Biphase Cobalt-Manganese Oxide with High Capacity and Rate Performance for Aqueous Sodium-Ion Electrochemical Energy Storage
Abstract
Manganese-based metal oxide electrode materials are of great importance in electrochemical energy storage for their favorable redox behavior, low cost and environmental-friendliness. However, their storage capacity and cycle life in aqueous Na-ion electrolytes is not satisfactory. In this paper, we report the development of a bi-phase cobalt-manganese oxide (Co-Mn-O) nanostructured electrode material, comprised of a layered MnO2.H2O birnessite phase and a (Co0.83Mn0.13Va0.04)tetra(Co0.38Mn1.62)octaO3.72 (Va: vacancy; tetra: tetrahedral sites; octa: octahedral sites) spinel phase, verified by neutron total scattering and pair distribution function analyses. The bi-phase Co-Mn-O material demonstrates an excellent storage capacity towards Na-ions in an aqueous electrolyte (121 mA h g-1 at a scan rate of 1 mV s-1 in the half-cell and 81 mA h g-1 at a current density of 2 A g-1 after 5000 cycles in full-cells), as well as high rate performance (57 mA h g-1 a rate of 360 C). Electro-kinetic analysis and in situ X-ray diffraction measurements further confirm that the synergistic interaction between the spinel and layered phases, as well as the vacancy of the tetrahedral sites of spinel phase, contribute to the improved capacity and rate performance of the Co-Mn-O material by facilitating both diffusion-limited redox and capacitive charge storage processes.
- Authors:
-
[1]
- Univ. of New Hampshire, Durham, NH (United States). Dept. of Chemical Engineering
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS). X-ray Science Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division and Spallation Neutron Source (SNS) outstation Juelich Centre for Neutron Science (JCNS), Forschungszentrum Juelich GmbH
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Xiaowei Teng/University of New Hampshire
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Univ. of New Hampshire, Durham, NH (United States); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1430860
- Alternate Identifier(s):
- OSTI ID: 1410130; OSTI ID: 1430704; OSTI ID: 1594488
- Report Number(s):
- BNL-203384-2018-JAAM
Journal ID: ISSN 1616-301X
- Grant/Contract Number:
- SC0012704; AC05‐00OR22725; SC0010286; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 28; Journal Issue: 3; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; bi-phase cobalt-manganese oxide; aqueous Na-ion storage; capacitive and diffusion-limited redox capacities; in situ X-ray diffraction; pair distribution function
Citation Formats
Shan, Xiaoqiang, Charles, Daniel S., Xu, Wenqian, Feygenson, Mikhail, Su, Dong, and Teng, Xiaowei. Biphase Cobalt-Manganese Oxide with High Capacity and Rate Performance for Aqueous Sodium-Ion Electrochemical Energy Storage. United States: N. p., 2017.
Web. doi:10.1002/adfm.201703266.
Shan, Xiaoqiang, Charles, Daniel S., Xu, Wenqian, Feygenson, Mikhail, Su, Dong, & Teng, Xiaowei. Biphase Cobalt-Manganese Oxide with High Capacity and Rate Performance for Aqueous Sodium-Ion Electrochemical Energy Storage. United States. https://doi.org/10.1002/adfm.201703266
Shan, Xiaoqiang, Charles, Daniel S., Xu, Wenqian, Feygenson, Mikhail, Su, Dong, and Teng, Xiaowei. Wed .
"Biphase Cobalt-Manganese Oxide with High Capacity and Rate Performance for Aqueous Sodium-Ion Electrochemical Energy Storage". United States. https://doi.org/10.1002/adfm.201703266. https://www.osti.gov/servlets/purl/1430860.
@article{osti_1430860,
title = {Biphase Cobalt-Manganese Oxide with High Capacity and Rate Performance for Aqueous Sodium-Ion Electrochemical Energy Storage},
author = {Shan, Xiaoqiang and Charles, Daniel S. and Xu, Wenqian and Feygenson, Mikhail and Su, Dong and Teng, Xiaowei},
abstractNote = {Manganese-based metal oxide electrode materials are of great importance in electrochemical energy storage for their favorable redox behavior, low cost and environmental-friendliness. However, their storage capacity and cycle life in aqueous Na-ion electrolytes is not satisfactory. In this paper, we report the development of a bi-phase cobalt-manganese oxide (Co-Mn-O) nanostructured electrode material, comprised of a layered MnO2.H2O birnessite phase and a (Co0.83Mn0.13Va0.04)tetra(Co0.38Mn1.62)octaO3.72 (Va: vacancy; tetra: tetrahedral sites; octa: octahedral sites) spinel phase, verified by neutron total scattering and pair distribution function analyses. The bi-phase Co-Mn-O material demonstrates an excellent storage capacity towards Na-ions in an aqueous electrolyte (121 mA h g-1 at a scan rate of 1 mV s-1 in the half-cell and 81 mA h g-1 at a current density of 2 A g-1 after 5000 cycles in full-cells), as well as high rate performance (57 mA h g-1 a rate of 360 C). Electro-kinetic analysis and in situ X-ray diffraction measurements further confirm that the synergistic interaction between the spinel and layered phases, as well as the vacancy of the tetrahedral sites of spinel phase, contribute to the improved capacity and rate performance of the Co-Mn-O material by facilitating both diffusion-limited redox and capacitive charge storage processes.},
doi = {10.1002/adfm.201703266},
journal = {Advanced Functional Materials},
number = 3,
volume = 28,
place = {United States},
year = {2017},
month = {11}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 21 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Crystallographic and magnetic properties of several spinels containing trivalent ja-1044 manganese
journal, December 1958
- Wickham, D. G.; Croft, W. J.
- Journal of Physics and Chemistry of Solids, Vol. 7, Issue 4
Enhanced Supercapacitor Performance for Equal Co–Mn Stoichiometry in Colloidal Co 3-x Mn x O 4 Nanoparticles, in Additive-Free Electrodes
journal, November 2015
- Perera, Sanjaya D.; Ding, Xiaoyue; Bhargava, Anuj
- Chemistry of Materials, Vol. 27, Issue 23
Hybrid energy storage: the merging of battery and supercapacitor chemistries
journal, January 2015
- Dubal, D. P.; Ayyad, O.; Ruiz, V.
- Chemical Society Reviews, Vol. 44, Issue 7
Performance Enhancement and Mechanistic Studies of Room-Temperature Sodium–Sulfur Batteries with a Carbon-Coated Functional Nafion Separator and a Na 2 S/Activated Carbon Nanofiber Cathode
journal, January 2016
- Yu, Xingwen; Manthiram, Arumugam
- Chemistry of Materials, Vol. 28, Issue 3
High-Energy MnO 2 Nanowire/Graphene and Graphene Asymmetric Electrochemical Capacitors
journal, September 2010
- Wu, Zhong-Shuai; Ren, Wencai; Wang, Da-Wei
- ACS Nano, Vol. 4, Issue 10
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Metal Oxide Hollow Nanostructures for Lithium-ion Batteries
journal, March 2012
- Wang, Zhiyu; Zhou, Liang; David Lou, Xiong Wen
- Advanced Materials, Vol. 24, Issue 14, p. 1903-1911
Pseudocapacitive Charge Storage in Thick Composite MoS 2 Nanocrystal-Based Electrodes
journal, October 2016
- Cook, John B.; Kim, Hyung-Seok; Lin, Terri C.
- Advanced Energy Materials, Vol. 7, Issue 2
Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014
- Augustyn, Veronica; Simon, Patrice; Dunn, Bruce
- Energy & Environmental Science, Vol. 7, Issue 5
On the formation of solid solution in Co3−xMnxO4 system
journal, April 1972
- Naka, Shigeharu; Inagaki, Michio; Tanaka, Tatsuo
- Journal of Materials Science, Vol. 7, Issue 4
The Present and Projected Performance and Cost of Double-layer and Pseudo-capacitive Ultracapacitors for Hybrid Vehicle Applications
conference, January 2005
- Burke, A.
- 2005 IEEE Vehicle Power and Propulsion Conference
Impedance, power, energy, and pulse performance characteristics of small commercial Li-ion cells
journal, October 1999
- Nagasubramanian, G.; Jungst, R. G.; Doughty, D. H.
- Journal of Power Sources, Vol. 83, Issue 1-2
GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013
- Toby, Brian H.; Von Dreele, Robert B.
- Journal of Applied Crystallography, Vol. 46, Issue 2
Nanotechnology for environmentally sustainable electromobility
journal, December 2016
- Ellingsen, Linda Ager-Wick; Hung, Christine Roxanne; Majeau-Bettez, Guillaume
- Nature Nanotechnology, Vol. 11, Issue 12
Towards High Power High Energy Aqueous Sodium-Ion Batteries: The NaTi 2 (PO 4 ) 3 /Na 0.44 MnO 2 System
journal, October 2012
- Li, Zheng; Young, David; Xiang, Kai
- Advanced Energy Materials, Vol. 3, Issue 3
Storage of Potassium Ions in Layered Vanadium Pentoxide Nanofiber Electrodes for Aqueous Pseudocapacitors
journal, October 2013
- Yeager, Matthew P.; Du, Wenxin; Bishop, Brendan
- ChemSusChem, Vol. 6, Issue 12
Behavior of Molybdenum Nitrides as Materials for Electrochemical Capacitors
journal, January 1998
- Liu, T. -C.
- Journal of The Electrochemical Society, Vol. 145, Issue 6
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide
journal, September 2013
- Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E.
- Science, Vol. 341, Issue 6153
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries
journal, January 2014
- Lee, J.; Urban, A.; Li, X.
- Science, Vol. 343, Issue 6170
Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts
journal, December 2010
- Cheng, Fangyi; Shen, Jian; Peng, Bo
- Nature Chemistry, Vol. 3, Issue 1
Battery materials for ultrafast charging and discharging
journal, March 2009
- Kang, Byoungwoo; Ceder, Gerbrand
- Nature, Vol. 458, Issue 7235, p. 190-193
Nanostructured Bilayered Vanadium Oxide Electrodes for Rechargeable Sodium-Ion Batteries
journal, December 2011
- Tepavcevic, Sanja; Xiong, Hui; Stamenkovic, Vojislav R.
- ACS Nano, Vol. 6, Issue 1
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance
journal, April 2013
- Augustyn, Veronica; Come, Jérémy; Lowe, Michael A.
- Nature Materials, Vol. 12, Issue 6
CoMn2O4 Spinel Hierarchical Microspheres Assembled with Porous Nanosheets as Stable Anodes for Lithium-ion Batteries
journal, December 2012
- Hu, Lin; Zhong, Hao; Zheng, Xinrui
- Scientific Reports, Vol. 2, Issue 1
Mesoporous Li x Mn 2 O 4 Thin Film Cathodes for Lithium-Ion Pseudocapacitors
journal, July 2016
- Lesel, Benjamin K.; Ko, Jesse S.; Dunn, Bruce
- ACS Nano, Vol. 10, Issue 8
Phase and composition controllable synthesis of cobalt manganese spinel nanoparticles towards efficient oxygen electrocatalysis
journal, June 2015
- Li, Chun; Han, Xiaopeng; Cheng, Fangyi
- Nature Communications, Vol. 6, Issue 1
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
The Effect of Crystallinity on the Rapid Pseudocapacitive Response of Nb2O5
journal, December 2011
- Kim, Jong Woung; Augustyn, Veronica; Dunn, Bruce
- Advanced Energy Materials, Vol. 2, Issue 1
Lithium Storage Mechanisms and Effect of Partial Cobalt Substitution in Manganese Carbonate Electrodes
journal, May 2012
- Mirhashemihaghighi, Shadi; León, Bernardo; Pérez Vicente, Carlos
- Inorganic Chemistry, Vol. 51, Issue 10
Controlled synthesis of hierarchical Co x Mn 3−x O 4 array micro-/nanostructures with tunable morphology and composition as integrated electrodes for lithium-ion batteries
journal, January 2013
- Yu, Le; Zhang, Lei; Wu, Hao Bin
- Energy Environ. Sci., Vol. 6, Issue 9
A Spinel-Integrated P2-Type Layered Composite: High-Rate Cathode for Sodium-Ion Batteries
journal, January 2016
- Zheng, Jianming; Yan, Pengfei; Kan, Wang Hay
- Journal of The Electrochemical Society, Vol. 163, Issue 3
Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage
journal, November 2016
- Shan, Xiaoqiang; Charles, Daniel S.; Lei, Yinkai
- Nature Communications, Vol. 7, Issue 1
Multidimensional materials and device architectures for future hybrid energy storage
journal, September 2016
- Lukatskaya, Maria R.; Dunn, Bruce; Gogotsi, Yury
- Nature Communications, Vol. 7, Issue 1
Facile synthesis of hierarchical Co3O4@MnO2 core–shell arrays on Ni foam for asymmetric supercapacitors
journal, April 2014
- Huang, Ming; Zhang, Yuxin; Li, Fei
- Journal of Power Sources, Vol. 252
High Performance Pseudocapacitor Based on 2D Layered Metal Chalcogenide Nanocrystals
journal, February 2015
- Muller, Guillaume A.; Cook, John B.; Kim, Hyung-Seok
- Nano Letters, Vol. 15, Issue 3
A 3D Oxalate-Based Network as a Precursor for the CoMn 2 O 4 Spinel: Synthesis and Structural and Magnetic Studies
journal, August 2014
- Habjanič, Jelena; Jurić, Marijana; Popović, Jasminka
- Inorganic Chemistry, Vol. 53, Issue 18
Effects of Ni Doping on the Initial Electrochemical Performance of Vanadium Oxide Nanotubes for Na-Ion Batteries
journal, June 2014
- Kim, Hyunjin; Kim, Ryoung-Hee; Lee, Seok-Soo
- ACS Applied Materials & Interfaces, Vol. 6, Issue 14
Subzero-Temperature Cathode for a Sodium-Ion Battery
journal, June 2016
- You, Ya; Yao, Hu-Rong; Xin, Sen
- Advanced Materials, Vol. 28, Issue 33
Works referencing / citing this record:
Hydrated Layered Vanadium Oxide as a Highly Reversible Cathode for Rechargeable Aqueous Zinc Batteries
journal, January 2019
- Zhang, Ning; Jia, Ming; Dong, Yang
- Advanced Functional Materials, Vol. 29, Issue 10
Ultrafast Aqueous Potassium‐Ion Batteries Cathode for Stable Intermittent Grid‐Scale Energy Storage
journal, June 2018
- Ren, Wenhao; Chen, Xianjue; Zhao, Chuan
- Advanced Energy Materials, Vol. 8, Issue 24
Wider Voltage Window, High Capacity and Ultra‐Long Life of an Na 0.91 MnO 2 Cathode for an Aqueous High‐Performance Supercapacitor
journal, September 2019
- Qin, Tianfeng
- Batteries & Supercaps, Vol. 2, Issue 11
Lab‐Scale In Situ X‐Ray Diffraction Technique for Different Battery Systems: Designs, Applications, and Perspectives
journal, May 2019
- Xia, Maoting; Liu, Tingting; Peng, Na
- Small Methods, Vol. 3, Issue 7
Dual-phase nanostructuring of layered metal oxides for high-performance aqueous rechargeable potassium ion microbatteries
journal, September 2019
- Li, Ying-Qi; Shi, Hang; Wang, Sheng-Bo
- Nature Communications, Vol. 10, Issue 1
A review on mechanistic understanding of MnO 2 in aqueous electrolyte for electrical energy storage systems
journal, August 2019
- Shin, Jaewook; Seo, Joon Kyo; Yaylian, Riley
- International Materials Reviews