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Title: A Shell-Shaped Carbon Architecture with High-Loading Capability for Lithium Sulfide Cathodes

Abstract

Lithium sulfide (Li2S) is considered a highly attractive cathode for establishing high-energy-density rechargeable batteries, especially due to its high charge-storage capacity and compatibility with lithium-metal-free anodes. Although various approaches have recently been pursued with Li2S to obtain high performance, formidable challenges still remain with cell design (e.g., low Li2S loading, insufficient Li2S content, and an excess electrolyte) to realize high areal, gravimetric, and volumetric capacities. This study demonstrates a shell-shaped carbon architecture for holding pure Li2S, offering innovation in cell-design parameters and gains in electrochemical characteristics.

Authors:
 [1];  [1];  [1];  [1]
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  1. Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program, Texas Materials Institute
Publication Date:
Research Org.:
Univ. of Texas, Austin, TX (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1430177
Alternate Identifier(s):
OSTI ID: 1378808; OSTI ID: 1487393
Grant/Contract Number:  
EE0007218
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 7; Journal Issue: 17; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE

Citation Formats

Chung, Sheng-Heng, Han, Pauline, Chang, Chi-Hao, and Manthiram, Arumugam. A Shell-Shaped Carbon Architecture with High-Loading Capability for Lithium Sulfide Cathodes. United States: N. p., 2017. Web. doi:10.1002/aenm.201700537.
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Chung, Sheng-Heng, Han, Pauline, Chang, Chi-Hao, & Manthiram, Arumugam. A Shell-Shaped Carbon Architecture with High-Loading Capability for Lithium Sulfide Cathodes. United States. https://doi.org/10.1002/aenm.201700537
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Chung, Sheng-Heng, Han, Pauline, Chang, Chi-Hao, and Manthiram, Arumugam. Thu . "A Shell-Shaped Carbon Architecture with High-Loading Capability for Lithium Sulfide Cathodes". United States. https://doi.org/10.1002/aenm.201700537. https://www.osti.gov/servlets/purl/1430177.
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@article{osti_1430177,
title = {A Shell-Shaped Carbon Architecture with High-Loading Capability for Lithium Sulfide Cathodes},
author = {Chung, Sheng-Heng and Han, Pauline and Chang, Chi-Hao and Manthiram, Arumugam},
abstractNote = {Lithium sulfide (Li2S) is considered a highly attractive cathode for establishing high-energy-density rechargeable batteries, especially due to its high charge-storage capacity and compatibility with lithium-metal-free anodes. Although various approaches have recently been pursued with Li2S to obtain high performance, formidable challenges still remain with cell design (e.g., low Li2S loading, insufficient Li2S content, and an excess electrolyte) to realize high areal, gravimetric, and volumetric capacities. This study demonstrates a shell-shaped carbon architecture for holding pure Li2S, offering innovation in cell-design parameters and gains in electrochemical characteristics.},
doi = {10.1002/aenm.201700537},
journal = {Advanced Energy Materials},
number = 17,
volume = 7,
place = {United States},
year = {2017},
month = {5}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/aenm.201700537
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Citation Metrics:
Cited by: 19 works
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Figures / Tables:

Figure 1 Figure 1: (a) Schematic structure of a core-shell Li2S cathode. Optimization of the cell-design parameters: (b) E/L-ratio, (c) active-material-amount, (d) literature analysis based on references R1 – R55 (listed at the end of the supporting information) and this work. The calculation of parameters including everything in the cathode region andmore » the cathode material alone are marked, respectively, with and without *.« less
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Works referenced in this record:

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    Works referencing / citing this record:

    Toward High Performance Lithium-Sulfur Batteries Based on Li 2 S Cathodes and Beyond: Status, Challenges, and Perspectives
    journal, March 2018

    • Su, Dawei; Zhou, Dong; Wang, Chengyin
    • Advanced Functional Materials, Vol. 28, Issue 38
    • DOI: 10.1002/adfm.201800154

    Progress on the Critical Parameters for Lithium-Sulfur Batteries to be Practically Viable
    journal, May 2018

    • Chung, Sheng-Heng; Chang, Chi-Hao; Manthiram, Arumugam
    • Advanced Functional Materials, Vol. 28, Issue 28
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    A Bifunctional Perovskite Promoter for Polysulfide Regulation toward Stable Lithium-Sulfur Batteries
    journal, November 2017

    Rational Design of Statically and Dynamically Stable Lithium-Sulfur Batteries with High Sulfur Loading and Low Electrolyte/Sulfur Ratio
    journal, December 2017

    A Facile, Low-Cost Hot-Pressing Process for Fabricating Lithium-Sulfur Cells with Stable Dynamic and Static Electrochemistry
    journal, October 2018

    • Chung, Sheng-Heng; Lai, Ke-Yu; Manthiram, Arumugam
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    Current Status and Future Prospects of Metal–Sulfur Batteries
    journal, May 2019

    A Li 2 S‐TiS 2 ‐Electrolyte Composite for Stable Li 2 S‐Based Lithium–Sulfur Batteries
    journal, June 2019

    • Chung, Sheng‐Heng; Manthiram, Arumugam
    • Advanced Energy Materials, Vol. 9, Issue 30
    • DOI: 10.1002/aenm.201901397

    Controlling Nucleation in Lithium Metal Anodes
    journal, July 2018

    Nanostructured Host Materials for Trapping Sulfur in Rechargeable Li-S Batteries: Structure Design and Interfacial Chemistry
    journal, November 2017

    Ionic liquid treated carbon nanotube sponge as high areal capacity cathode for lithium sulfur batteries
    journal, March 2018

    • Lin, Henry Taisun; Yang, Gang; Tsao, Yi-Yun Timothy
    • Journal of Applied Electrochemistry, Vol. 48, Issue 5
    • DOI: 10.1007/s10800-018-1181-7

    Structural Design of Lithium–Sulfur Batteries: From Fundamental Research to Practical Application
    journal, June 2018

    Electrochemically primed functional redox mediator generator from the decomposition of solid state electrolyte
    journal, April 2019

    Facile preparation of ultrafine Ti 4 O 7 nanoparticle-embedded porous carbon for high areal capacity lithium–sulfur batteries
    journal, January 2018

    • Chen, Ao; Liu, Weifang; Hu, Hang
    • Journal of Materials Chemistry A, Vol. 6, Issue 41
    • DOI: 10.1039/c8ta07511e
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      Figures / Tables found in this record:

      Figure 1 (p. 14)figure
      Figure 2 (p. 15)figure
      Figure 3 (p. 16)figure
      Figure S1 (p. 21)figure
      Figure S2 (p. 21)figure
      Figure S3 (p. 22)figure
      Figure S4 (p. 22)figure
      Figure S5 (p. 23)figure
      Figure S6 (p. 23)figure
      Figure S7 (p. 24)figure
      Table S1 (part 1) (p. 25)table
      Table S1 (part 2) (p. 26)table
      Table S1 (part 3) (p. 27)table
      Table S1 (part 4) (p. 28)table
      Table S1 (part 5) (p. 29)table
      Table S2 (p. 29)table
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