Red Phosphorus-Embedded Cross-Link-Structural Carbon Films as Flexible Anodes for Highly Reversible Li-Ion Storage
Abstract
Red phosphorus (P) is considered to be one of the most attractive anodic materials for lithium-ion batteries (LIBs) due to its high theoretical capacity of 2596 mAh g–1. However, intrinsic characteristics such as the poor electronic conductivity and large volume expansion at lithiation impede the development of red P. Here, we design a new strategy to embed red P particles into a cross-link-structural carbon film (P–C film), in order to improve the electronic conductivity and accommodate the volume expansion. The red P/carbon film is synthesized via vapor phase polymerization (VPP) followed by the pyrolysis process, working as a flexible binder-free anode for LIBs. High cycle stability and good rate capability are achieved by the P–C film anode. With 21% P content in the film, it displays a capacity of 903 mAh g–1 after 640 cycles at a current density of 100 mA g–1 and a capacity of 460 mAh g–1 after 1000 cycles at 2.0 A g–1. Additionally, the Coulombic efficiency reaches almost 100% for each cycle. As a result, the superior properties of the P–C films together with their facile fabrication make this material attractive for further flexible and high energy density LIB applications.
- Authors:
-
[2];
[1]
- Univ. of Shanghai for Science and Technology, Shanghai (China)
- Tianjin Univ., Tianjin (China)
- Shanghai Jiao Tong Univ., Shanghai (China)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- National Science Foundation of China; USDOE
- OSTI Identifier:
- 1430222
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 41; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; anode; binder-free; flexible; Li-ion battery; red phosphorus
Citation Formats
Ruan, Jiafeng, Yuan, Tao, Pang, Yuepeng, Xu, Xinbo, Yang, Junhe, Hu, Wenbin, Zhong, Cheng, Ma, Zi -Feng, Bi, Xuanxuan, and Zheng, Shiyou. Red Phosphorus-Embedded Cross-Link-Structural Carbon Films as Flexible Anodes for Highly Reversible Li-Ion Storage. United States: N. p., 2017.
Web. doi:10.1021/acsami.7b12556.
Ruan, Jiafeng, Yuan, Tao, Pang, Yuepeng, Xu, Xinbo, Yang, Junhe, Hu, Wenbin, Zhong, Cheng, Ma, Zi -Feng, Bi, Xuanxuan, & Zheng, Shiyou. Red Phosphorus-Embedded Cross-Link-Structural Carbon Films as Flexible Anodes for Highly Reversible Li-Ion Storage. United States. https://doi.org/10.1021/acsami.7b12556
Ruan, Jiafeng, Yuan, Tao, Pang, Yuepeng, Xu, Xinbo, Yang, Junhe, Hu, Wenbin, Zhong, Cheng, Ma, Zi -Feng, Bi, Xuanxuan, and Zheng, Shiyou. Fri .
"Red Phosphorus-Embedded Cross-Link-Structural Carbon Films as Flexible Anodes for Highly Reversible Li-Ion Storage". United States. https://doi.org/10.1021/acsami.7b12556. https://www.osti.gov/servlets/purl/1430222.
@article{osti_1430222,
title = {Red Phosphorus-Embedded Cross-Link-Structural Carbon Films as Flexible Anodes for Highly Reversible Li-Ion Storage},
author = {Ruan, Jiafeng and Yuan, Tao and Pang, Yuepeng and Xu, Xinbo and Yang, Junhe and Hu, Wenbin and Zhong, Cheng and Ma, Zi -Feng and Bi, Xuanxuan and Zheng, Shiyou},
abstractNote = {Red phosphorus (P) is considered to be one of the most attractive anodic materials for lithium-ion batteries (LIBs) due to its high theoretical capacity of 2596 mAh g–1. However, intrinsic characteristics such as the poor electronic conductivity and large volume expansion at lithiation impede the development of red P. Here, we design a new strategy to embed red P particles into a cross-link-structural carbon film (P–C film), in order to improve the electronic conductivity and accommodate the volume expansion. The red P/carbon film is synthesized via vapor phase polymerization (VPP) followed by the pyrolysis process, working as a flexible binder-free anode for LIBs. High cycle stability and good rate capability are achieved by the P–C film anode. With 21% P content in the film, it displays a capacity of 903 mAh g–1 after 640 cycles at a current density of 100 mA g–1 and a capacity of 460 mAh g–1 after 1000 cycles at 2.0 A g–1. Additionally, the Coulombic efficiency reaches almost 100% for each cycle. As a result, the superior properties of the P–C films together with their facile fabrication make this material attractive for further flexible and high energy density LIB applications.},
doi = {10.1021/acsami.7b12556},
journal = {ACS Applied Materials and Interfaces},
number = 41,
volume = 9,
place = {United States},
year = {Fri Sep 29 00:00:00 EDT 2017},
month = {Fri Sep 29 00:00:00 EDT 2017}
}
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