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Title: A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode

A low-cost sodium-ion full cell with a O3-type layered Na[Cu 0.2(Fe 1/3Mn2/3) 0.8]O 2 cathode and an alloy-type P-TiP2-C anode is presented. The cathode is synthesized by an oxalate coprecipitation method and optimized cathodes shows a high specific capacity of 135 mAh g -1 at 0.1C rate with a high rate capability of 90 mAh g-1 at 1C rate and 70 mAh g -1 at 2C rate with good cyclability. The full cell exhibits better capacity retention than the half cell with the cathode due to the elimination of the degradation caused by sodium-metal anode. The dramatically enhanced electrochemical performance of the Na[Cu 0.2(Fe 1/3Mn 2/3) 0.8]O 2 / P-TiP 2-C full cell compared to that of the sample with no Cu is attributed to the structural stabilization imparted by Cu by suppressing the phase change from the O3 structure to the P3 structure during cycling.
Authors:
 [1] ;  [1] ;  [1] ;  [1]
  1. Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program & Texas Materials Inst.
Publication Date:
Grant/Contract Number:
SC0005397
Type:
Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 164; Journal Issue: 2; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Research Org:
Univ. of Texas, Austin, TX (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Materials Sciences & Engineering Division
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE; Sodium-ion batteries; alloy anodes; full cell; layered cathodes
OSTI Identifier:
1430255

Oh, Seung-Min, Oh, Pilgun, Kim, Sang-Ok, and Manthiram, Arumugam. A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode. United States: N. p., Web. doi:10.1149/2.0931702jes.
Oh, Seung-Min, Oh, Pilgun, Kim, Sang-Ok, & Manthiram, Arumugam. A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode. United States. doi:10.1149/2.0931702jes.
Oh, Seung-Min, Oh, Pilgun, Kim, Sang-Ok, and Manthiram, Arumugam. 2016. "A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode". United States. doi:10.1149/2.0931702jes. https://www.osti.gov/servlets/purl/1430255.
@article{osti_1430255,
title = {A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode},
author = {Oh, Seung-Min and Oh, Pilgun and Kim, Sang-Ok and Manthiram, Arumugam},
abstractNote = {A low-cost sodium-ion full cell with a O3-type layered Na[Cu0.2(Fe1/3Mn2/3)0.8]O2 cathode and an alloy-type P-TiP2-C anode is presented. The cathode is synthesized by an oxalate coprecipitation method and optimized cathodes shows a high specific capacity of 135 mAh g-1 at 0.1C rate with a high rate capability of 90 mAh g-1 at 1C rate and 70 mAh g-1 at 2C rate with good cyclability. The full cell exhibits better capacity retention than the half cell with the cathode due to the elimination of the degradation caused by sodium-metal anode. The dramatically enhanced electrochemical performance of the Na[Cu0.2(Fe1/3Mn2/3)0.8]O2 / P-TiP2-C full cell compared to that of the sample with no Cu is attributed to the structural stabilization imparted by Cu by suppressing the phase change from the O3 structure to the P3 structure during cycling.},
doi = {10.1149/2.0931702jes},
journal = {Journal of the Electrochemical Society},
number = 2,
volume = 164,
place = {United States},
year = {2016},
month = {12}
}