Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate

Borjas, Rosendo; Mariappan Balasekaran, Samundeeswari; Poineau, Frederic

doi:10.1107/S241431461800528X

Title: Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate

Abstract

The bis(tetraphenylarsonium) hexachloridozirconate(IV) salt, (AsPh ₄ ) ₂ [ZrCl ₆ ] (Ph = C ₆ H ₅ ), was prepared more than 25 years ago [Esmadi & Sutcliffe (1991). Indian J. Chem. 30 A , 99–101], but its crystal structure was never reported. By following a similar experimental procedure, the compound was synthesized and its crystal structure was investigated as a acetonitrile tetrasolvate, (As(C ₆ H ₅ ) ₄ ) ₂ [ZrCl ₆ ]·4CH ₃ CN, by single-crystal X –ray diffraction. The [ZrCl ₆ ] ²⁻ anion adopts a slightly distorted octahedral coordination sphere, with Zr—Cl bond lengths of 2.4586 (6), 2.4723 (6), and 2.4818 (5) Å, and Cl—Zr—Cl angles ranging from 89.602 (19) to 90.397 (19)°.

Authors:

Borjas, Rosendo;

; Poineau, Frederic

Publication Date:: Fri Apr 06 00:00:00 EDT 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1432087

Grant/Contract Number:: NE0008449

Resource Type:: Published Article

Journal Name:: IUCrData

Additional Journal Information:: Journal Name: IUCrData Journal Volume: 3 Journal Issue: 4; Journal ID: ISSN 2414-3146

Publisher:: International Union of Crystallography (IUCr)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, and Poineau, Frederic. Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate.  United Kingdom: N. p., 2018. 
Web.  doi:10.1107/S241431461800528X.

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                    Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, & Poineau, Frederic. Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate.  United Kingdom.  https://doi.org/10.1107/S241431461800528X

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                    Borjas, Rosendo, Mariappan Balasekaran, Samundeeswari, and Poineau, Frederic. Fri .  
"Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate".  United Kingdom.  https://doi.org/10.1107/S241431461800528X.

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@article{osti_1432087,

  title        = {Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate},

  author       = {Borjas, Rosendo and Mariappan Balasekaran, Samundeeswari and Poineau, Frederic},

  abstractNote = {The bis(tetraphenylarsonium) hexachloridozirconate(IV) salt, (AsPh 4 ) 2 [ZrCl 6 ] (Ph = C 6 H 5 ), was prepared more than 25 years ago [Esmadi & Sutcliffe (1991). Indian J. Chem. 30 A , 99–101], but its crystal structure was never reported. By following a similar experimental procedure, the compound was synthesized and its crystal structure was investigated as a acetonitrile tetrasolvate, (As(C 6 H 5 ) 4 ) 2 [ZrCl 6 ]·4CH 3 CN, by single-crystal X –ray diffraction. The [ZrCl 6 ] 2− anion adopts a slightly distorted octahedral coordination sphere, with Zr—Cl bond lengths of 2.4586 (6), 2.4723 (6), and 2.4818 (5) Å, and Cl—Zr—Cl angles ranging from 89.602 (19) to 90.397 (19)°.},

  doi          = {10.1107/S241431461800528X},

  journal      = {IUCrData},

  number       = 4,

  volume       = 3,

  place        = {United Kingdom},

  year         = {Fri Apr 06 00:00:00 EDT 2018},

  month        = {Fri Apr 06 00:00:00 EDT 2018}

}

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Works referenced in this record:

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journal, March 2013

Jeon, Min Ku; Lee, Chang Hwa; Lee, You Lee
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Title: Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate

Abstract

Citation Formats

Zirconium recovery from zircaloy shavings journal, July 1996

Preparation and Properties of Ammonium Hexachlorozirconate(IV) and Its Reaction with Gaseous Ammonia journal, July 1987

Bis(tetraphenylarsonium) hexabromorhenate(IV) journal, January 2007

SHELXT – Integrated space-group and crystal-structure determination journal, January 2015

publCIF : software for editing, validating and formatting crystallographic information files journal, June 2010

Structure studies of technetium complexes. VII. Structure of tetraphenylarsonium hexachlorotechnetate(IV), [As(C6H5)4]2[TcCl6] journal, August 1984

The Synthesis and Properties of the Anhydrous Hexachlorozirconates of Sodium and Potassium journal, May 1964

Crystal structure refinement with SHELXL journal, January 2015

Process Development Studies for Zirconium Recovery/Recycle from used Nuclear Fuel Cladding journal, January 2012

Demonstration of Zr Recovery from 50 g Scale Zircaloy-4 Cladding Hulls using a Chlorination Method [50 g 규모의 Zircaloy-4 피복관으로부터 염소화 방법을 이용한 Zr 회수 거동 연구] journal, March 2013

Zirconium recovery from zircaloy shavings
journal, July 1996

Preparation and Properties of Ammonium Hexachlorozirconate(IV) and Its Reaction with Gaseous Ammonia
journal, July 1987

Bis(tetraphenylarsonium) hexabromorhenate(IV)
journal, January 2007

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

publCIF : software for editing, validating and formatting crystallographic information files
journal, June 2010

Structure studies of technetium complexes. VII. Structure of tetraphenylarsonium hexachlorotechnetate(IV), [As(C6H5)4]2[TcCl6]
journal, August 1984

The Synthesis and Properties of the Anhydrous Hexachlorozirconates of Sodium and Potassium
journal, May 1964

Crystal structure refinement with SHELXL
journal, January 2015

Process Development Studies for Zirconium Recovery/Recycle from used Nuclear Fuel Cladding
journal, January 2012

Demonstration of Zr Recovery from 50 g Scale Zircaloy-4 Cladding Hulls using a Chlorination Method [50 g 규모의 Zircaloy-4 피복관으로부터 염소화 방법을 이용한 Zr 회수 거동 연구]
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