Pyrolytic Carbon Nanosheets for Ultrafast and Ultrastable Sodium‐Ion Storage
Abstract
Abstract Na‐ion cointercalation in the graphite host structure in a glyme‐based electrolyte represents a new possibility for using carbon‐based materials (CMs) as anodes for Na‐ion storage. However, local microstructures and nanoscale morphological features in CMs affect their electrochemical performances; they require intensive studies to achieve high levels of Na‐ion storage performances. Here, pyrolytic carbon nanosheets (PCNs) composed of multitudinous graphitic nanocrystals are prepared from renewable bioresources by heating. In particular, PCN‐2800 prepared by heating at 2800 °C has a distinctive sp 2 carbon bonding nature, crystalline domain size of ≈44.2 Å, and high electrical conductivity of ≈320 S cm −1 , presenting significantly high rate capability at 600 C (60 A g −1 ) and stable cycling behaviors over 40 000 cycles as an anode for Na‐ion storage. The results of this study show the unusual graphitization behaviors of a char‐type carbon precursor and exceptionally high rate and cycling performances of the resulting graphitic material, PCN‐2800, even surpassing those of supercapacitors.
- Authors:
-
- Department of Polymer Science and Engineering Inha University Incheon 402‐751 South Korea
- Department of Materials Science and Engineering University of Illinois at Urbana − Champaign Urbana IL 61801 USA
- Institute of Advanced Composite Materials Korea Institute of Science and Technology (KIST) 92 Chudong‐ro, Bongdong‐eup Wanju‐gun Jeonbuk 55324 South Korea
- Division of Electron Microscopic Research Korea Basic Science Institute Daejeon 34133 South Korea
- Carbon Composite Materials Research Center Korea Institute of Science and Technology 92 Chudong‐ro, Bongdong‐eup Wanju‐gun Jeonbuk 55324 South Korea
- Department of Chemical Engineering Kangwon National University Samcheok 245‐711 South Korea
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1431138
- Grant/Contract Number:
- DE‐AC02‐06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Small
- Additional Journal Information:
- Journal Name: Small Journal Volume: 14 Journal Issue: 17; Journal ID: ISSN 1613-6810
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Cho, Se Youn, Kang, Minjee, Choi, Jaewon, Lee, Min Eui, Yoon, Hyeon Ji, Kim, Hae Jin, Leal, Cecilia, Lee, Sungho, Jin, Hyoung‐Joon, and Yun, Young Soo. Pyrolytic Carbon Nanosheets for Ultrafast and Ultrastable Sodium‐Ion Storage. Germany: N. p., 2018.
Web. doi:10.1002/smll.201703043.
Cho, Se Youn, Kang, Minjee, Choi, Jaewon, Lee, Min Eui, Yoon, Hyeon Ji, Kim, Hae Jin, Leal, Cecilia, Lee, Sungho, Jin, Hyoung‐Joon, & Yun, Young Soo. Pyrolytic Carbon Nanosheets for Ultrafast and Ultrastable Sodium‐Ion Storage. Germany. https://doi.org/10.1002/smll.201703043
Cho, Se Youn, Kang, Minjee, Choi, Jaewon, Lee, Min Eui, Yoon, Hyeon Ji, Kim, Hae Jin, Leal, Cecilia, Lee, Sungho, Jin, Hyoung‐Joon, and Yun, Young Soo. Tue .
"Pyrolytic Carbon Nanosheets for Ultrafast and Ultrastable Sodium‐Ion Storage". Germany. https://doi.org/10.1002/smll.201703043.
@article{osti_1431138,
title = {Pyrolytic Carbon Nanosheets for Ultrafast and Ultrastable Sodium‐Ion Storage},
author = {Cho, Se Youn and Kang, Minjee and Choi, Jaewon and Lee, Min Eui and Yoon, Hyeon Ji and Kim, Hae Jin and Leal, Cecilia and Lee, Sungho and Jin, Hyoung‐Joon and Yun, Young Soo},
abstractNote = {Abstract Na‐ion cointercalation in the graphite host structure in a glyme‐based electrolyte represents a new possibility for using carbon‐based materials (CMs) as anodes for Na‐ion storage. However, local microstructures and nanoscale morphological features in CMs affect their electrochemical performances; they require intensive studies to achieve high levels of Na‐ion storage performances. Here, pyrolytic carbon nanosheets (PCNs) composed of multitudinous graphitic nanocrystals are prepared from renewable bioresources by heating. In particular, PCN‐2800 prepared by heating at 2800 °C has a distinctive sp 2 carbon bonding nature, crystalline domain size of ≈44.2 Å, and high electrical conductivity of ≈320 S cm −1 , presenting significantly high rate capability at 600 C (60 A g −1 ) and stable cycling behaviors over 40 000 cycles as an anode for Na‐ion storage. The results of this study show the unusual graphitization behaviors of a char‐type carbon precursor and exceptionally high rate and cycling performances of the resulting graphitic material, PCN‐2800, even surpassing those of supercapacitors.},
doi = {10.1002/smll.201703043},
journal = {Small},
number = 17,
volume = 14,
place = {Germany},
year = {Tue Apr 03 00:00:00 EDT 2018},
month = {Tue Apr 03 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/smll.201703043
https://doi.org/10.1002/smll.201703043
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 21 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Metal-Air Batteries with High Energy Density: Li-Air versus Zn-Air
journal, December 2010
- Lee, Jang-Soo; Tai Kim, Sun; Cao, Ruiguo
- Advanced Energy Materials, Vol. 1, Issue 1, p. 34-50
Rechargeable Ca-Ion Batteries: A New Energy Storage System
journal, December 2015
- Lipson, Albert L.; Pan, Baofei; Lapidus, Saul H.
- Chemistry of Materials, Vol. 27, Issue 24
Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011
- Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
- Advanced Functional Materials, Vol. 21, Issue 20
Conversion Reaction of Copper Sulfide Based Nanohybrids for Sodium-Ion Batteries
journal, October 2017
- Kim, Na Rae; Choi, Jaewon; Yoon, Hyeon Ji
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 11
Sodium-ion supercapacitors based on nanoporous pyroproteins containing redox-active heteroatoms
journal, October 2016
- Cho, Se Youn; Yoon, Hyeon Ji; Kim, Na Rae
- Journal of Power Sources, Vol. 329
An aqueous, polymer-based redox-flow battery using non-corrosive, safe and low-cost materials
journal, October 2015
- Janoschka, Tobias; Martin, Norbert; Martin, Udo
- Nature, Vol. 527, Issue 7576, p. 78-81
Sodium intercalation chemistry in graphite
journal, January 2015
- Kim, Haegyeom; Hong, Jihyun; Yoon, Gabin
- Energy & Environmental Science, Vol. 8, Issue 10
Use of Graphite as a Highly Reversible Electrode with Superior Cycle Life for Sodium-Ion Batteries by Making Use of Co-Intercalation Phenomena
journal, July 2014
- Jache, Birte; Adelhelm, Philipp
- Angewandte Chemie International Edition, Vol. 53, Issue 38
Lithium-free transition metal monoxides for positive electrodes in lithium-ion batteries
journal, January 2017
- Jung, Sung-Kyun; Kim, Hyunchul; Cho, Min Gee
- Nature Energy, Vol. 2, Issue 2
An ultrafast rechargeable aluminium-ion battery
journal, April 2015
- Lin, Meng-Chang; Gong, Ming; Lu, Bingan
- Nature, Vol. 520, Issue 7547
Sodium-Ion Storage in Pyroprotein-Based Carbon Nanoplates
journal, September 2015
- Yun, Young Soo; Park, Kyu-Young; Lee, Byoungju
- Advanced Materials, Vol. 27, Issue 43
High-resolution electron microscopy of a microporous carbon
journal, June 2000
- Harris, P. J. F.; Burian, A.; Duber, S.
- Philosophical Magazine Letters, Vol. 80, Issue 6
Improved Electrochemical Performance of Na-Ion Batteries in Ether-Based Electrolytes: A Case Study of ZnS Nanospheres
journal, November 2015
- Su, Dawei; Kretschmer, Katja; Wang, Guoxiu
- Advanced Energy Materials, Vol. 6, Issue 2
Restoration of thermally reduced graphene oxide by atomic-level selenium doping
journal, December 2016
- Yun, Young Soo; Yoon, Gabin; Park, Min
- NPG Asia Materials, Vol. 8, Issue 12
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012
- Palomares, Verónica; Serras, Paula; Villaluenga, Irune
- Energy & Environmental Science, Vol. 5, Issue 3
Sodium titanate nanotube/graphite, an electric energy storage device using Na+-based organic electrolytes
journal, November 2013
- Zhao, Liping; Qi, Li; Wang, Hongyu
- Journal of Power Sources, Vol. 242
Tin Phosphide as a Promising Anode Material for Na-Ion Batteries
journal, April 2014
- Kim, Youngjin; Kim, Yongil; Choi, Aram
- Advanced Materials, Vol. 26, Issue 24
Ultrasmall Sn Nanoparticles Embedded in Carbon as High-Performance Anode for Sodium-Ion Batteries
journal, October 2014
- Liu, Yongchang; Zhang, Ning; Jiao, Lifang
- Advanced Functional Materials, Vol. 25, Issue 2
Carbonization of a stable β-sheet-rich silk protein into a pseudographitic pyroprotein
journal, May 2015
- Cho, Se Youn; Yun, Young Soo; Lee, Sungho
- Nature Communications, Vol. 6, Issue 1
Highly stable and ultrafast electrode reaction of graphite for sodium ion batteries
journal, October 2015
- Zhu, Zhiqiang; Cheng, Fangyi; Hu, Zhe
- Journal of Power Sources, Vol. 293
Tin Sulfide-Based Nanohybrid for High-Performance Anode of Sodium-Ion Batteries
journal, June 2017
- Choi, Jaewon; Kim, Na Rae; Lim, Kyungmi
- Small, Vol. 13, Issue 30
Carbonization and graphitization
journal, January 1984
- Oberlin, A.
- Carbon, Vol. 22, Issue 6, p. 521-541
A New High-Energy Cathode for a Na-Ion Battery with Ultrahigh Stability
journal, September 2013
- Park, Young-Uk; Seo, Dong-Hwa; Kwon, Hyung-Soon
- Journal of the American Chemical Society, Vol. 135, Issue 37
A highly reversible, low-strain Mg-ion insertion anode material for rechargeable Mg-ion batteries
journal, August 2014
- Wu, Na; Lyu, Ying-Chun; Xiao, Rui-Juan
- NPG Asia Materials, Vol. 6, Issue 8
TEMPO-Based Catholyte for High-Energy Density Nonaqueous Redox Flow Batteries
journal, October 2014
- Wei, Xiaoliang; Xu, Wu; Vijayakumar, Murugesan
- Advanced Materials, Vol. 26, Issue 45
Microstructural changes in porous hematite nanoparticles upon calcination
journal, May 2011
- Johnsen, Rune E.; Knudsen, Kenneth D.; Molenbroek, Alfons M.
- Journal of Applied Crystallography, Vol. 44, Issue 3
Defective Graphene as a High-Capacity Anode Material for Na- and Ca-Ion Batteries
journal, January 2014
- Datta, Dibakar; Li, Junwen; Shenoy, Vivek B.
- ACS Applied Materials & Interfaces, Vol. 6, Issue 3
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
Microporous Carbon Nanoplates from Regenerated Silk Proteins for Supercapacitors
journal, February 2013
- Yun, Young Soo; Cho, Se Youn; Shim, Jinyong
- Advanced Materials, Vol. 25, Issue 14
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Single-Crystalline Bilayered V 2 O 5 Nanobelts for High-Capacity Sodium-Ion Batteries
journal, November 2013
- Su, Dawei; Wang, Guoxiu
- ACS Nano, Vol. 7, Issue 12
Small-Angle Scattering from Polymeric Mass Fractals of Arbitrary Mass-Fractal Dimension
journal, April 1996
- Beaucage, G.
- Journal of Applied Crystallography, Vol. 29, Issue 2
Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects
journal, November 2013
- Yin, Ya-Xia; Xin, Sen; Guo, Yu-Guo
- Angewandte Chemie International Edition, Vol. 52, Issue 50
Long-Lasting Nb 2 O 5 -Based Nanocomposite Materials for Li-Ion Storage
journal, January 2017
- Song, Min Yeong; Kim, Na Rae; Yoon, Hyeon Ji
- ACS Applied Materials & Interfaces, Vol. 9, Issue 3
Ultra-Thin Hollow Carbon Nanospheres for Pseudocapacitive Sodium-Ion Storage
journal, December 2014
- Yun, Young Soo; Cho, Se Youn; Kim, Haegyeom
- ChemElectroChem, Vol. 2, Issue 3
Bismuth: A new anode for the Na-ion battery
journal, March 2015
- Su, Dawei; Dou, Shixue; Wang, Guoxiu
- Nano Energy, Vol. 12
Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering
journal, December 1995
- Beaucage, G.
- Journal of Applied Crystallography, Vol. 28, Issue 6
Ultrafast Solvent-Assisted Sodium Ion Intercalation into Highly Crystalline Few-Layered Graphene
journal, December 2015
- Cohn, Adam P.; Share, Keith; Carter, Rachel
- Nano Letters, Vol. 16, Issue 1
Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011
- Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
- Energy & Environmental Science, Vol. 4, Issue 9
Conditions for Reversible Na Intercalation in Graphite: Theoretical Studies on the Interplay Among Guest Ions, Solvent, and Graphite Host
journal, September 2016
- Yoon, Gabin; Kim, Haegyeom; Park, Inchul
- Advanced Energy Materials, Vol. 7, Issue 2
Hierarchically Porous Carbon Nanosheets from Waste Coffee Grounds for Supercapacitors
journal, February 2015
- Yun, Young Soo; Park, Min Hong; Hong, Sung Ju
- ACS Applied Materials & Interfaces, Vol. 7, Issue 6
High-Performance Sodium-Ion Pseudocapacitors Based on Hierarchically Porous Nanowire Composites
journal, April 2012
- Chen, Zheng; Augustyn, Veronica; Jia, Xilai
- ACS Nano, Vol. 6, Issue 5
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Recent Progress in Electrode Materials for Sodium-Ion Batteries
journal, July 2016
- Kim, Hyungsub; Kim, Haegyeom; Ding, Zhang
- Advanced Energy Materials, Vol. 6, Issue 19
Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014
- Larcher, D.; Tarascon, J-M.
- Nature Chemistry, Vol. 7, Issue 1
Sodium-Ion Batteries
journal, May 2012
- Slater, Michael D.; Kim, Donghan; Lee, Eungje
- Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
Ultrathin MoS 2 Nanosheets as Anode Materials for Sodium-Ion Batteries with Superior Performance
journal, December 2014
- Su, Dawei; Dou, Shixue; Wang, Guoxiu
- Advanced Energy Materials, Vol. 5, Issue 6
Durable potassium ion battery electrodes from high-rate cointercalation into graphitic carbons
journal, January 2016
- Cohn, Adam P.; Muralidharan, Nitin; Carter, Rachel
- Journal of Materials Chemistry A, Vol. 4, Issue 39
Amphicharge-Storable Pyropolymers Containing Multitiered Nanopores
journal, June 2017
- Kim, Na Rae; Lee, Sang Moon; Kim, Min Wook
- Advanced Energy Materials, Vol. 7, Issue 19
Asymmetric Energy Storage Devices Based on Surface-Driven Sodium-Ion Storage
journal, December 2016
- Song, Min Yeong; Kim, Na Rae; Cho, Se Youn
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Microporous carbon nanosheets with redox-active heteroatoms for pseudocapacitive charge storage
journal, January 2015
- Yun, Y. S.; Kim, D. -H.; Hong, S. J.
- Nanoscale, Vol. 7, Issue 37
The Mechanisms of Lithium and Sodium Insertion in Carbon Materials
journal, January 2001
- Stevens, D. A.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 148, Issue 8