EuCo2-yAs2.  United States.  https://doi.org/10.1103/PhysRevB.97.144403

Copy to clipboard


                    Sangeetha, N. S., Anand, V. K., Cuervo-Reyes, Eduardo, Smetana, V., Mudring, A. -V., and Johnston, D. C. Fri .  
"Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet EuCo2-yAs2".  United States.  https://doi.org/10.1103/PhysRevB.97.144403.  https://www.osti.gov/servlets/purl/1433661.

Copy to clipboard


                    
@article{osti_1433661,

  title        = {Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet EuCo2-yAs2},

  author       = {Sangeetha, N. S. and Anand, V. K. and Cuervo-Reyes, Eduardo and Smetana, V. and Mudring, A. -V. and Johnston, D. C.},

  abstractNote = {EuCo2-yAs2 with the tetragonal ThCr2Si2 structure is known to contain Eu+2 ions with spin S=$\frac{7}{2}$that order below a temperature TN ≈ 47 K into an antiferromagnetic (AFM) proper helical structure with the ordered moments aligned in the tetragonal ab plane, perpendicular to the helix axis along the c axis, with no contribution from the Co atoms. Here we carry out a detailed investigation of the properties of single crystals. We consistently find about 5% vacancies on the Co site from energy-dispersive x-ray analysis and x-ray diffraction refinements. Enhanced ordered and effective moments of the Eu spins are found in most of our crystals. Electronic structure calculations indicate that the enhanced moments arise from polarization of the d bands, as occurs in ferromagnetic Gd metal. Electrical resistivity measurements indicate metallic behavior. The low-field in-plane magnetic susceptibilities $\chi_{ab}$ (T < TN) for several crystals are reported that are fitted well by unified molecular field theory (MFT), and the Eu–Eu exchange interactions Jij are extracted from the fits. High-field magnetization M data for magnetic fields H ∥ ab reveal what appears to be a first-order spin-flop transition followed at higher field by a second-order metamagnetic transition of unknown origin, and then by another second-order transition to the paramagnetic (PM) state. For H ∥ c , the magnetization shows only a second-order transition from the canted AFM to the PM state, as expected. The critical fields for the AFM to PM transition are in approximate agreement with the predictions of MFT. Heat capacity Cp measurements in zero and high H are reported. Phase diagrams for H ∥ c and H ∥ ab versus T are constructed from the high-field M (H ,T) and Cp (H,T) measurements. Lastly, the magnetic part Cmag (T,H = 0) of Cp (T,H= 0) is extracted and is fitted rather well below TN by MFT, although dynamic short-range AFM order is apparent in Cmag (T) up to about 70 K, where the molar entropy attains its high- T limit of R ln 8.},

  doi          = {10.1103/PhysRevB.97.144403},

  journal      = {Physical Review B},

  number       = 14,

  volume       = 97,

  place        = {United States},

  year         = {Fri Apr 06 00:00:00 EDT 2018},

  month        = {Fri Apr 06 00:00:00 EDT 2018}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/PhysRevB.97.144403

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 17 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

Itinerant and local-moment magnetism in ${EuCr}_{2}$ ${As}_{2}$ single crystals
journal, April 2014

Paramanik, U. B.; Prasad, R.; Geibel, C.
Physical Review B, Vol. 89, Issue 14
DOI: 10.1103/PhysRevB.89.144423

Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo $_{2}$ As $_{2}$
journal, July 2013

Pandey, Abhishek; Quirinale, D. G.; Jayasekara, W.
Physical Review B, Vol. 88, Issue 1
DOI: 10.1103/PhysRevB.88.014526

${EuCo}_{2} P_{2}$ : A model molecular-field helical Heisenberg antiferromagnet
journal, July 2016

Sangeetha, N. S.; Cuervo-Reyes, Eduardo; Pandey, Abhishek
Physical Review B, Vol. 94, Issue 1
DOI: 10.1103/PhysRevB.94.014422

Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators ${SrMn}_{2} {As}_{2}$ and ${CaMn}_{2} {As}_{2}$
journal, September 2016

Sangeetha, N. S.; Pandey, Abhishek; Benson, Zackery A.
Physical Review B, Vol. 94, Issue 9
DOI: 10.1103/PhysRevB.94.094417

Mössbauer and magnetic susceptibility investigations of strontium, lanthanum and europium transition metal phosphides with ThCr2Si2 type structure
journal, January 1988

Mörsen, E.; Mosel, B. D.; Müller-Warmuth, W.
Journal of Physics and Chemistry of Solids, Vol. 49, Issue 7
DOI: 10.1016/0022-3697(88)90030-3

Magnetic dipole interactions in crystals
journal, January 2016

Johnston, David C.
Physical Review B, Vol. 93, Issue 1
DOI: 10.1103/PhysRevB.93.014421

Spin-polarized energy-band structure, conduction-electron polarization, spin densities, and the neutron magnetic form factor of ferromagnetic gadolinium
journal, September 1974

Harmon, B. N.; Freeman, A. J.
Physical Review B, Vol. 10, Issue 5
DOI: 10.1103/PhysRevB.10.1979

A Theory of Metallic Ferro- and Antiferromagnetism on Zener's Model
journal, July 1956

Kasuya, Tadao
Progress of Theoretical Physics, Vol. 16, Issue 1
DOI: 10.1143/PTP.16.45

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M.
Journal of Applied Crystallography, Vol. 48, Issue 1
DOI: 10.1107/S1600576714022985

Magnetic order in ${BaMn}_{2} {As}_{2}$ from neutron diffraction measurements
journal, September 2009

Singh, Yogesh; Green, M. A.; Huang, Q.
Physical Review B, Vol. 80, Issue 10
DOI: 10.1103/PhysRevB.80.100403

Magnetic Susceptibility of Collinear and Noncollinear Heisenberg Antiferromagnets
journal, August 2012

Johnston, D. C.
Physical Review Letters, Vol. 109, Issue 7
DOI: 10.1103/PhysRevLett.109.077201

Antiferromagnetic structure and electronic properties of ${BaCr}_{2} {As}_{2}$ and ${BaCrFeAs}_{2}$
journal, May 2017

Filsinger, Kai A.; Schnelle, Walter; Adler, Peter
Physical Review B, Vol. 95, Issue 18
DOI: 10.1103/PhysRevB.95.184414

Simple Model for Characterizing the Electrical Resistivity in $A - 15$ Superconductors
journal, April 1977

Wiesmann, H.; Gurvitch, M.; Lutz, H.
Physical Review Letters, Vol. 38, Issue 14
DOI: 10.1103/PhysRevLett.38.782

Magnetic structures of the Eu and Cr moments in ${EuCr}_{2} {As}_{2}$ : Neutron diffraction study
journal, September 2016

Nandi, S.; Xiao, Y.; Qureshi, N.
Physical Review B, Vol. 94, Issue 9
DOI: 10.1103/PhysRevB.94.094411

From molecules to solids with the DMol3 approach
journal, November 2000

Delley, B.
The Journal of Chemical Physics, Vol. 113, Issue 18
DOI: 10.1063/1.1316015

Magnetic structure and spin excitations in ${BaMn}_{2} {Bi}_{2}$
journal, February 2014

Calder, S.; Saparov, B.; Cao, H. B.
Physical Review B, Vol. 89, Issue 6
DOI: 10.1103/PhysRevB.89.064417

Antiferromagnetic order in the ThCr2Si2 type phosphides CaCo2P2 and CeCo2P2
journal, February 1998

Reehuis, M.; Jeitschko, W.; Kotzyba, G.
Journal of Alloys and Compounds, Vol. 266, Issue 1-2
DOI: 10.1016/S0925-8388(97)00486-6

The phase diagram and superabundant vacancy formation in Co–H alloys
journal, January 2006

Fukai, Yuh; Yokota, Saori; Yanagawa, Jun’ichi
Journal of Alloys and Compounds, Vol. 407, Issue 1-2
DOI: 10.1016/j.jallcom.2005.06.016

First-order phase transitions in EuCo $_{2}$ P $_{2}$ and SrNi $_{2}$ P $_{2}$
journal, December 1997

Huhnt, C.; Schlabitz, W.; Wurth, A.
Physical Review B, Vol. 56, Issue 21
DOI: 10.1103/PhysRevB.56.13796

Structural, magnetic, thermal, and electronic transport properties of single-crystal ${EuPd}_{2} {Sb}_{2}$
journal, February 2010

Das, S.; McFadden, K.; Singh, Yogesh
Physical Review B, Vol. 81, Issue 5
DOI: 10.1103/PhysRevB.81.054425

Indirect Exchange Coupling of Nuclear Magnetic Moments by Conduction Electrons
journal, October 1954

Ruderman, M. A.; Kittel, C.
Physical Review, Vol. 96, Issue 1
DOI: 10.1103/PhysRev.96.99

Magnetic properties of single crystal EuCo ₂ As ₂
journal, April 2012

Ballinger, Jared; Wenger, Lowell E.; Vohra, Yogesh K.
Journal of Applied Physics, Vol. 111, Issue 7
DOI: 10.1063/1.3671410

Paramagnetic Susceptibilities of Metallic Samarium Compounds
journal, September 1972

Stewart, A. M.
Physical Review B, Vol. 6, Issue 5
DOI: 10.1103/PhysRevB.6.1985

Antiferromagnetism in ${EuCu}_{2} {As}_{2}$ and ${EuCu}_{1.82} {Sb}_{2}$ single crystals
journal, May 2015

Anand, V. K.; Johnston, D. C.
Physical Review B, Vol. 91, Issue 18
DOI: 10.1103/PhysRevB.91.184403

Coexistence of antiferromagnetic and ferromagnetic spin correlations in ${SrCo}_{2} {As}_{2}$ revealed by ${}^{59}{Co}$ and ${}^{75}{As}$ NMR
journal, June 2015

Wiecki, P.; Ogloblichev, V.; Pandey, Abhishek
Physical Review B, Vol. 91, Issue 22
DOI: 10.1103/PhysRevB.91.220406

A Neutron diffraction study of the magnetic structure of EuCo2P2
journal, May 1992

Reehuis, M.; Jeitschko, W.; Möller, M. H.
Journal of Physics and Chemistry of Solids, Vol. 53, Issue 5
DOI: 10.1016/0022-3697(92)90208-U

Superconductivity in iron compounds
journal, December 2011

Stewart, G. R.
Reviews of Modern Physics, Vol. 83, Issue 4
DOI: 10.1103/RevModPhys.83.1589

Pressure-induced collapsed-tetragonal phase in ${SrCo}_{2} {As}_{2}$
journal, December 2015

Jayasekara, W. T.; Kaluarachchi, U. S.; Ueland, B. G.
Physical Review B, Vol. 92, Issue 22
DOI: 10.1103/PhysRevB.92.224103

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

Sheldrick, George M.
Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
DOI: 10.1107/S2053273314026370

Influence of classical anisotropy fields on the properties of Heisenberg antiferromagnets within unified molecular field theory
journal, December 2017

Johnston, David C.
Physical Review B, Vol. 96, Issue 22
DOI: 10.1103/PhysRevB.96.224428

Influence of uniaxial single-ion anisotropy on the magnetic and thermal properties of Heisenberg antiferromagnets within unified molecular field theory
journal, March 2017

Johnston, David C.
Physical Review B, Vol. 95, Issue 9
DOI: 10.1103/PhysRevB.95.094421

Relation between the specific heat and susceptibility of an antiferromagnet
journal, October 1962

Fisher, Michael E.
Philosophical Magazine, Vol. 7, Issue 82
DOI: 10.1080/14786436208213705

Colloquium : The unexpected properties of alkali metal iron selenide superconductors
journal, May 2013

Dagotto, Elbio
Reviews of Modern Physics, Vol. 85, Issue 2
DOI: 10.1103/RevModPhys.85.849

A Transition from Localized to Strongly Correlated Electron Behavior and Mixed Valence Driven by Physical or Chemical Pressure in ACo ₂ As ₂ (A = Eu and Ca)
journal, February 2016

Tan, Xiaoyan; Fabbris, Gilberto; Haskel, Daniel
Journal of the American Chemical Society, Vol. 138, Issue 8
DOI: 10.1021/jacs.5b12659

Antiferromagnetic order and spin dynamics in iron-based superconductors
journal, August 2015

Dai, Pengcheng
Reviews of Modern Physics, Vol. 87, Issue 3
DOI: 10.1103/RevModPhys.87.855

Magnetic, transport, and thermal properties of single crystals of the layered arsenide ${BaMn}_{2} {As}_{2}$
journal, March 2009

Singh, Yogesh; Ellern, A.; Johnston, D. C.
Physical Review B, Vol. 79, Issue 9
DOI: 10.1103/PhysRevB.79.094519

Optical properties of the iron-pnictide analog BaMn $_{2}$ As $_{2}$
journal, July 2012

Antal, A.; Knoblauch, T.; Singh, Y.
Physical Review B, Vol. 86, Issue 1
DOI: 10.1103/PhysRevB.86.014506

Magnetization and Electrical Resistivity of Gadolinium Single Crystals
journal, November 1963

Nigh, H. E.; Legvold, S.; Spedding, F. H.
Physical Review, Vol. 132, Issue 3
DOI: 10.1103/PhysRev.132.1092

Strong Coupling of the Fe-Spin State and the As-As Hybridization in Iron-Pnictide Superconductors from First-Principle Calculations
journal, January 2009

Yildirim, T.
Physical Review Letters, Vol. 102, Issue 3
DOI: 10.1103/PhysRevLett.102.037003

Structural, thermal, magnetic, and electronic transport properties of the LaNi $_{2}$ (Ge $_{1 - x}$ P $_{x}$ ) $_{2}$ system
journal, February 2012

Goetsch, R. J.; Anand, V. K.; Pandey, Abhishek
Physical Review B, Vol. 85, Issue 5
DOI: 10.1103/PhysRevB.85.054517

Is ${BaCr}_{2} {As}_{2}$ symmetrical to ${BaFe}_{2} {As}_{2}$ with respect to half $3 d$ shell filling?
journal, May 2017

Richard, P.; van Roekeghem, A.; Lv, B. Q.
Physical Review B, Vol. 95, Issue 18
DOI: 10.1103/PhysRevB.95.184516

Ferromagnetic quantum critical point induced by dimer-breaking in SrCo2(Ge1−xPx)2
journal, January 2011

Jia, Shuang; Jiramongkolchai, Pawina; Suchomel, M. R.
Nature Physics, Vol. 7, Issue 3
DOI: 10.1038/nphys1868

Ternary lanthanoid-transition metal pnictides with ThCr2Si2-type structure
journal, April 1978

Marchand, Roger; Jeitschko, Wolfgang
Journal of Solid State Chemistry, Vol. 24, Issue 3-4
DOI: 10.1016/0022-4596(78)90026-9

Antiferromagnetism in semiconducting ${SrMn}_{2} {Sb}_{2}$ and ${BaMn}_{2} {Sb}_{2}$ single crystals
journal, January 2018

Sangeetha, N. S.; Smetana, V.; Mudring, A. -V.
Physical Review B, Vol. 97, Issue 1
DOI: 10.1103/PhysRevB.97.014402

Frustrated magnetic interactions, giant magneto–elastic coupling, and magnetic phonons in iron–pnictides
journal, May 2009

Yildirim, Taner
Physica C: Superconductivity, Vol. 469, Issue 9-12
DOI: 10.1016/j.physc.2009.03.038

Angle-resolved photoemission observation of Mn-pnictide hybridization and negligible band structure renormalization in ${BaMn}_{2} {As}_{2}$ and ${BaMn}_{2} {Sb}_{2}$
journal, October 2016

Zhang, W. -L.; Richard, P.; van Roekeghem, A.
Physical Review B, Vol. 94, Issue 15
DOI: 10.1103/PhysRevB.94.155155

Pressure-induced Transition of the Sublattice Magnetization in ${EuCo}_{2} P_{2}$ : Change from Local Moment $Eu (4 f)$ to Itinerant $Co (3 d)$ Magnetism
journal, January 1998

Chefki, M.; Abd-Elmeguid, M. M.; Micklitz, H.
Physical Review Letters, Vol. 80, Issue 4
DOI: 10.1103/PhysRevLett.80.802

Magnetic properties of ternary lanthanoid transition metal arsenides studied by Mössbauer and susceptibility measurements
journal, February 1993

Raffius, H.; Mörsen, E.; Mosel, B. D.
Journal of Physics and Chemistry of Solids, Vol. 54, Issue 2
DOI: 10.1016/0022-3697(93)90301-7

Crystal structure refinement with SHELXL
journal, January 2015

Sheldrick, George M.
Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
DOI: 10.1107/S2053229614024218

Unified molecular field theory for collinear and noncollinear Heisenberg antiferromagnets
journal, February 2015

Johnston, David C.
Physical Review B, Vol. 91, Issue 6
DOI: 10.1103/PhysRevB.91.064427

Iron-based superconductors: Current status of materials and pairing mechanism
journal, July 2015

Hosono, Hideo; Kuroki, Kazuhiko
Physica C: Superconductivity and its Applications, Vol. 514
DOI: 10.1016/j.physc.2015.02.020

Formation of collapsed tetragonal phase in EuCo ₂ As ₂ under high pressure
journal, October 2010

Bishop, Matthew; Uhoya, Walter; Tsoi, Georgiy
Journal of Physics: Condensed Matter, Vol. 22, Issue 42
DOI: 10.1088/0953-8984/22/42/425701

Crystal growth and physical properties of SrCu $_{2}$ As $_{2}$ , SrCu $_{2}$ Sb $_{2}$ , and BaCu $_{2}$ Sb $_{2}$
journal, June 2012

Anand, V. K.; Perera, P. Kanchana; Pandey, Abhishek
Physical Review B, Vol. 85, Issue 21
DOI: 10.1103/PhysRevB.85.214523

Crystal and magnetic structure of CaCo $_{1.86}$ As $_{2}$ studied by x-ray and neutron diffraction
journal, November 2013

Quirinale, D. G.; Anand, V. K.; Kim, M. G.
Physical Review B, Vol. 88, Issue 17
DOI: 10.1103/PhysRevB.88.174420

The magnetic structure of EuCu ₂ Sb ₂
journal, May 2015

Ryan, D. H.; Cadogan, J. M.; Anand, V. K.
Journal of Physics: Condensed Matter, Vol. 27, Issue 20
DOI: 10.1088/0953-8984/27/20/206002

What drives nematic order in iron-based superconductors?
journal, January 2014

Fernandes, R. M.; Chubukov, A. V.; Schmalian, J.
Nature Physics, Vol. 10, Issue 2
DOI: 10.1038/nphys2877

High-temperature superconductivity in iron pnictides and chalcogenides
journal, March 2016

Si, Qimiao; Yu, Rong; Abrahams, Elihu
Nature Reviews Materials, Vol. 1, Issue 4
DOI: 10.1038/natrevmats.2016.17

Magnetic Properties of Cu-Mn Alloys
journal, June 1957

Yosida, Kei
Physical Review, Vol. 106, Issue 5
DOI: 10.1103/PhysRev.106.893

Collinear antiferromagnetism in trigonal SrMn ₂ As ₂ revealed by single-crystal neutron diffraction
journal, November 2016

Das, Pinaki; Sangeetha, N. S.; Pandey, Abhishek
Journal of Physics: Condensed Matter, Vol. 29, Issue 3
DOI: 10.1088/0953-8984/29/3/035802

Magnetic structure of ${EuFe}_{2} {As}_{2}$ determined by single-crystal neutron diffraction
journal, November 2009

Xiao, Y.; Su, Y.; Meven, M.
Physical Review B, Vol. 80, Issue 17
DOI: 10.1103/PhysRevB.80.174424

Spin fluctuations in iron pnictides and chalcogenides: From antiferromagnetism to superconductivity
journal, January 2016

Inosov, Dmytro S.
Comptes Rendus Physique, Vol. 17, Issue 1-2
DOI: 10.1016/j.crhy.2015.03.001

Boltzmann Theory Generalized to Include Band Mixing: A Possible Theory for "Resistivity Saturation" in Metals
journal, March 1979

Chakraborty, B.; Allen, P. B.
Physical Review Letters, Vol. 42, Issue 11
DOI: 10.1103/PhysRevLett.42.736

Improved tetrahedron method for Brillouin-zone integrations
journal, June 1994

Blöchl, Peter E.; Jepsen, O.; Andersen, O. K.
Physical Review B, Vol. 49, Issue 23
DOI: 10.1103/PhysRevB.49.16223

Physical properties of metallic antiferromagnetic ${CaCo}_{1.86}$ ${As}_{2}$ single crystals
journal, June 2014

Anand, V. K.; Dhaka, R. S.; Lee, Y.
Physical Review B, Vol. 89, Issue 21
DOI: 10.1103/PhysRevB.89.214409

Observation of a remarkable reduction of correlation effects in BaCr ₂ As ₂ by ARPES
journal, November 2017

Nayak, Jayita; Filsinger, Kai; Fecher, Gerhard H.
Proceedings of the National Academy of Sciences, Vol. 114, Issue 47
DOI: 10.1073/pnas.1702234114

A common thread: The pairing interaction for unconventional superconductors
journal, October 2012

Scalapino, D. J.
Reviews of Modern Physics, Vol. 84, Issue 4
DOI: 10.1103/RevModPhys.84.1383

Magnetic exchange interactions in ${BaMn}_{2} {As}_{2}$ : A case study of the $J_{1}$ - $J_{2}$ - $J_{c}$ Heisenberg model
journal, September 2011

Johnston, D. C.; McQueeney, R. J.; Lake, B.
Physical Review B, Vol. 84, Issue 9
DOI: 10.1103/PhysRevB.84.094445

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides
journal, October 2010

Johnston, David C.
Advances in Physics, Vol. 59, Issue 6
DOI: 10.1080/00018732.2010.513480

Zur Struktur ternärer Übergangsmetallarsenide/On the Structure of Ternary Arsenides
journal, June 1980

Pfisterer, Martin; Nagorsen, Günter
Zeitschrift für Naturforschung B, Vol. 35, Issue 6
DOI: 10.1515/znb-1980-0611

Bindungsverhältnisse und magnetische Eigenschaften ternärer Arsenide ET2As2 / Bonding and Magnetic Properties in Ternary Arsenides ET2As2
journal, July 1983

Pfisterer, Martin; Nagorsen, Günter
Zeitschrift für Naturforschung B, Vol. 38, Issue 7
DOI: 10.1515/znb-1983-0704

Similar Records in DOE PAGES and OSTI.GOV collections:

Magnetic, thermal, and electronic-transport properties of EuMg₂Bi₂ single crystals

Journal Article Pakhira, Santanu ; Tanatar, M. A. ; Johnston, D. C. - Physical Review B

Tmore »« less
Cited by 19
https://doi.org/10.1103/PhysRevB.101.214407

Full Text Available
Crystal growth and magnetic structure of ${MnBi}_{2} {Te}_{4}$

Journal Article Yan, Jiaqiang ; Zhang, Qiang ; Heitmann, Thomas ; ... - Physical Review Materials

Millimore »« less
Cited by 194
https://doi.org/10.1103/PhysRevMaterials.3.064202

Full Text Available
Magnetic ground state and magnetic excitations in black dioptase ${Cu}_{6} {Si}_{6} O_{18}$

Journal Article Podlesnyak, Andrey A. ; Prokhnenko, Oleksandr ; Nikitin, Stanislav E. ; ... - Physical Review B

Tmore »« less
Cited by 3
https://doi.org/10.1103/PhysRevB.100.184401

Full Text Available
Non-Fermi-liquid types of behavior associated with a magnetic quantum critical point in $Sr {({Co}_{1 - x} {Ni}_{x})}_{2} {As}_{2}$ single crystals

Journal Article Sangeetha, N. S. ; Wang, L. -L. ; Smirnov, A. V. ; ... - Physical Review B

The compound SrCo₂As₂ with the body-centered tetragonal ThCr₂Si₂ structure is known to remain paramagnetic down to a temperature T = 0.05 K, but inelastic neutron scattering studies have shown that both ferromagnetic (FM) and antiferromagnetic (AFM) fluctuations occur in single crystals. Thus it is of interest to study how the magnetism evolves on doping SrCo₂As₂. Previous work on polycrystalline samples of Sr (Co_1-x Ni_x)₂ As₂ indicated the development of AFM order for 0 < x ≲ 0.3. Here we studied single crystals of Sr(Co_1-x Ni_x)₂ As₂ for 0 < x ≤ 1 and confirmed the occurrence of AFM order whichmore »« less
Cited by 17
https://doi.org/10.1103/PhysRevB.100.094447

Full Text Available
Suppression of the antiferromagnetic metallic state in the pressurized $MnB i_{2} T e_{4}$ single crystal

Journal Article Chen, K. Y. ; Yan, Jiaqiang ; Parker, David S. ; ... - Physical Review Materials

We smore »« less
Cited by 44
https://doi.org/10.1103/PhysRevMaterials.3.094201

Full Text Available

Similar Records

Title: Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet EuCo 2 - y As 2

Abstract

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Itinerant and local-moment magnetism in EuCr 2 As 2 single crystals journal, April 2014

Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo 2 As 2 journal, July 2013

EuCo 2 P 2 : A model molecular-field helical Heisenberg antiferromagnet journal, July 2016

Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators SrMn 2 As 2 and CaMn 2 As 2 journal, September 2016

Mössbauer and magnetic susceptibility investigations of strontium, lanthanum and europium transition metal phosphides with ThCr2Si2 type structure journal, January 1988

Magnetic dipole interactions in crystals journal, January 2016

Spin-polarized energy-band structure, conduction-electron polarization, spin densities, and the neutron magnetic form factor of ferromagnetic gadolinium journal, September 1974

A Theory of Metallic Ferro- and Antiferromagnetism on Zener's Model journal, July 1956

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination journal, January 2015

Magnetic order in BaMn 2 As 2 from neutron diffraction measurements journal, September 2009

Magnetic Susceptibility of Collinear and Noncollinear Heisenberg Antiferromagnets journal, August 2012

Antiferromagnetic structure and electronic properties of BaCr 2 As 2 and BaCrFeAs 2 journal, May 2017

Simple Model for Characterizing the Electrical Resistivity in A − 15 Superconductors journal, April 1977

Magnetic structures of the Eu and Cr moments in EuCr 2 As 2 : Neutron diffraction study journal, September 2016

From molecules to solids with the DMol3 approach journal, November 2000

Magnetic structure and spin excitations in BaMn 2 Bi 2 journal, February 2014

Antiferromagnetic order in the ThCr2Si2 type phosphides CaCo2P2 and CeCo2P2 journal, February 1998

The phase diagram and superabundant vacancy formation in Co–H alloys journal, January 2006

First-order phase transitions in EuCo 2 P 2 and SrNi 2 P 2 journal, December 1997

Structural, magnetic, thermal, and electronic transport properties of single-crystal EuPd 2 Sb 2 journal, February 2010

Indirect Exchange Coupling of Nuclear Magnetic Moments by Conduction Electrons journal, October 1954

Magnetic properties of single crystal EuCo 2 As 2 journal, April 2012

Paramagnetic Susceptibilities of Metallic Samarium Compounds journal, September 1972

Antiferromagnetism in EuCu 2 As 2 and EuCu 1.82 Sb 2 single crystals journal, May 2015

Coexistence of antiferromagnetic and ferromagnetic spin correlations in SrCo 2 As 2 revealed by Co 59 and As 75 NMR journal, June 2015

A Neutron diffraction study of the magnetic structure of EuCo2P2 journal, May 1992

Superconductivity in iron compounds journal, December 2011

Pressure-induced collapsed-tetragonal phase in SrCo 2 As 2 journal, December 2015

SHELXT – Integrated space-group and crystal-structure determination journal, January 2015

Influence of classical anisotropy fields on the properties of Heisenberg antiferromagnets within unified molecular field theory journal, December 2017

Influence of uniaxial single-ion anisotropy on the magnetic and thermal properties of Heisenberg antiferromagnets within unified molecular field theory journal, March 2017

Relation between the specific heat and susceptibility of an antiferromagnet journal, October 1962

Colloquium : The unexpected properties of alkali metal iron selenide superconductors journal, May 2013

A Transition from Localized to Strongly Correlated Electron Behavior and Mixed Valence Driven by Physical or Chemical Pressure in ACo 2 As 2 (A = Eu and Ca) journal, February 2016

Antiferromagnetic order and spin dynamics in iron-based superconductors journal, August 2015

Magnetic, transport, and thermal properties of single crystals of the layered arsenide BaMn 2 As 2 journal, March 2009

Optical properties of the iron-pnictide analog BaMn 2 As 2 journal, July 2012

Magnetization and Electrical Resistivity of Gadolinium Single Crystals journal, November 1963

Strong Coupling of the Fe-Spin State and the As-As Hybridization in Iron-Pnictide Superconductors from First-Principle Calculations journal, January 2009

Structural, thermal, magnetic, and electronic transport properties of the LaNi 2 (Ge 1 − x P x ) 2 system journal, February 2012

Is BaCr 2 As 2 symmetrical to BaFe 2 As 2 with respect to half 3 d shell filling? journal, May 2017

Ferromagnetic quantum critical point induced by dimer-breaking in SrCo2(Ge1−xPx)2 journal, January 2011

Ternary lanthanoid-transition metal pnictides with ThCr2Si2-type structure journal, April 1978

Antiferromagnetism in semiconducting SrMn 2 Sb 2 and BaMn 2 Sb 2 single crystals journal, January 2018

Frustrated magnetic interactions, giant magneto–elastic coupling, and magnetic phonons in iron–pnictides journal, May 2009

Angle-resolved photoemission observation of Mn-pnictide hybridization and negligible band structure renormalization in BaMn 2 As 2 and BaMn 2 Sb 2 journal, October 2016

Pressure-induced Transition of the Sublattice Magnetization in EuCo 2 P 2 : Change from Local Moment Eu ( 4 f ) to Itinerant Co ( 3 d ) Magnetism journal, January 1998

Magnetic properties of ternary lanthanoid transition metal arsenides studied by Mössbauer and susceptibility measurements journal, February 1993

Crystal structure refinement with SHELXL journal, January 2015

Unified molecular field theory for collinear and noncollinear Heisenberg antiferromagnets journal, February 2015

Iron-based superconductors: Current status of materials and pairing mechanism journal, July 2015

Formation of collapsed tetragonal phase in EuCo 2 As 2 under high pressure journal, October 2010

Crystal growth and physical properties of SrCu 2 As 2 , SrCu 2 Sb 2 , and BaCu 2 Sb 2 journal, June 2012

Crystal and magnetic structure of CaCo 1.86 As 2 studied by x-ray and neutron diffraction journal, November 2013

The magnetic structure of EuCu 2 Sb 2 journal, May 2015

What drives nematic order in iron-based superconductors? journal, January 2014

High-temperature superconductivity in iron pnictides and chalcogenides journal, March 2016

Magnetic Properties of Cu-Mn Alloys journal, June 1957

Collinear antiferromagnetism in trigonal SrMn 2 As 2 revealed by single-crystal neutron diffraction journal, November 2016

Magnetic structure of EuFe 2 As 2 determined by single-crystal neutron diffraction journal, November 2009

Spin fluctuations in iron pnictides and chalcogenides: From antiferromagnetism to superconductivity journal, January 2016

Boltzmann Theory Generalized to Include Band Mixing: A Possible Theory for "Resistivity Saturation" in Metals journal, March 1979

Improved tetrahedron method for Brillouin-zone integrations journal, June 1994

Physical properties of metallic antiferromagnetic CaCo 1.86 As 2 single crystals journal, June 2014

Observation of a remarkable reduction of correlation effects in BaCr 2 As 2 by ARPES journal, November 2017

A common thread: The pairing interaction for unconventional superconductors journal, October 2012

Magnetic exchange interactions in BaMn 2 As 2 : A case study of the J 1 - J 2 - J c Heisenberg model journal, September 2011

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides journal, October 2010

Zur Struktur ternärer Übergangsmetallarsenide/On the Structure of Ternary Arsenides journal, June 1980

Bindungsverhältnisse und magnetische Eigenschaften ternärer Arsenide ET2As2 / Bonding and Magnetic Properties in Ternary Arsenides ET2As2 journal, July 1983

Title: Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet ${EuCo}_{2 - y} {As}_{2}$

Generalized Gradient Approximation Made Simple
journal, October 1996

Itinerant and local-moment magnetism in ${EuCr}_{2}$ ${As}_{2}$ single crystals
journal, April 2014

Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo $_{2}$ As $_{2}$
journal, July 2013

${EuCo}_{2} P_{2}$ : A model molecular-field helical Heisenberg antiferromagnet
journal, July 2016

Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators ${SrMn}_{2} {As}_{2}$ and ${CaMn}_{2} {As}_{2}$
journal, September 2016

Mössbauer and magnetic susceptibility investigations of strontium, lanthanum and europium transition metal phosphides with ThCr2Si2 type structure
journal, January 1988

Magnetic dipole interactions in crystals
journal, January 2016

Spin-polarized energy-band structure, conduction-electron polarization, spin densities, and the neutron magnetic form factor of ferromagnetic gadolinium
journal, September 1974

A Theory of Metallic Ferro- and Antiferromagnetism on Zener's Model
journal, July 1956

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

Magnetic order in ${BaMn}_{2} {As}_{2}$ from neutron diffraction measurements
journal, September 2009

Magnetic Susceptibility of Collinear and Noncollinear Heisenberg Antiferromagnets
journal, August 2012

Antiferromagnetic structure and electronic properties of ${BaCr}_{2} {As}_{2}$ and ${BaCrFeAs}_{2}$
journal, May 2017

Simple Model for Characterizing the Electrical Resistivity in $A - 15$ Superconductors
journal, April 1977

Magnetic structures of the Eu and Cr moments in ${EuCr}_{2} {As}_{2}$ : Neutron diffraction study
journal, September 2016

From molecules to solids with the DMol3 approach
journal, November 2000

Magnetic structure and spin excitations in ${BaMn}_{2} {Bi}_{2}$
journal, February 2014

Antiferromagnetic order in the ThCr2Si2 type phosphides CaCo2P2 and CeCo2P2
journal, February 1998

The phase diagram and superabundant vacancy formation in Co–H alloys
journal, January 2006

First-order phase transitions in EuCo $_{2}$ P $_{2}$ and SrNi $_{2}$ P $_{2}$
journal, December 1997

Structural, magnetic, thermal, and electronic transport properties of single-crystal ${EuPd}_{2} {Sb}_{2}$
journal, February 2010

Indirect Exchange Coupling of Nuclear Magnetic Moments by Conduction Electrons
journal, October 1954

Magnetic properties of single crystal EuCo ₂ As ₂
journal, April 2012

Paramagnetic Susceptibilities of Metallic Samarium Compounds
journal, September 1972

Antiferromagnetism in ${EuCu}_{2} {As}_{2}$ and ${EuCu}_{1.82} {Sb}_{2}$ single crystals
journal, May 2015

Coexistence of antiferromagnetic and ferromagnetic spin correlations in ${SrCo}_{2} {As}_{2}$ revealed by ${}^{59}{Co}$ and ${}^{75}{As}$ NMR
journal, June 2015

A Neutron diffraction study of the magnetic structure of EuCo2P2
journal, May 1992

Superconductivity in iron compounds
journal, December 2011

Pressure-induced collapsed-tetragonal phase in ${SrCo}_{2} {As}_{2}$
journal, December 2015

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

Influence of classical anisotropy fields on the properties of Heisenberg antiferromagnets within unified molecular field theory
journal, December 2017

Influence of uniaxial single-ion anisotropy on the magnetic and thermal properties of Heisenberg antiferromagnets within unified molecular field theory
journal, March 2017

Relation between the specific heat and susceptibility of an antiferromagnet
journal, October 1962

Colloquium : The unexpected properties of alkali metal iron selenide superconductors
journal, May 2013

A Transition from Localized to Strongly Correlated Electron Behavior and Mixed Valence Driven by Physical or Chemical Pressure in ACo ₂ As ₂ (A = Eu and Ca)
journal, February 2016

Antiferromagnetic order and spin dynamics in iron-based superconductors
journal, August 2015

Magnetic, transport, and thermal properties of single crystals of the layered arsenide ${BaMn}_{2} {As}_{2}$
journal, March 2009

Optical properties of the iron-pnictide analog BaMn $_{2}$ As $_{2}$
journal, July 2012

Magnetization and Electrical Resistivity of Gadolinium Single Crystals
journal, November 1963

Strong Coupling of the Fe-Spin State and the As-As Hybridization in Iron-Pnictide Superconductors from First-Principle Calculations
journal, January 2009

Structural, thermal, magnetic, and electronic transport properties of the LaNi $_{2}$ (Ge $_{1 - x}$ P $_{x}$ ) $_{2}$ system
journal, February 2012

Is ${BaCr}_{2} {As}_{2}$ symmetrical to ${BaFe}_{2} {As}_{2}$ with respect to half $3 d$ shell filling?
journal, May 2017

Ferromagnetic quantum critical point induced by dimer-breaking in SrCo2(Ge1−xPx)2
journal, January 2011

Ternary lanthanoid-transition metal pnictides with ThCr2Si2-type structure
journal, April 1978

Antiferromagnetism in semiconducting ${SrMn}_{2} {Sb}_{2}$ and ${BaMn}_{2} {Sb}_{2}$ single crystals
journal, January 2018

Frustrated magnetic interactions, giant magneto–elastic coupling, and magnetic phonons in iron–pnictides
journal, May 2009

Angle-resolved photoemission observation of Mn-pnictide hybridization and negligible band structure renormalization in ${BaMn}_{2} {As}_{2}$ and ${BaMn}_{2} {Sb}_{2}$
journal, October 2016

Pressure-induced Transition of the Sublattice Magnetization in ${EuCo}_{2} P_{2}$ : Change from Local Moment $Eu (4 f)$ to Itinerant $Co (3 d)$ Magnetism
journal, January 1998

Magnetic properties of ternary lanthanoid transition metal arsenides studied by Mössbauer and susceptibility measurements
journal, February 1993

Crystal structure refinement with SHELXL
journal, January 2015

Unified molecular field theory for collinear and noncollinear Heisenberg antiferromagnets
journal, February 2015

Iron-based superconductors: Current status of materials and pairing mechanism
journal, July 2015

Formation of collapsed tetragonal phase in EuCo ₂ As ₂ under high pressure
journal, October 2010

Crystal growth and physical properties of SrCu $_{2}$ As $_{2}$ , SrCu $_{2}$ Sb $_{2}$ , and BaCu $_{2}$ Sb $_{2}$
journal, June 2012

Crystal and magnetic structure of CaCo $_{1.86}$ As $_{2}$ studied by x-ray and neutron diffraction
journal, November 2013

The magnetic structure of EuCu ₂ Sb ₂
journal, May 2015

What drives nematic order in iron-based superconductors?
journal, January 2014

High-temperature superconductivity in iron pnictides and chalcogenides
journal, March 2016

Magnetic Properties of Cu-Mn Alloys
journal, June 1957

Collinear antiferromagnetism in trigonal SrMn ₂ As ₂ revealed by single-crystal neutron diffraction
journal, November 2016

Magnetic structure of ${EuFe}_{2} {As}_{2}$ determined by single-crystal neutron diffraction
journal, November 2009

Spin fluctuations in iron pnictides and chalcogenides: From antiferromagnetism to superconductivity
journal, January 2016

Boltzmann Theory Generalized to Include Band Mixing: A Possible Theory for "Resistivity Saturation" in Metals
journal, March 1979

Improved tetrahedron method for Brillouin-zone integrations
journal, June 1994

Physical properties of metallic antiferromagnetic ${CaCo}_{1.86}$ ${As}_{2}$ single crystals
journal, June 2014

Observation of a remarkable reduction of correlation effects in BaCr ₂ As ₂ by ARPES
journal, November 2017

A common thread: The pairing interaction for unconventional superconductors
journal, October 2012

Magnetic exchange interactions in ${BaMn}_{2} {As}_{2}$ : A case study of the $J_{1}$ - $J_{2}$ - $J_{c}$ Heisenberg model
journal, September 2011

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides
journal, October 2010

Zur Struktur ternärer Übergangsmetallarsenide/On the Structure of Ternary Arsenides
journal, June 1980

Bindungsverhältnisse und magnetische Eigenschaften ternärer Arsenide ET2As2 / Bonding and Magnetic Properties in Ternary Arsenides ET2As2
journal, July 1983