Manipulation of Optical Transmittance by Ordered-Oxygen-Vacancy in Epitaxial LaBaCo2O5.5+δ Thin Films
Abstract
Giant optical transmittance changes of over 300% in wide wavelength range from 500 nm to 2500 nm were observed in LaBaCo2O5.5+δ thin films annealed in air and ethanol ambient, respectively. The reduction process induces high density of ordered oxygen vacancies and the formation of LaBaCo2O5.5 (δ = 0) structure evidenced by aberration-corrected transmission electron microscopy. Moreover, the first-principles calculations reveal the origin and mechanism of optical transmittance enhancement in LaBaCo2O5.5 (δ = 0), which exhibits quite different energy band structure compared to that of LaBaCo2O6 (δ = 0.5). The discrepancy of energy band structure was thought to be the direct reason for the enhancement of optical transmission in reducing ambient. Thus, LaBaCo2O5.5+δ thin films show great prospect for applications on optical gas sensors in reducing/oxidizing atmosphere.
- Authors:
-
- Xi'an Jiaotong Univ., Xi'an (China). School of Electronic and Information Engineering
- Chinese Academy of Sciences, Changchun (China). Changchun Inst. of Optics, Fine Mechanics and Physics and State Key Lab. of Luminescence and Applications
- Xidian Univ., Xi'an (China). School of Microelectronics and State Key Discipline Lab. of Wide Band Gap Semiconductor Technology
- Xi'an Jiaotong Univ., Xi'an (China). State Key Lab. for Mechanical Behavior of Materials
- Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Physics, Applied Physics, and Astronomy
- Univ. of Texas, San Antonio, TX (United States). Dept. of Physics and Astronomy; Univ. of Houston, TX (United States). The Texas Center for Superconductivity
- Publication Date:
- Research Org.:
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- Sponsoring Org.:
- USDOE; National Natural Science Foundation of China (NSFC); National Basic Research Program of China
- OSTI Identifier:
- 1430215
- Grant/Contract Number:
- SC0002623; 51202185; 51390472; 51501143; 2015CB654903; 11504368; 51572211; 51202176
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; 47 OTHER INSTRUMENTATION; Electronic properties and materials
Citation Formats
Cheng, Sheng, Lu, Jiangbo, Han, Dong, Liu, Ming, Lu, Xiaoli, Ma, Chunrui, Zhang, Shengbai, and Chen, Chonglin. Manipulation of Optical Transmittance by Ordered-Oxygen-Vacancy in Epitaxial LaBaCo2O5.5+δ Thin Films. United States: N. p., 2016.
Web. doi:10.1038/srep37496.
Cheng, Sheng, Lu, Jiangbo, Han, Dong, Liu, Ming, Lu, Xiaoli, Ma, Chunrui, Zhang, Shengbai, & Chen, Chonglin. Manipulation of Optical Transmittance by Ordered-Oxygen-Vacancy in Epitaxial LaBaCo2O5.5+δ Thin Films. United States. https://doi.org/10.1038/srep37496
Cheng, Sheng, Lu, Jiangbo, Han, Dong, Liu, Ming, Lu, Xiaoli, Ma, Chunrui, Zhang, Shengbai, and Chen, Chonglin. Wed .
"Manipulation of Optical Transmittance by Ordered-Oxygen-Vacancy in Epitaxial LaBaCo2O5.5+δ Thin Films". United States. https://doi.org/10.1038/srep37496. https://www.osti.gov/servlets/purl/1430215.
@article{osti_1430215,
title = {Manipulation of Optical Transmittance by Ordered-Oxygen-Vacancy in Epitaxial LaBaCo2O5.5+δ Thin Films},
author = {Cheng, Sheng and Lu, Jiangbo and Han, Dong and Liu, Ming and Lu, Xiaoli and Ma, Chunrui and Zhang, Shengbai and Chen, Chonglin},
abstractNote = {Giant optical transmittance changes of over 300% in wide wavelength range from 500 nm to 2500 nm were observed in LaBaCo2O5.5+δ thin films annealed in air and ethanol ambient, respectively. The reduction process induces high density of ordered oxygen vacancies and the formation of LaBaCo2O5.5 (δ = 0) structure evidenced by aberration-corrected transmission electron microscopy. Moreover, the first-principles calculations reveal the origin and mechanism of optical transmittance enhancement in LaBaCo2O5.5 (δ = 0), which exhibits quite different energy band structure compared to that of LaBaCo2O6 (δ = 0.5). The discrepancy of energy band structure was thought to be the direct reason for the enhancement of optical transmission in reducing ambient. Thus, LaBaCo2O5.5+δ thin films show great prospect for applications on optical gas sensors in reducing/oxidizing atmosphere.},
doi = {10.1038/srep37496},
journal = {Scientific Reports},
number = 1,
volume = 6,
place = {United States},
year = {Wed Nov 23 00:00:00 EST 2016},
month = {Wed Nov 23 00:00:00 EST 2016}
}
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