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Title: Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate

The bis(tetraphenylarsonium) hexachloridozirconate(IV) salt, (AsPh 4 ) 2 [ZrCl 6 ] (Ph = C 6 H 5 ), was prepared more than 25 years ago [Esmadi & Sutcliffe (1991). Indian J. Chem. 30 A , 99–101], but its crystal structure was never reported. By following a similar experimental procedure, the compound was synthesized and its crystal structure was investigated as a acetonitrile tetrasolvate, (As(C 6 H 5 ) 4 ) 2 [ZrCl 6 ]·4CH 3 CN, by single-crystal X –ray diffraction. The [ZrCl 6 ] 2− anion adopts a slightly distorted octahedral coordination sphere, with Zr—Cl bond lengths of 2.4586 (6), 2.4723 (6), and 2.4818 (5) Å, and Cl—Zr—Cl angles ranging from 89.602 (19) to 90.397 (19)°.
Authors:
; ORCiD logo ;
Publication Date:
Grant/Contract Number:
NE0008449
Type:
Published Article
Journal Name:
IUCrData
Additional Journal Information:
Journal Name: IUCrData Journal Volume: 3 Journal Issue: 4; Journal ID: ISSN 2414-3146
Publisher:
International Union of Crystallography (IUCr)
Sponsoring Org:
USDOE
Country of Publication:
Country unknown/Code not available
Language:
English
OSTI Identifier:
1432087

Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, and Poineau, Frederic. Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate. Country unknown/Code not available: N. p., Web. doi:10.1107/S241431461800528X.
Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, & Poineau, Frederic. Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate. Country unknown/Code not available. doi:10.1107/S241431461800528X.
Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, and Poineau, Frederic. 2018. "Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate". Country unknown/Code not available. doi:10.1107/S241431461800528X.
@article{osti_1432087,
title = {Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate},
author = {Borjas, Rosendo and Mariappan Balasekaran, Samundeeswari and Poineau, Frederic},
abstractNote = {The bis(tetraphenylarsonium) hexachloridozirconate(IV) salt, (AsPh 4 ) 2 [ZrCl 6 ] (Ph = C 6 H 5 ), was prepared more than 25 years ago [Esmadi & Sutcliffe (1991). Indian J. Chem. 30 A , 99–101], but its crystal structure was never reported. By following a similar experimental procedure, the compound was synthesized and its crystal structure was investigated as a acetonitrile tetrasolvate, (As(C 6 H 5 ) 4 ) 2 [ZrCl 6 ]·4CH 3 CN, by single-crystal X –ray diffraction. The [ZrCl 6 ] 2− anion adopts a slightly distorted octahedral coordination sphere, with Zr—Cl bond lengths of 2.4586 (6), 2.4723 (6), and 2.4818 (5) Å, and Cl—Zr—Cl angles ranging from 89.602 (19) to 90.397 (19)°.},
doi = {10.1107/S241431461800528X},
journal = {IUCrData},
number = 4,
volume = 3,
place = {Country unknown/Code not available},
year = {2018},
month = {4}
}