Picolinamide-Based Iridium Catalysts for Dehydrogenation of Formic Acid in Water: Effect of Amide N Substituent on Activity and Stability
Abstract
Abstract To develop highly efficient catalysts for dehydrogenation of formic acid in water, we investigated several Cp*Ir catalysts with various amide ligands. The catalyst with an N ‐phenylpicolinamide ligand exhibited a TOF of 118 000 h −1 at 60 °C. A constant rate (TOF>35 000 h −1 ) was maintained for six hours, and a TON of 1 000 000 was achieved at 50 °C.
- Authors:
-
[1];
[1];
[1];
[2];
[2];
[1]
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Research Inst. of Energy Frontier. Dept. of Energy and Environment
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Japan Science and Technology Agency (JST)
- OSTI Identifier:
- 1430848
- Alternate Identifier(s):
- OSTI ID: 1429932
- Report Number(s):
- BNL-203368-2018-JAAM
Journal ID: ISSN 0947-6539
- Grant/Contract Number:
- SC0012704; JPMJCR1342
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry - A European Journal
- Additional Journal Information:
- Journal Volume: 24; Journal Issue: 69; Journal ID: ISSN 0947-6539
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 08 HYDROGEN; dehydrogenation; formic acid; hydrogen storage
Citation Formats
Kanega, Ryoichi, Onishi, Naoya, Wang, Lin, Murata, Kazuhisa, Muckerman, James T., Fujita, Etsuko, and Himeda, Yuichiro. Picolinamide-Based Iridium Catalysts for Dehydrogenation of Formic Acid in Water: Effect of Amide N Substituent on Activity and Stability. United States: N. p., 2018.
Web. doi:10.1002/chem.201800428.
Kanega, Ryoichi, Onishi, Naoya, Wang, Lin, Murata, Kazuhisa, Muckerman, James T., Fujita, Etsuko, & Himeda, Yuichiro. Picolinamide-Based Iridium Catalysts for Dehydrogenation of Formic Acid in Water: Effect of Amide N Substituent on Activity and Stability. United States. https://doi.org/10.1002/chem.201800428
Kanega, Ryoichi, Onishi, Naoya, Wang, Lin, Murata, Kazuhisa, Muckerman, James T., Fujita, Etsuko, and Himeda, Yuichiro. Thu .
"Picolinamide-Based Iridium Catalysts for Dehydrogenation of Formic Acid in Water: Effect of Amide N Substituent on Activity and Stability". United States. https://doi.org/10.1002/chem.201800428. https://www.osti.gov/servlets/purl/1430848.
@article{osti_1430848,
title = {Picolinamide-Based Iridium Catalysts for Dehydrogenation of Formic Acid in Water: Effect of Amide N Substituent on Activity and Stability},
author = {Kanega, Ryoichi and Onishi, Naoya and Wang, Lin and Murata, Kazuhisa and Muckerman, James T. and Fujita, Etsuko and Himeda, Yuichiro},
abstractNote = {Abstract To develop highly efficient catalysts for dehydrogenation of formic acid in water, we investigated several Cp*Ir catalysts with various amide ligands. The catalyst with an N ‐phenylpicolinamide ligand exhibited a TOF of 118 000 h −1 at 60 °C. A constant rate (TOF>35 000 h −1 ) was maintained for six hours, and a TON of 1 000 000 was achieved at 50 °C.},
doi = {10.1002/chem.201800428},
journal = {Chemistry - A European Journal},
number = 69,
volume = 24,
place = {United States},
year = {Thu Mar 01 00:00:00 EST 2018},
month = {Thu Mar 01 00:00:00 EST 2018}
}
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Works referencing / citing this record:
Ligand Effect on the Stability of Water‐Soluble Iridium Catalysts for High‐Pressure Hydrogen Gas Production by Dehydrogenation of Formic Acid
journal, March 2019
- Iguchi, Masayuki; Onishi, Naoya; Himeda, Yuichiro
- ChemPhysChem, Vol. 20, Issue 10
Iridium–NHC-based catalyst for ambient pressure storage and low temperature release of H 2 via the CO 2 /HCO 2 H couple
journal, January 2018
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Ligand Effect on the Stability of Water‐Soluble Iridium Catalysts for High‐Pressure Hydrogen Gas Production by Dehydrogenation of Formic Acid
journal, March 2019
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