Nitrogen-doped carbon nanofibers derived from polypyrrole coated bacterial cellulose as high-performance electrode materials for supercapacitors and Li-ion batteries
Abstract
Here, nitrogen-doped carbon nanofiber (NDCN) was synthesized via carbonization of polypyrrole (PPy) coated bacterial cellulose (BC) composites, where BC serves as templates as well as precursor, and PPy serves as the nitrogen source. The synthesized NDCN was employed as electrode for both supercapacitors and Li-ion batteries. The large surface area exposed to electrolyte resulting from the 3D carbon networks leads to sufficient electrode/electrolyte interface and creates shorter transport paths of electrolyte ions and Li+ ion. Besides, the three types of N dopants in NDCN improve the electronic conductivity, as well as superior electrochemical performance.
- Authors:
-
- Huazhong Univ. of Science and Technology, Wuhan (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Tianjin Univ., Tianjin (China). School of Materials Science and Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Stony Brook Univ., NY (United States). Dept. of Materials Science and Engineering
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1342630
- Alternate Identifier(s):
- OSTI ID: 1430165
- Report Number(s):
- BNL-113424-2017-JA
Journal ID: ISSN 0013-4686; R&D Project: 16060; 16060; KC0403020
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Electrochimica Acta
- Additional Journal Information:
- Journal Volume: 210; Journal Issue: C; Journal ID: ISSN 0013-4686
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; Li-ion battery; Center for Functional Nanomaterials; supercapacitors; polypyrrole; bacterial cellulose; nitrogen-doping
Citation Formats
Lei, Wen, Han, Lili, Xuan, Cuijuan, Lin, Ruoqian, Liu, Hongfang, Xin, Huolin L., and Wang, Deli. Nitrogen-doped carbon nanofibers derived from polypyrrole coated bacterial cellulose as high-performance electrode materials for supercapacitors and Li-ion batteries. United States: N. p., 2016.
Web. doi:10.1016/j.electacta.2016.05.158.
Lei, Wen, Han, Lili, Xuan, Cuijuan, Lin, Ruoqian, Liu, Hongfang, Xin, Huolin L., & Wang, Deli. Nitrogen-doped carbon nanofibers derived from polypyrrole coated bacterial cellulose as high-performance electrode materials for supercapacitors and Li-ion batteries. United States. https://doi.org/10.1016/j.electacta.2016.05.158
Lei, Wen, Han, Lili, Xuan, Cuijuan, Lin, Ruoqian, Liu, Hongfang, Xin, Huolin L., and Wang, Deli. Tue .
"Nitrogen-doped carbon nanofibers derived from polypyrrole coated bacterial cellulose as high-performance electrode materials for supercapacitors and Li-ion batteries". United States. https://doi.org/10.1016/j.electacta.2016.05.158. https://www.osti.gov/servlets/purl/1342630.
@article{osti_1342630,
title = {Nitrogen-doped carbon nanofibers derived from polypyrrole coated bacterial cellulose as high-performance electrode materials for supercapacitors and Li-ion batteries},
author = {Lei, Wen and Han, Lili and Xuan, Cuijuan and Lin, Ruoqian and Liu, Hongfang and Xin, Huolin L. and Wang, Deli},
abstractNote = {Here, nitrogen-doped carbon nanofiber (NDCN) was synthesized via carbonization of polypyrrole (PPy) coated bacterial cellulose (BC) composites, where BC serves as templates as well as precursor, and PPy serves as the nitrogen source. The synthesized NDCN was employed as electrode for both supercapacitors and Li-ion batteries. The large surface area exposed to electrolyte resulting from the 3D carbon networks leads to sufficient electrode/electrolyte interface and creates shorter transport paths of electrolyte ions and Li+ ion. Besides, the three types of N dopants in NDCN improve the electronic conductivity, as well as superior electrochemical performance.},
doi = {10.1016/j.electacta.2016.05.158},
journal = {Electrochimica Acta},
number = C,
volume = 210,
place = {United States},
year = {Tue May 24 00:00:00 EDT 2016},
month = {Tue May 24 00:00:00 EDT 2016}
}
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