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Title: Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate

Abstract

The bis(tetraphenylarsonium) hexachloridozirconate(IV) salt, (AsPh 4 ) 2 [ZrCl 6 ] (Ph = C 6 H 5 ), was prepared more than 25 years ago [Esmadi & Sutcliffe (1991). Indian J. Chem. 30 A , 99–101], but its crystal structure was never reported. By following a similar experimental procedure, the compound was synthesized and its crystal structure was investigated as a acetonitrile tetrasolvate, (As(C 6 H 5 ) 4 ) 2 [ZrCl 6 ]·4CH 3 CN, by single-crystal X –ray diffraction. The [ZrCl 6 ] 2− anion adopts a slightly distorted octahedral coordination sphere, with Zr—Cl bond lengths of 2.4586 (6), 2.4723 (6), and 2.4818 (5) Å, and Cl—Zr—Cl angles ranging from 89.602 (19) to 90.397 (19)°.

Authors:
; ORCiD logo;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1432087
Grant/Contract Number:  
NE0008449
Resource Type:
Published Article
Journal Name:
IUCrData
Additional Journal Information:
Journal Name: IUCrData Journal Volume: 3 Journal Issue: 4; Journal ID: ISSN 2414-3146
Publisher:
International Union of Crystallography (IUCr)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, and Poineau, Frederic. Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate. United Kingdom: N. p., 2018. Web. doi:10.1107/S241431461800528X.
Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, & Poineau, Frederic. Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate. United Kingdom. doi:10.1107/S241431461800528X.
Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, and Poineau, Frederic. Fri . "Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate". United Kingdom. doi:10.1107/S241431461800528X.
@article{osti_1432087,
title = {Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate},
author = {Borjas, Rosendo and Mariappan Balasekaran, Samundeeswari and Poineau, Frederic},
abstractNote = {The bis(tetraphenylarsonium) hexachloridozirconate(IV) salt, (AsPh 4 ) 2 [ZrCl 6 ] (Ph = C 6 H 5 ), was prepared more than 25 years ago [Esmadi & Sutcliffe (1991). Indian J. Chem. 30 A , 99–101], but its crystal structure was never reported. By following a similar experimental procedure, the compound was synthesized and its crystal structure was investigated as a acetonitrile tetrasolvate, (As(C 6 H 5 ) 4 ) 2 [ZrCl 6 ]·4CH 3 CN, by single-crystal X –ray diffraction. The [ZrCl 6 ] 2− anion adopts a slightly distorted octahedral coordination sphere, with Zr—Cl bond lengths of 2.4586 (6), 2.4723 (6), and 2.4818 (5) Å, and Cl—Zr—Cl angles ranging from 89.602 (19) to 90.397 (19)°.},
doi = {10.1107/S241431461800528X},
journal = {IUCrData},
number = 4,
volume = 3,
place = {United Kingdom},
year = {2018},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1107/S241431461800528X

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Works referenced in this record:

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053273314026370

publCIF : software for editing, validating and formatting crystallographic information files
journal, June 2010


Crystal structure refinement with SHELXL
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053229614024218

Process Development Studies for Zirconium Recovery/Recycle from used Nuclear Fuel Cladding
journal, January 2012